Foundations Of Statistical Mechanics

Phase space, ergodic problems, central limit theorem, dispersion and distribution of sum functions. Chapters include Geometry and Kinematics of the Phase Space; Ergodic Problem; Reduction to the Problem of the Theory of Probability; Application of the Central Limit Theorem; Ideal Monatomic Gas; The Foundation of Thermodynamics; and more.

In a certain sense this book has been twenty-five years in the writing, since I first struggled with the foundations of the subject as a graduate student. It has taken that long to develop a deep appreciation of what Gibbs was attempting to convey to us near the end of his life and to understand fully the same ideas as resurrected by E.T. Jaynes much later. Many classes of students were destined to help me sharpen these thoughts before I finally felt confident that, for me at least, the foundations of the subject had been clarified sufficiently. More than anything, this work strives to address the following questions: What is statistical mechanics? Why is this approach so extraordinarily effective in describing bulk matter in terms of its constituents? The response given here is in the form of a very definite point of view-the principle of maximum entropy (PME). There have been earlier attempts to approach the subject in this way, to be sure, reflected in the books by Tribus [Thermostat ics and Thermodynamics, Van Nostrand, 1961], Baierlein [Atoms and Information Theory, Freeman, 1971], and Hobson [Concepts in Statistical Mechanics, Gordon and Breach, 1971].

International Series of Monographs in Natural Philosophy, Volume 22: Foundations of Statistical Mechanics: A Deductive Treatment presents the main approaches to the basic problems of statistical mechanics. This book examines the theory that provides explicit recognition to the limitations on one's powers of observation. Organized into six chapters, this volume begins with an overview of the main physical assumptions and their idealization in the form of postulates. This text then examines the consequences of these postulates that culminate in a derivation of the fundamental formula for calculating probabilities in terms of dynamic quantities. Other chapters provide a careful analysis of the significant notion of entropy, which shows the links between thermodynamics and statistical mechanics and also between communication theory and statistical mechanics. The final chapter deals with the thermodynamic concept of entropy. This book is intended to be suitable for students of theoretical physics. Probability theorists, statisticians, and philosophers will also find this book useful.

Classic 1912 article reformulated the foundations of the statistical approach in mechanics. Largely still valid, the treatment covers older formulation of statistico-mechanical investigations, modern formulation of kineto-statistics of the gas model, and more. 1959 edition.

Phase space, ergodic problems, central limit theorem, dispersion and distribution of sum functions. Chapters include Geometry and Kinematics of the Phase Space; Ergodic Problem; Reduction to the Problem of the Theory of Probability; Application of the Central Limit Theorem; Ideal Monatomic Gas; The Foundation of Thermodynamics; and more.

Foundations of Classical and Quantum Statistical Mechanics details the theoretical foundation the supports the concepts in classical and quantum statistical mechanics. The title discusses the various problems set by the theoretical justification of statistical mechanics methods. The text first covers the the ergodic theory in classical statistical mechanics, and then proceeds to tackling quantum mechanical ensembles. Next, the selection discusses the the ergodic theorem in quantum statistical mechanics and probability quantum ergodic theorems. The selection also details H-theorems and kinetic equations in classical and quantum statistical mechanics. The book will be of great interest to students, researchers, and practitioners of physics, chemistry, and engineering.

Lawrence Sklar offers a comprehensive, non-technical introduction to statistical mechanics and attempts to understand its foundational elements.

A philosophical perspective to statistical mechanics for graduate students and researchers in the foundations and philosophy of physics.