Fundamental Principles Of Polymeric Materials

New edition brings classic text up to date with the latest science, techniques, and applications With its balanced presentation of polymer chemistry, physics, and engineering applications, the Third Edition of this classic text continues to instill readers with a solid understanding of the core concepts underlying polymeric materials. Both students and instructors have praised the text for its clear explanations and logical organization. It begins with molecular-level considerations and then progressively builds the reader's knowledge with discussions of bulk properties, mechanical behavior, and processing methods. Following a brief introduction, Fundamental Principles of Polymeric Materials is divided into four parts: Part 1: Polymer Fundamentals Part 2: Polymer Synthesis Part 3: Polymer Properties Part 4: Polymer Processing and Performance Thoroughly Updated and Revised Readers familiar with the previous edition of this text will find that the organization and style have been updated with new material to help them grasp key concepts and discover the latest science, techniques, and applications. For example, there are new introductory sections on organic functional groups focusing on the structures found in condensation polymerizations. The text also features new techniques for polymer analysis, processing, and microencapsulation as well as emerging techniques such as atom transfer radical polymerization. At the end of each chapter are problems—including many that are new to this edition—to test the reader's grasp of core concepts as they advance through the text. There are also references leading to the primary literature for further investigation of individual topics. A classic in its field, this text enables students in chemistry, chemical engineering, materials science, and mechanical engineering to fully grasp and apply the fundamentals of polymeric materials, preparing them for more advanced coursework.

Expanded discussion of extended-chain crystals and their commercial developments; phase behavior in polymer-solvent systems; and three-dimensional stress and strain introduction to the Flory-Huggins theory; the "modified Cross" model; and Tobolsky's "Procedure X" for extracting discrete relaxation times and moduli from data. New sections on scaleup calculations for the laminar flow of non-Newtonian fluids; liquid-crystal polymers; and group-transfer polymerization, including a quantitative treatment of Ziegler-Natta polymerization with worked-out examples. All kinetic expressions are written in terms of conversions (rather than monomer concentration) for greater generality and ease of application. Kinetic expressions incorporate the possibility of a variable-volume reaction mass, and feature new examples to illustrate the effects of variable volume.

Now in its second edition, this widely used text provides a unique presentation of today's polymer science. It is both comprehensive and readable. The authors are leading educators in this field with extensive background in industrial and academic polymer research. The text starts with a description of the types of microstructures found in polymer

Exploring the chemistry of synthesis, mechanisms of polymerization, reaction engineering of step-growth and chain-growth polymerization, polymer characterization, thermodynamics and structural, mechanical, thermal and transport behavior of polymers as melts, solutions and solids, Fundamentals of Polymer Engineering, Third Edition covers essential concepts and breakthroughs in reactor design and polymer production and processing. It contains modern theories and real-world examples for a clear understanding of polymer function and development. This fully updated edition addresses new materials, applications, processing techniques, and interpretations of data in the field of polymer science. It discusses the conversion of biomass and coal to plastics and fuels, the use of porous polymers and membranes for water purification, and the use of polymeric membranes in fuel cells. Recent developments are brought to light in detail, and there are new sections on the improvement of barrier properties of polymers, constitutive equations for polymer melts, additive manufacturing and polymer recycling. This textbook is aimed at senior undergraduate students and first year graduate students in polymer engineering and science courses, as well as professional engineers, scientists, and chemists. Examples and problems are included at the end of each chapter for concept reinforcement.

W ALL ARE SURROUNDED by plastic materials and cannot imagine modem life and utilities without the synthetic polymers. And yet, how many of us can distinguish between polyethylene and PVC? After all, most people name any polymer as ''Nylon. /I Is there any distinction between polymers and plastics? This introductory textbook tries to answer these questions and many others. It endeavors to provide the basic information required in modem life about the best utilization of new materials in the plastics era; the chemical sources of synthetic polymers, and the processes in which small"simple" molecules are converted to giant macromolecules, namely, high polymers; and the understanding of the role of these unique structures, their behavior and performance, their mechanical and thermal properties, flow and deforma tion. As we are mainly interested in the final product, the processing of plastics, through shaping and forming, presents a significant challenge to polymer engineering. All this is broadly discussed, ending with modem issues like composites, ecology and future prediction, followed by up-to-date informa tion and data about old as well as novel high performance polymers. The text is particularly targeted towards senior students of science and engineering (chemical, material, mechanical and others) who may use it as the first window to the world of polymers. At the same time many profession als who are involved in the resin or plastics industry may prefer this approach without elaborate math or overloading.

Exploring the characterization, thermodynamics and structural, mechanical, thermal and transport behavior of polymers as melts, solutions and solids, this text covers essential concepts and breakthroughs in reactor design and polymer production and processing. It contains modern theories, end-of-chapter problems and real-world examples for a clear understanding of polymer function and development. Fundamentals of Polymer Engineering, Second Edition provides a thorough grounding in the fundamentals of polymer science for more advanced study in the field of polymers. Topics include reaction engineering of step-growth polymerization, emulsion polymerization, and polymer diffusion.