Linear Polyurethanes

This volume describes in detail the mechanisms of the diisocyanates and polyols polyaddition process as well as its kinetic and process aspects important for obtaining linear polyurethanes. General kinetics of the process and its experimental verification, using GPC chromatography as well as NMR spectroscopy and MALDI-ToF spectrometry, are presented. Accompanied by over 400 references, the author presents synthesis methods, physicochemical properties of linear polyurethanes (analyzed with DCS, TG, DMTA, Rtg, AFM microscopy methods) as semiproducts for foams, elastomers, lacquers and coatings. Research results concerning free surface energy of the polyurethane coatings are also presented. Special attention is given to the latest polyurethane applications, such as ecological waterborne dispersions, biodegradation resistant elastomers and coatings used as medical implants and binders for ceramic powder materials. Moreover, the book contains information on urethane-isocyanate prepolymers applications, which are potential semifinished products for elastomers, foams, coatings, adhesives and interpenetrating polymer network composites.

Handbook of Polyurethanes serves as the first source of information of useful polymers. This new book thoroughly covers the entire spectrum of polyurethanes - from current technology to buyer's information. Discussions include: block and heteroblock systems rubber plasticity structure-property relations microphase separation catalysis of isocyanate reactions synthesis of polyurethanes for thermoplastics, thermosets, and curable compositions by either heat or U.V. energy biomedical applications of urethane elastomers castables, sealants, and caulking compounds flexible and semi-flexible foams health and safety This handbook compiles data from many sources, exhaustively illustrating the complex principles involved in polyurethane chemistry and technology. Handbook of Polyurethanes represents invaluable information for corporations, universities, or independent inventors.

This volume describes in detail the mechanisms of the diisocyanates and polyols polyaddition process as well as its kinetic and process aspects important for obtaining linear polyurethanes. General kinetics of the process and its experimental verification, using GPC chromatography as well as NMR spectroscopy and MALDI-ToF spectrometry, are presented. Accompanied by over 400 references, the author presents synthesis methods, physicochemical properties of linear polyurethanes (analyzed with DCS, TG, DMTA, Rtg, AFM microscopy methods) as semiproducts for foams, elastomers, lacquers and coatings. Research results concerning free surface energy of the polyurethane coatings are also presented. Special attention is given to the latest polyurethane applications, such as ecological waterborne dispersions, biodegradation resistant elastomers and coatings used as medical implants and binders for ceramic powder materials. Moreover, the book contains information on urethane-isocyanate prepolymers applications, which are potential semifinished products for elastomers, foams, coatings, adhesives and interpenetrating polymer network composites.

Polyurethanes in Biomedical Applications studies the use of polyurethanes in implanted medical devices. This analysis describes the concepts of polymer science, the manufacture of polyurethanes, and the biological responses to implant polyurethanes, reflecting the developments in biomaterials science and the interdisciplinary nature of bioengineering.

This book is a collection of 22 per-reviewed scientific papers on the synthesis and characterization of polyurethanes with special chemical and physical properties. In our "plastic age", polyurethanes are one of the most versatile polymers with broad and excellent mechanical and chemical properties. These polyurethanes can be found in many areas of our every day`s life ranging from insulators through hard and soft foams to various biomedical devices. The huge number of possible variations in the types of reactants allows the scientists to design and tailor the properties of polyurethanes to specific needs. The fascinating chemistry and materials science of polyurethanes have attracted interests of many scientists. As a result, the progress in this field made by these scholars are summarized in this book with special emphasizes on the structure-property relationships and biomedical applications of polyurethanes as well as their environmental aspects are also highlighted in some papers. Thus, this collection of papers is recommended to all readers who are interested not only in the synthesis and properties of polyurethanes but want to be familiar with the theoretical description of their formation as well.

Polyurethanes are formed by reacting a polyol (an alcohol with more than two reactive hydroxyl groups per molecule) with a diisocyanate or a polymeric isocyanate in the presence of suitable catalysts and additives. Because a variety of diisocyanates and a wide range of polyols can be used to produce polyurethane, a broad spectrum of materials can be produced to meet the needs of specific applications. During World War II, a widespread use of polyurethanes was first seen, when they were used as a replacement for rubber, which at that time was expensive and hard to obtain. During the war, other applications were developed, largely involving coatings of different kinds, from airplane finishes to resistant clothing. Subsequent decades saw many further developments and today we are surrounded by polyurethane applications in every aspect of our everyday lives. While polyurethane is a product that most people are not overly familiar with, as it is generally "hidden" behind covers or surfaces made of other materials, it would be hard to imagine life without polyurethanes.

The Polymeric Materials Encyclopedia presents state-of-the-art research and development on the synthesis, properties, and applications of polymeric materials. This groundbreaking work includes the largest number of contributors in the world for a reference publication in polymer science, and examines many fields not covered in any other reference. With multiple articles on many subjects, the encyclopedia offers you a broad-based perspective on a multitude of topics, as well as detailed research information, figures, tables, illustrations, and references. Updates published as new research unfolds will continue to provide you with the latest advances in polymer science, and will keep the encyclopedia at the forefront of the field well into the future. From novices to experienced researchers in the field, anyone and everyone working in polymer science today needs this complete assessment of the state of the art. The entire 12-volume set will be available in your choice of printed or CD-ROM format.