Handbook On Fullerene Synthesis Properties And Applications

The discovery of fullerenes, a new allotropic modification of carbon, is a prominent achievement of the late 20th century in chemistry. In this book, the authors present topical research in the study of the synthesis, properties and applications of fullerene. Topics discussed include phase equilibria in the fullerene-containing system; ionic compounds of fullerenes obtained by synthesis in solution; symmetrical features of fullerene structures in the fundamental domains theory of point symmetry groups; the biomedical application of fullerene; metal complex catalysts in the chemistry of fullerenes; functionalised nanofullerenes for hydrogen storage; self-assembly properties of fullerenes; and, the radiation induced phenomena in fullerenes.

Nanocarbon chemistry and physics is a fast-developing, broad research area – the Nobel prizes in 1996 and 2010 awarded to two key discoveries in the field, and several other nanocarbon achievements of comparable importance. Owing to this rapid growth, the nanocarbon landscape fundamentally changes every few years, creating a need to survey the field on a regular basis to update the books that have become incomplete or even obsolete. As such, this book focuses on fullerenes and metallofullerenes and also on the related areas of nanotubes and graphenes. All the covered research topics provide important fundamental knowledge for the natural sciences, but also for applications in molecular electronics, superconductivity, catalysis, photovoltaics and medical diagnostics. The current nanocarbon research activities have particularly high application potential in the conversion of solar energy, future molecular memories, non-conventional materials for optoelectronics, and new treatments for civilization diseases. Offering a truly up-to-date critical survey of nanocarbon science, its concepts and highlights, it follows the concept of a handbook: it addresses key topics systematically, from historical background, methodological aspects, current important issues, and application potential, all supplied with extensive referencing. With individual chapters written by leading experts with extensive research experience, it is a comprehensive reference resource for graduate students and active researchers alike.

Written by an outstanding team of experts in the interdisciplinary areas of research, this book is based on a new classification of the different types of fullerene polymers according to their chemical structures. It covers all aspects, from different classes, to their synthesis and applications in material science. Of great interest to polymer and synthetic chemists, but also for material scientists and industrial chemists.

1. Functionalization of graphene / Nikolaos Karousis, Solon Economopoulos and Nikos Tagmatarchis -- 2. Advanced carbon materials for electrochemical energy conversion and storage / Junbo Hou [und weitere] -- 3. Carbon nanomaterial-based molecular architectures for light energy conversion / Taku Hasobe -- 4. Electrochemistry of carbon nanostructures: from pristine materials to functional devices / Matteo Iurlo [und weitere] -- 5. Fullerene-based self-assembled morphological materials / Yanfei Shen, Junko Aimi and Takashi Nakanishi -- 6. Hybrids involving fullerenes and carbon nanotubes / Maria Vizuete [und weitere] -- 7. Semiconductor carbon nanotube optics / Lisa J. Nogaj, Libai Huang and Todd D. Krauss -- 8. Near-field optics of SWNTs and FRET in their nanoscale complexes / Tetyana Ignatova, Andrei M. Nemilentsau and Slava V. Rotkin -- 9. Understanding the role of the metal catalyst in carbon nanotube growth: towards chiral-selective growth of single-walled carbon nanotubes / Wei-Hung Chiang and R. Mohan Sankaran -- 10. Stability computations for fullerenes and metallofullerenes / Zdenek Slanina [und weitere]

The seventh and eighth volumes of Handbook of Carbon Nano Materials focus on novel properties and applications of nanocarbons, viz., graphene, nanotube and fullerene. The books provide a comprehensive overview of the author's work, and significant discoveries and pioneering contributions from other groups. Specific applications cover latest developments in graphene synthesis, CVD of carbon nanomaterials, multifunctional carbon nanostructures, chemical manipulation, energy conversion and storage, nanotube micellar surface chemistry, and biosensor development. This is a highly useful book for graduate students, as well as beginning and senior researchers.

A hands on reference guide for scientists working in the area of medicine, biology, chemistry, physics, materials science, sensor and biosensor, devices and nanotechnology. The first volume compiles topics from leading authors on medicinal and bio-related applications while the second volume covers topics ranging from materials and fundamental applications. In-depth and comprehensive coverage of topics combined with the perspectives for future research by the contributing authors. An invaluable reference source essential for both beginning and advanced researchers in the field.

This is the first set of Handbook of Porphyrin Science.Porphyrins, phthalocyanines and their numerous analogues and derivatives are materials of tremendous importance in chemistry, materials science, physics, biology and medicine. They are the red color in blood (heme) and the green in leaves (chlorophyll); they are also excellent ligands that can coordinate with almost every metal in the Periodic Table. Grounded in natural systems, porphyrins are incredibly versatile and can be modified in many ways; each new modification yields derivatives demonstrated new chemistry, physics and biology, with a vast array of medicinal and technical applications.As porphyrins are currently employed as platforms for study of theoretical principles and applications in a wide variety of fields, the Handbook of Porphyrin Science represents a timely ongoing series dealing in detail with the synthesis, chemistry, physicochemical and medical properties and applications of polypyrrole macrocycles. Professors Karl Kadish, Kevin Smith and Roger Guilard are internationally recognized experts in the research field of porphyrins, each having his own separate area of expertise in the field. Between them, they have published over 1500 peer-reviewed papers and edited more than three dozen books on diverse topics of porphyrins and phthalocyanines. In assembling the new volumes of this unique Handbook, they have selected and attracted the very best scientists in each sub-discipline as contributing authors of the chaptersThis Handbook will prove to be a modern authoritative treatise on the subject as it is a collection of up-to-date works by world-renowned experts in the field. Complete with hundreds of figures, tables and structural formulas, and thousands of literature citations, all researchers and graduate students in this field will find the Handbook of Porphyrin Science an essential, major reference source for many years to come.

The fullerenes, hailed as one of the discoveries of the century, have created whole new fields of organic/organometallic chemistry and of physics. Together with the related nanotubes, they hold the promise of providing new materials with novel chemical and solid state properties. The cost of the basic fullerenes is now such that research into them is feasible for very many chemists. This book describes the fundamental aspects of fullerene chemistry. Following brief background on the discovery, basic fullerene nomenclature, and relevant properties (including those of endohedral fullerenes and nanotubes), there are chapters describing the rules governing the addition patterns, and each of the reaction types with representative examples. Leading references are given to key papers describing individual reactions and phenomena. Contents:The Structure and Properties of FullerenesAddition PatternsHydrogenationReduction by Electron Addition, and Reaction of Fullerene Radical Anions with ElectrophilesNucleophilic Addition, and Reaction of Fullerene Anions with ElectrophilesRadical ReactionsNucleophilic Substitution of Fullerenes: Fullerenes as ElectrophilesCycloadditionsOxidation and the Formation of Radical Cations and CationsInorganic and Organometallic Derivatives of FullerenesPolymers, Dendrimers, Dimers, Dumb-bells and Related StructuresHeterofullerenesThe Chemistry of Incar-fullerene (Endohedral Fullerenes) Readership: Undergraduates and researchers in chemistry. Keywords:Fullerenes;Chemistry;(Fullerene) Properties;(Fullerene) Nomenclature;(Fullerene) Reactions;(Fullerene) DiscoveryReviews:“… this is an affordable and readable introduction to experimental fullerene chemistry, with pictures, facts and open problems to whet the appetite of those wondering where these new molecules will lead. It can be recommended to specialists and a general audience alike.”Chemistry in Britain