Irreversibilities In Quantum Mechanics

The problem of irreversibility is ubiquitous in physics and chemistry. The present book attempts to present a unified theoretical and conceptual framework for the description of various irreversible phenomena in quantum mechanics. In a sense, this book supplements conventional textbooks on quantum mechanics by including the theory of irreversibilities. However, the content and style of this book are more appropriate for a monograph than a textbook. We have tried to arrange the material so that, as far as possible, the reader need not continually refer elsewhere. The references to the literature make no pretense of completeness. The book is by no means a survey of present theoretical work. We have tried to highlight the basic principles and their results, while the attention has been mainly paid to the problems in which the author himself has been involved. The book as a whole is designed for the reader with knowledge of theoretical physics (especially quantum mechanics) at university level. This book is based on the courses of lectures given at the Chemistry Department of Tel-Aviv University.

The subject of this book emerged from a series of lectures that the author gave at the Department of Physics of the University of North Texas during the 1992 Spring Semester, and reflects the vivacious discussions that he has been having with the students and the co-workers attending this course. The main conclusion of these discussions was that the major tenet of the "conservative" physicists, that classical physics must be recovered from quantum mechanics by adopting the statistical perspective of Gibbs, implying by necessity a Gibbs ensemble of Universes as well as a Gibbs ensemble of observers, is not satisfactory. It is actually as unsatisfactory as the dominant approaches to irreversibility. The book examines the current approaches to irreversibility, in classical and quantum physics, and shows that an objective theory of irreversibility does not exist yet, and that all the current theories of irreversibility share with quantum mechanics elements of subjectivity, making crucial the role played by the observer. In addition to the traditional quantum mechanical paradoxes, concerning the quantum theory of measurement, the book also discusses the new difficulties that the physics of chaos is causing to the widely accepted correspondence principle, and suggests that the Boltzmann dream, the dream that the fracture between dynamics and thermodynamics might be healed, cannot become true within the framework of the current physics, and that the establishment of a new physics is necessary for that ambitious purpose to be achieved.

In Resonances, Instability, and Irreversibility: The LiouvilleSpace Extension of Quantum Mechanics T. Petrosky and I. Prigogine Unstable Systems in Generalized Quantum Theory E. C. G. Sudarshan, Charles B. Chiu, and G. Bhamathi Resonances and Dilatation Analyticity in Liouville Space Erkki J. Brandas Time, Irreversibility, and Unstable Systems in QuantumPhysics E. Eisenberg and L. P. Horwitz Quantum Systems with Diagonal Singularity I. Antoniou and Z. Suchanecki Nonadiabatic Crossing of Decaying Levels V. V. and Vl. V. Kocharovsky and S. Tasaki Can We Observe Microscopic Chaos in the Laboratory? Pierre Gaspard Proton Nonlocality and Decoherence in Condensed Matter --Predictions and Experimental Results C. A. Chatzidimitriou-Dreismann "We are at a most interesting moment in the history of science.Classical science emphasized equilibrium, stability, and timereversibility. Now we see instabilities, fluctuations, evolution onall levels of observations. This change of perspective requires newtools, new concepts. This volume invites the reader not to anenumeration of final achievements of contemporary science, but toan excursion to science in the making." --from the Foreword by I.Prigogine What are the dynamical roots of irreversibility? How can past andfuture be distinguished on the fundamental level of description?Are human beings the children of time --or its progenitors? Inrecent years, a growing number of chemists and physicists haveagreed that the solution to the problem of irreversibility requiresan extension of classical and quantum mechanics. There is, however,no consensus on which direction this extension should take toinclude the dynamical description of irreversible processes. Resonances, Instability, and Irreversibility surveys recentattempts --both direct and indirect --to address the problem ofirreversibility. Internationally recognized researchers report ontheir recent studies, which run the gamut from experimental tohighly mathematical. The subject matter of these papers falls intothree categories: classical systems with emphasis on chaos anddynamical instability, resonances and unstable quantum systems, andthe general problem of irreversibility. Presenting the cutting edge of research into some of the mostcompelling questions that face contemporary chemical physics,Resonances, Instability, and Irreversibility is fascinating readingfor professionals and students in every area of the discipline.

The idea of editing the present volume in the Lecture Notes in Physics series arosewhileorganizingthe“ConferenceonIrreversibleQuantumDynamics”that took place at The Abdus Salam International Center for Theoretical Physics, Trieste, Italy, from July 29 to August 2, 2002. The aim of the Conference was to bring together di?erent groups of - searcherswhoseinterestsandpursuitsinvolveirreversibilityandtimeasymmetry in quantum mechanics. The Conference promoted open and in-depth exchanges of di?erent points of view, concerning both the content and character of qu- tum irreversibility and the methodologies used to study it. The following main themes were addressed: • Theoretical Aspects of Quantum Irreversible Dynamics • Open Quantum Systems and Applications • Foundational Aspects of Irreversible Quantum Dynamics • Asymmetric Time Evolution and Resonances Eachthemewasreviewedbyanexpertinthe?eld,accompaniedbymorespeci?c, research-like shorter talks. The whole topic of quantum irreversibility in all its manifold aspects has always raised a lot of interest, starting with the description of unstable systems in quantum mechanics and the issue of quantum measurement. Further, in - cent years a boost of activity concerning noise, dissipation and open systems has been prompted by the fast developing ?eld of quantum communication and information theory. These considerations motivated the editors to put together a volume that tries to summarize the present day status of the research in the ?eld, with the aim of providing the reader with an accessible and exhaustive introduction to it.

The Sitges International School of Physics is the second one to be held in Spain on the Many Body Problem. The first one took place on Mallorca during the summer 1969. The aim of the school was mainly to direct the interest of professors and students of Spanish Universities tow~rds this concrete field of re search. For this purpose 55 ~specially prepared lectures were given by an eminent collection of lecturers. Besides, a school of this class contri butes to the scientific formation of many students from other countries. Also, in a meeting of this kind, personal contacts are born that favour future co~laboration between scientists. In view of the success of the first two schools, we intend to foster future international meetings on this subject until interest in it is consolidated in Spain. All the lectures given are published here except those of Professor P.C. Martin whose lec tures have previously been published. I would like to thank all those people who helped to make this school a success, and in particular: Prof. J.L. Villar-Palasi, Minister of Educa tion of Spain for sponsoring the school. Dr. R. Diez-Hochleitner, Undersecretary of the Ministry of Education for receiving the project of this school with such enthusiasm. v PREFACE Prof. E.Costa-Novella, Director General of Universities in Spain and Dr. F.Arias-Salgado who showed such interest and patience while assuring the necessary finance would be found for the school.

A dominant feature of our ordinary experience of the world is a sense of irreversible change: things lose form, people grow old, energy dissipates. On the other hand, a major conceptual scheme we use to describe the natural world, molecular dynamics, has reversibility at its core. The need to harmonize conceptual schemes and experience leads to several questions, one of which is the focus of this book. How does irreversibility at the macroscopic level emerge from the reversibility that prevails at the molecular level? Attempts to explain the emergence have emphasized probability, and assigned different probabilities to the forward and reversed directions of processes so that one direction is far more probable than the other. The conclu sion is promising, but the reasons for it have been obscure. In many cases the aim has been to find an explana tion in the nature of probability itself. Reactions to that have been divided: some think the aim is justified while others think it is absurd.

Leading research, perspectives, and analysis of dynamical systems and irreversibility Edited by Nobel Prize winner Ilya Prigogine and renowned authority Stuart A. Rice, the Advances in Chemical Physics series provides a forum for critical, authoritative evaluations in every area of the discipline. In a format that encourages the expression of individual points of view, experts in the field present comprehensive analyses of subjects of interest. Volume 122 collects papers from the XXI Solvay Conference on Physics, dedicated to the exploration of "Dynamical Systems and Irreversibility." Ioannis Antoniou, Deputy Director of the International Solvay Institutes for Physics and Chemistry, edits and assembles this cutting-edge research, including articles such as "Non-Markovian Effects in the Standard Map," "Harmonic Analysis of Unstable Systems," "Age and Age Fluctuations in an Unstable Quantum System," and discussion of many more subjects. Advances in Chemical Physics remains the premier venue for presentations of new findings in its field.

In the book the idea of irreversibility as an inherent property of time is developed theoretically and experimentally. The matter is related with causality, and the method of causal analysis is presented. The quantum causal analysis helps understand the principle of week causality which admits extraction of information from the future without the classical paradoxes. It implies a possibility of observation of the future as the existing reality. So, the acceptance of time irreversibility leads to a striking manifestation of reversibility – signaling in reverse time. Quantum insight allows considering correlations of the distant irreversible processes as nonlocal ones originated from a macroscopic entanglement. The experimental approach to study of macroscopic nonlocality is discussed, and design of the experimental setup is described. The results of experiments on macroscopic nonlocal correlations, the signals in reverse time and their application to the forecast of large-scale random processes are expounded.