Halide Glasses For Infrared Fiberoptics

The field of heavy metal halide glasses (namely fluorides) is only ten years old now, but it has developed rapidly since the discovery of fluorozirconate glasses by the group at the University of Rennes (France). The main reason for this was the early demonstration of the enormous potential of such glasses for use as long-haul ultra-low loss middle infrared waveguide materials, aided in part by the scientific interest held by their unusual short range structures. As a result, significant research efforts were initiated in the academic, government and industrial sectors in Europe, the United States and Japan. However, the search for a finished product has per haps led to a partial overlooking of some of the more funda mental aspects by the scientific community. After the initial excitement, the workers in this field are perhaps at a crossroads where attenuations lower than 1 dB/Km need to be obtained for long lengths of fiber of good chemical and thermal stability, in order to guarantee continual R&D sUE ports. Therefore, there is a strong need for a critical asses sment of the potential of halide glasses for infrared fiber optics and the formulation of recommendations for future re search in this area and other related fields.

The field of heavy metal halide glasses (namely fluorides) is only ten years old now, but it has developed rapidly since the discovery of fluorozirconate glasses by the group at the University of Rennes (France). The main reason for this was the early demonstration of the enormous potential of such glasses for use as long-haul ultra-low loss middle infrared waveguide materials, aided in part by the scientific interest held by their unusual short range structures. As a result, significant research efforts were initiated in the academic, government and industrial sectors in Europe, the United States and Japan. However, the search for a finished product has per haps led to a partial overlooking of some of the more funda mental aspects by the scientific community. After the initial excitement, the workers in this field are perhaps at a crossroads where attenuations lower than 1 dB/Km need to be obtained for long lengths of fiber of good chemical and thermal stability, in order to guarantee continual R&D sUE ports. Therefore, there is a strong need for a critical asses sment of the potential of halide glasses for infrared fiber optics and the formulation of recommendations for future re search in this area and other related fields.

Mid-Infrared Fibre Photonics: Glass Materials, Fibre Fabrication and Processing, Laser Sources and Devicess combines the latest glass chemistry, fibre fabrication and post processing techniques to provide a comprehensive reference on the fundamental science and latest research in fibre photonics for the mid-infrared range. The book systematically reviews the key glass materials systems including fluorides, chalcogenides, and oxides. Each materials chapter includes discussion of composition, structure, thermal, optical and mechanical properties, extrinsic and intrinsic loss mechanisms, materials preparation and purification techniques. Then Mid-Infrared Fibre Photonics: Glass Materials, Fibre Fabrication and Processing, Laser Sources and Devicess covers the most relevant fabrication, post-processing, and spectroscopy techniques. Fibre sources are also addressed including fibre sources for continuous wave emission, pulsed emission, and broadband emission. The book concludes with a brief overview of important medical, sensing and defence applications. Systematic coverage of the most relevant materials for mid-infrared fibre photonics including discussion of composition, structure, thermal, optical and mechanical properties, loss mechanisms, materials preparation and purification techniques Reviews the key fabrication and processing techniques of mid-infrared fibre technologies Addresses the important medical, sensing and defence applications

In the past 10 years, there have been many developments in the field of infrared transmitting fiber optics. This is highlighted by the many different fiber compositions that have been studied around the world for numerous practical applications. This book reviews different fiber systems, describing material properties, techniques used to prepare the fibers and fiber properties with particular emphasis on optical properties. These fibers possess unique optical, mechanical, and physical properties, enabling many technologies. Examples of applications are described within given chapters, allowing an engineer or scientist to choose the most appropriate fiber for a desired application. The introduction gives the reader an overview of transmission theory so that the basic concepts are clearly understood by someone new to the field. The next several chapters describe the different types of infrared transmitting fibers, including glass fibers such as those based on silica, fluoride, and chalcogenide glasses; the crystalline fibers based on single or polycrystalline materials; and hollow waveguides. The commercial chemical sensing applications of some of these new fibers are described. The final chapter summarizes the properties of the fibers and highlights future prospects.

From the reviews: "The book should be acquired by all libraries with an interest in glass science and applications...the title will endure for many years as the standard work on the properties of optical glass." Optical Systems Engineering

In the CRC Handbook of Laser Science and Technology: Supplement 2, experts summarize the discovery and properties of new optical materials that have appeared since the publication of Volumes III-V. Included are the latest advances in optical crystals, glasses and plastics, laser host materials, phase conjugation materials, linear electrooptic materials, nonlinear optical materials, magnetooptic materials, elastooptic materials, photorefractive materials, liquid crystals, and thin film coatings. The book also includes expanded coverage of optical waveguide materials and new sections on optical liquids, glass fiber lasers, diamond optics, and gradient index materials. Appendices include Designation of Russian Optical Glasses; Abbreviations, Acronyms, and Mineralogical or Common Names for Optical Materials; and Abbreviations for Methods of Preparing Optical Materials. Extensive tabulations of materials properties with references to the primary literature are provided throughout the supplement. The CRC Handbook of Laser Science and Technology: Supplement 2 represents the latest volume in the most comprehensive, up-to-date listing of the properties of optical materials for lasers and laser systems, making it an essential reference work for all scientists and engineers working in laser research and development.

One of the most exciting prospects for optical fibres made from fluoride glasses is the possibility of providing long distance optical communication systems without the need for repeaters. This objective has stimulated much of the work into fluoride glasses over the past ten years, and has prompted the writing of this book. It has also emerged that fluoride fibres can transmit both visible and infrared energy (from about 0.5 to 5 ,urn) and that they have many applications outside the field of telecommunications. These include optical fibre sensors (particularly in remote infrared spectroscopy), laser surgery and fibre lasers. Several companies are now established in the field, and good quality fluoride fibres are available from sources throughout the USA, Europe and Japan. Moreover, the first commercial instruments based on fluoride fibres are finding their way to the market place and these fibres will undoubtedly form the basis of many more instruments yet to be developed. The work presented in this book represents the field both from an academic understanding of the materials and ways to convert them into fibre, and from a practical and commercial viewpoint. The principal author and some of the co authors are based at the British Telecom Research Laboratories in the UK.