Fabrication Of Metal Organic Framework Derived Nanomaterials And Their Electrochemical Applications

This thesis systematically introduces readers to a new metal-organic framework approach to fabricating nanostructured materials for electrochemical applications. Based on the metal-organic framework (MOF) approach, it also demonstrates the latest ideas on how to create optimal MOF and MOF-derived nanomaterials for electrochemical reactions under controlled conditions. The thesis offers a valuable resource for researchers who want to understand electrochemical reactions at nanoscale and optimize materials from rational design to achieve enhanced electrochemical performance. It also serves as a useful reference guide to fundamental research on advanced electrochemical energy storage materials and the synthesis of nanostructured materials.

Metal-Organic Framework Nanocomposites: From Design to Application assembles the latest advances in MOF nanocomposites, emphasizing their design, characterization, manufacturing, and application and offering a wide-ranging view of these materials with exceptional physical and chemical properties. FEATURES Discusses various types of MOF materials, such as polyaniline MOF nanocomposites, magnetic MOF nanocomposites, and carbon nanotube-based MOF nanocomposites Includes chapters on the usage of these materials in pollutant removal, electrochemical devices, photocatalysts, biomedical applications, and other applications Covers different aspects of composite fabrication from energy storage and catalysts, including preparation, design, and characterization techniques Emphasizes the latest technology in the field of manufacturing and design Aimed at researchers, academics, and advanced students in materials science and engineering, this book offers a comprehensive overview and analysis of these extraordinary materials.

Metal–organic frameworks (MOFs) are porous crystalline polymers con­structed by metal sites and organic building blocks. Since the discovery of MOFs in the 1990s, they have received tremendous research attention for various applications due to their high surface area, controllable mor­phology, tunable chemical properties, and multifunctionalities, including MOFs as precursors and self-sacrificing templates for synthesizing metal oxides, heteroatom-doped carbons, metal-atoms encapsulated carbons, and others. Thus, awareness and knowledge about MOFs and their derived nanomaterials with conceptual understanding are essential for the advanced material community. This breakthrough new volume aims to explore down-to-earth applications in fields such as bio­medical, environmental, energy, and electronics. This book provides an overview of the structural and fundamental properties, synthesis strate­gies, and versatile applications of MOFs and their derived nanomaterials. It gives an updated and comprehensive account of the research in the field of MOFs and their derived nanomaterials. Whether as a reference for industry professionals and nanotechnologists or for use in the classroom for graduate and postgraduate students, faculty members, and research and development specialists working in the area of inorganic chemistry, materials science, and chemical engineering, this is a must-have for any library.

Metal-Organic Framework-Based Nanomaterials for Energy Conversion and Storage addresses current challenges and covers design and fabrication approaches for nanomaterials based on metal organic frameworks for energy generation and storage technologies. The effect of synthetic diversity, functionalization, ways of improving conductivity and electronic transportation, tuning-in porosity to accommodate various types of electrolyte, and the criteria to achieve the appropriate pore size, shape and surface group of different metal sites and ligands are explored. The effect of integration of other elements, such as second metals or hetero-atomic doping in the system, to improve catalytic activity and durability, are also covered. This is an important reference source for materials scientists, engineers and energy scientists looking to further their understanding on how metal organic framework-based nanomaterials are being used to create more efficient energy conversion and storage systems. Describes major metal organic framework-based nanomaterials applications for fuel cell, battery, supercapacitor and photovoltaic applications Provides information on the various nanomaterial types used for creating the most efficient energy conversion and storage systems Assesses the major challenges of using nanotechnology to manufacture energy conversion and storage systems on an industrial scale

With an unprecedented population boom and rapid industrial development, environmental pollution has become a severe problem for the ecosystem and public health. Classical techniques for sensing and determining environmental contaminants often require complex pretreatments, expensive equipment, and longer testing times. Therefore, new, and state-of-the-art sensing technologies possessing the advantages of excellent sensitivity, rapid detection, ease of use, and suitability for in situ, real-time, and continuous monitoring of environmental pollutants, are highly desirable. Metal-Organic Frameworks-based Hybrid Materials for Environmental Sensing and Monitoring covers the current-state-of-the-art hybrid nanomaterials based on metal-organic frameworks for electrochemical monitoring purposes. Accomplished authors cover various synthetic routes, methods, and theories behind enhancing the electrochemical properties and applications of metal-organic frameworks-based hybrid nanomaterials for electrochemical sensing of environmental pollutants under one roof. This book is essential reading for all academic and industrial researchers working in the fields of materials science and nanotechnology.

Metal–organic frameworks (MOFs) are porous crystalline polymers constructed by metal sites and organic building blocks. Since the discovery of MOFs in the 1990s, they have received tremendous research attention for various applications due to their high surface area, controllable morphology, tunable chemical properties, and multifunctionalities, including MOFs as precursors and self-sacrificing templates for synthesizing metal oxides, heteroatom-doped carbons, metal-atoms encapsulated carbons, and others. Thus, awareness and knowledge about MOFs and their derived nanomaterials with conceptual understanding are essential for the advanced material community. This breakthrough new volume aims to explore down-to-earth applications in fields such as biomedical, environmental, energy, and electronics. This book provides an overview of the structural and fundamental properties, synthesis strategies, and versatile applications of MOFs and their derived nanomaterials. It gives an updated and comprehensive account of the research in the field of MOFs and their derived nanomaterials. Whether as a reference for industry professionals and nanotechnologists or for use in the classroom for graduate and postgraduate students, faculty members, and research and development specialists working in the area of inorganic chemistry, materials science, and chemical engineering, this is a must-have for any library.

Metal Oxides in Supercapacitors addresses the fundamentals of metal oxide-based supercapacitors and provides an overview of recent advancements in this area. Metal oxides attract most of the materials scientists use due to their excellent physico-chemical properties and stability in electrochemical systems. This justification for the usage of metal oxides as electrode materials in supercapacitors is their potential to attain high capacitance at low cost. After providing the principles, the heart of the book discusses recent advances, including: binary metal oxides-based supercapacitors, nanotechnology, ternary metal oxides, polyoxometalates and hybrids. Moreover, the factors affecting the charge storage mechanism of metal oxides are explored in detail. The electrolytes, which are the soul of supercapacitors and a mostly ignored character of investigations, are also exposed in depth, as is the fabrication and design of supercapacitors and their merits and demerits. Lastly, the market status of supercapacitors and a discussion pointing out the future scope and directions of next generation metal oxides based supercapacitors is explored, making this a comprehensive book on the latest, cutting-edge research in the field. Explores the most recent advances made in metal oxides in supercapacitors Discusses cutting-edge nanotechnology for supercapacitors Includes fundamental properties of metal oxides in supercapacitors that can be used to guide and promote technology development Contains contributions from leading international scientists active in supercapacitor research and manufacturing

Electrochemical Applications of Metal -Organic Frameworks: Advances and Future Potential brings together the basics of Metal-Organic Frameworks (MOFs and it's chemistry and electrochemistry), giving the reader an understanding of the complexities and possibilities of MOF electrochemistry. Providing in-depth coverage of various methods of the synthesis of MOFs for their electrochemical applications, the morphological and electrochemical properties of these materials are discussed along with their future development. Sections cover electrochemical applications of MOFs in batteries, supercapacitors, fuel cells, as anti-corrosive materials, sensors and in electrocatalysis, and more.Recent developments in MOFs that can hold active molecules such as enzymes, bacteria, nanoparticles and promote electrochemical activity are included. This book will be of great interest to researchers and professionals working in industry and academia or anyone interested in the applications of MOF in industrial processes. Provides in-depth coverage of the various methods of synthesis for metal-organic frameworks and their applications in electrochemistry Describes MOF based research in emerging technologies, including solid-state electrolytes and battery operation in extreme environments Provides an instructive roadmap for future MOF research in advanced energy storage devices