Indium

The extraordinary growth of the computer and semiconductor industries and the increasing consumption of indium in these technologies in recent years have placed major constraints on current and future reserves of this metal. In the past, geoscientists have noticed the occurrence of indium in a large variety of ore de posits and detailed geochemical and mineralogical work is available for a few ex amples. However, despite the current technological interest, there is no compre hensive textbook that deals with all aspects of indium mineralization and economics. The present study attempts to develop a general metallogenic concept for indium in identifying the essential enrichment processes and their economic significance. The study 'Indium Geology, Mineralogy, and Economics' was commissioned and funded by the German Federal Institute for Geosciences and Natural Re sources (BGR Hannover) and is a contribution to the research program 'BGR 2000 - Raw Materials with Short Lifetime Reserves'. This program focuses on raw materials with known reserves confined to the next 20-25 years at static de mand. The future availability of reserves is usually estimated by dividing the known reserves by the current annual consumption. In fact, lifetimes of reserves are inappropriate measures because they depend on many parameters and there fore represent a "snapshot" of a dynamic system. In order to provide a sustainable use of raw materials with short lifetime reserves, a significantly higher amount of innovation is needed compared to raw materials with long lifetime reserves.

Boron has all the best tunes. That may well be the first impression of the Group 13 elements. The chemical literature fosters the impression not only in the primary journals, but also in asteady outflowofbooks focussing more or less closely on boron and its compounds. The same preoccupation with boron is apparent in the coverage received by the Group 13 elements in the comprehensive and regularly updated volume of the Gmelin Handbook. Yet such an imbalance cannot be explained by any inherent lack ofvariety, interest or consequence in the 'heavier elements. Aluminium is the most abundant metal in the earth's crust; in the industrialised world the metal is second only to iron in its usage, and its compounds can justifiably be said to touch our lives daily - to the potential detriment of those and other lives, some would argue. From being chemical curios, gallium and indium have now gained considerably prominence as sources of compound semiconductors like gallium arsenide and indium antimonide. Nor is there any want ofincident in the chemistriesofthe heavier Group 13 elements. In their redox, coordination and structural properties, there is to be found music indeed, notable not always for its harmony but invariably for its richness and variety. Thisbook seeks to redress the balance with a definitive, wide-rangingand up-to-date review of the chemistry of the Group 13 metals aluminium, gallium, indium and thallium.

The last two decades have seen a renaissance in interest in the chemistry of the main group elements. In particular research on the metals of group 13 (aluminium, gallium, indium and thallium) has led to the synthesis and isolation of some very novel and unusual molecules, with implications for organometallic synthesis, new materials development, and with biological, medical and, environmental relevance. The Group 13 Metals Aluminium, Gallium, Indium and Thallium aims to cover new facts, developments and applications in the context of more general patterns of physical and chemical behaviour. Particular attention is paid to the main growth areas, including the chemistry of lower formal oxidation states, cluster chemistry, the investigation of solid oxides and hydroxides, advances in the formation of III-V and related compounds, the biological significance of Group 13 metal complexes, and the growing importance of the metals and their compounds in the mediation of organic reactions. Chapters cover: general features of the group 13 elements group 13 metals in the +3 oxidation state: simple inorganic compounds formal oxidation state +3: organometallic chemistry formal oxidation state +2: metal-metal bonded vs. mononuclear derivatives group 13 metals in the +1 oxidation state mixed or intermediate valence group 13 metal compounds aluminium and gallium clusters: metalloid clusters and their relation to the bulk phases, to naked clusters, and to nanoscaled materials simple and mixed metal oxides and hydroxides: solids with extended structures of different dimensionalities and porosities coordination and solution chemistry of the metals: biological, medical and, environmental relevance III-V and related semiconductor materials group 13 metal-mediated organic reactions The Group 13 Metals Aluminium, Gallium, Indium and Thallium provides a detailed, wide-ranging, and up-to-date review of the chemistry of this important group of metals. It will find a place on the bookshelves of practitioners, researchers and students working in inorganic, organometallic, and materials chemistry.

The Chemistry of Aluminium, Gallium, Indium and Thallium

The feasibility of using indium seals for large vacuum bell jars has been investigated. It is shown that such seals can be made; however, use of this type seal for repetitive operations is not recommended.

The Analytical Chemistry of Indium is a compilation of information on the analytical chemistry of indium, a metal that is important in optical and electronics industries and a component of certain alloys. The monograph aims to provide factual material available on the analytical chemistry of indium. The book gives an overview of the history and chemical properties of the element indium. Methods for the detection, separation, and determination of indium, including special methods for its determination in industrial and natural products are likewise discussed and evaluated. The text will be of good use to chemists, physicists, materials engineers, researchers, and students.