Marine Electrochemistry

A concise introduction to the fundamentals of electrochemical methods and their practical application to environmental and oceanographic studies. All the chapters are written by practitioners with considerable experience in the various techniques both in the laboratory and in the field. Features detailed treatments of the conductometric determination of salinity and the amperometric determination of oxygen; the use of potentiometric sensors both for direct measurement and as end-point detectors in titrimetric procedures; electrodeposition procedures as a versatile and chemically selective means of obtaining uncontaminated samples for analysis by spectroscopic and neutron activation analysis; and voltammetry.

There has long been a need for effective methods of measuring corrosion within light water nuclear reactors. This important volume discusses key issues surrounding the development of high temperature reference electrodes and other electrochemical techniques. The book is divided into three parts with part one reviewing the latest developments in the use of reference electrode technology in both pressurised water and boiling water reactors. Parts two and three cover different types of corrosion and tribocorrosion and ways they can be measured using such techniques as electrochemical impedance spectroscopy. Topics covered across the book include in-pile testing, modelling techniques and the tribocorrosion behaviour of stainless steel under reactor conditions. Electrochemistry in light water reactors is a valuable reference for all those concerned with corrosion problems in this key technology for the power industry. Discusses key issues surrounding the development of high temperature reference eletrodes A valuable reference for all concerned with corrosion problems in this key technology

The new edition of LaQue's classic text on marine corrosion, providing fully updated control engineering practices and applications Extensively updated throughout, the second edition of La Que's Handbook of Marine Corrosion remains the standard single-source reference on the unique nature of seawater as a corrosive environment. Designed to help readers reduce operational and life cycle costs for materials in marine environments, this authoritative resource provides clear guidance on design, materials selection, and implementation of corrosion control engineering practices for materials in atmospheric, immersion, or wetted marine environments. Completely rewritten for the 21st century, this new edition reflects current environmental regulations, best practices, materials, and processes, with special emphasis placed on the engineering, behavior, and practical applications of materials. Divided into three parts, the book first explains the fundamentals of corrosion in marine environments, including atmospheric corrosion, erosion, microbiological corrosion, fatigue, environmental cracking, and cathodic delamination. The second part discusses corrosion control methods and materials selection that can mitigate or eliminate corrosion in different marine environments. The third section provides the reader with specific applications of corrosion engineering to structures, systems, or components that exist in marine environments. This much-needed new edition: Presents a comprehensive and up-to-date account of the science and engineering aspects of marine corrosion Focuses on engineering aspects, descriptive behavior, and practical applications of materials usage in marine environments Addresses the various materials used in marine environments, including metals, polymers, alloys, coatings, and composites Incorporates current regulations, standards, and recommended practices of numerous organizations such as ASTM International, the US Navy, the American Bureau of Shipping, the International Organization for Standardization, and the International Maritime Organization Written in a clear and understandable style, La Que's Handbook of Marine Corrosion, Second Edition is an indispensable resource for engineers and materials scientists in disciplines spanning the naval, maritime, commercial, shipping industries, particularly corrosion engineers, ship designers, naval architects, marine engineers, oceanographers, and other professionals involved with products that operate in marine environments.

Using reference electrodes to monitor the electrochemical potential of steel reinforcement in concrete is a well established technique for assessing the severity of corrosion and for controlling cathodic protection systems. This report gives a state-of-the-art overview of the electrochemical and physical characteristics and performance of embeddable reference electrodes for concrete, and the method used for installing them. The report first reviews electrochemical potential and reference electrodes in general. It then assesses the different types of reference electrodes for concrete. Finally, it considers key issues such as location and quality control which need to be considered when installing reference electrodes in steel-reinforced concrete structures. Provides a state-of-the-art overview of the electrochemical and physical characteristics and performance of embeddable reference electrodes for concrete Considers key issues such as location and quality control

Humankind's use of zinc stretches back to antiquity, and it was a component in some of the earliest known alloy systems. Even though metallic zinc was not "discovered" in Europe until 1746 (by Marggral), zinc ores were used for making brass in biblical times, and an 87% zinc alloy was found in prehistoric ruins in Transylvania. Also, zinc (the metal) was produced in quantity in India as far back as the thirteenth century, well before it was recognized as being a separate element. The uses of zinc are manifold, ranging from galvanizing to die castings to electronics. It is a preferred anode material in high-energy-density batteries (e.g., Ni/Zn, Ag/Zn, ZnJair), so that its electrochemistry, particularly in alkaline media, has been extensively explored. In the passive state, zinc is photoelectrochemically active, with the passive film displaying n-type characteristics. For the same reason that zinc is considered to be an excellent battery anode, it has found extensive use as a sacrificial anode for the protection of ships and pipelines from corrosion. Indeed, aside from zinc's well-known attributes as an alloying element, its widespread use is principally due to its electrochemical properties, which include a well-placed position in the galvanic series for protecting iron and steel in natural aqueous environments and its reversible dissolution behavior in alkaline solutions.

Electrochemistry and Corrosion Science is a graduate level text/professional reference that describes the types of corrosion on metallic materials. The focus will be on modeling and engineering approximation schemes that describe the thermodynamics and kinetics of electrochemical systems. The principles of corrosion behavior and metal recovery are succinctly described with the aid of pictures, figures, graphs and schematic models, followed by derivation of equations to quantify relevant parameters. Example problems are included to illustrate the application of electrochemical concepts and mathematics for solving complex corrosion problems. This book differs from others in that the subject matter is organized around the modeling and predicating approaches that are used to determine detrimental and beneficial electrochemical events. Thus, this book will take a more practical approach and make it especially useful as a basic text and reference for professional engineers.