Introduction To Physics And Chemistry Of Combustion

Most of the material covered in this book deals with the fundamentals of chemistry and physics of key processes and fundamental mechanisms for various combustion and combustion related phenomena in gaseous combustible mixture. It provides the reader with basic knowledge of burning processes and mechanisms of reaction wave propagation. The combustion of a gas mixture (flame, explosion, detonation) is necessarily accompanied by motion of the gas. The process of combustion is therefore not only a chemical phenomenon but also one of gas dynamics. The material selection focuses on the gas phase and with premixed gas combustion. Premixed gas combustion is of practical importance in engines, modern gas turbine and explosions, where the fuel and air are essentially premixed, and combustion occurs by the propagation of a front separating unburned mixture from fully burned mixture. Since premixed combustion is the most fundamental and potential for practical applications, the emphasis in the present work is be placed on regimes of premixed combustion. This text is intended for graduate students of different specialties, including physics, chemistry, mechanical engineering, computer science, mathematics and astrophysics.

This book provides a rigorous treatment of the coupling of chemical reactions and fluid flow. Combustion-specific topics of chemistry and fluid mechanics are considered and tools described for the simulation of combustion processes. This edition is completely restructured. Mathematical Formulae and derivations as well as the space-consuming reaction mechanisms have been replaced from the text to appendix. A new chapter discusses the impact of combustion processes on the atmosphere, the chapter on auto-ignition is extended to combustion in Otto- and Diesel-engines, and the chapters on heterogeneous combustion and on soot formation are heavily revised.

This book provides the latest achievements and original research work in physics of combustion processes and application of the methods developed in combustion physics for astrophysical problems of stars burning, supernovae explosions and a confined thermonuclear fusion. All the materials in the book are presented in a concise and easily accessible way, but at the same time provides a deep physical inside in the phenomena considered. It is an effective theoretical course with the direct practical implications in engineering fields of engine’s development, energy production, safety issues inherent to terrestrial combustion, as well as in thermonuclear combustion in the inertial fusion. This book is aimed at university students, Ph.D. students and engineers, as well as professionals in combustion, energy-related research, astrophysics and researchers in neighboring fields.

This graduate-level text incorporates these advances in a comprehensive treatment of the fundamental principles of combustion physics. The presentation emphasises analytical proficiency and physical insight, with the former achieved through complete, though abbreviated, derivations at different levels of rigor, and the latter through physical interpretations of analytical solutions, experimental observations, and computational simulations. Exercises are mostly derivative in nature in order to further strengthen the student's mastery of the theory. Implications of the fundamental knowledge gained herein on practical phenomena are discussed whenever appropriate. These distinguishing features provide a solid foundation for an academic program in combustion science and engineering.

Throughout its previous four editions, Combustion has made a very complex subject both enjoyable and understandable to its student readers and a pleasure for instructors to teach. With its clearly articulated physical and chemical processes of flame combustion and smooth, logical transitions to engineering applications, this new edition continues that tradition. Greatly expanded end-of-chapter problem sets and new areas of combustion engineering applications make it even easier for students to grasp the significance of combustion to a wide range of engineering practice, from transportation to energy generation to environmental impacts. Combustion engineering is the study of rapid energy and mass transfer usually through the common physical phenomena of flame oxidation. It covers the physics and chemistry of this process and the engineering applications—including power generation in internal combustion automobile engines and gas turbine engines. Renewed concerns about energy efficiency and fuel costs, along with continued concerns over toxic and particulate emissions, make this a crucial area of engineering. New chapter on new combustion concepts and technologies, including discussion on nanotechnology as related to combustion, as well as microgravity combustion, microcombustion, and catalytic combustion—all interrelated and discussed by considering scaling issues (e.g., length and time scales) New information on sensitivity analysis of reaction mechanisms and generation and application of reduced mechanisms Expanded coverage of turbulent reactive flows to better illustrate real-world applications Important new sections on stabilization of diffusion flames—for the first time, the concept of triple flames will be introduced and discussed in the context of diffusion flame stabilization

Combustion is an old technology, which at present provides about 90% of our worldwide energy support. Combustion research in the past used fluid mechanics with global heat release by chemical reactions described with thermodynamics, assuming infinitely fast reactions. This approach was useful for stationary combustion processes, but it is not sufficient for transient processes like ignition and quenching or for pollutant formation. Yet pollutant formation during combustion of fossil fuels is a central topic and will continue to be so in future. This book provides a detailed and rigorous treatment of the coupling of chemical reactions and fluid flow. Also, combustion-specific topics of chemistry and fluid mechanics are considered, and tools described for the simulation of combustion processes. For the 2nd edition, the parts dealing with experiments, spray combustion, and soot were thoroughly revised.

"With a facsimile reproduction of Faraday's manuscript lecture notes from Royal Institution MS F4 J21"