Materials Science And Engineering Of Carbon

Materials Science and Engineering of Carbon: Characterization discusses 12 characterization techniques, focusing on their application to carbon materials, including X-ray diffraction, X-ray small-angle scattering, transmission electron microscopy, Raman spectroscopy, scanning electron microscopy, image analysis, X-ray photoelectron spectroscopy, magnetoresistance, electrochemical performance, pore structure analysis, thermal analyses, and quantification of functional groups. Each contributor in the book has worked on carbon materials for many years, and their background and experience will provide guidance on the development and research of carbon materials and their further applications. Focuses on characterization techniques for carbon materials Authored by experts who are considered specialists in their respective techniques Presents practical results on various carbon materials, including fault results, which will help readers understand the optimum conditions for the characterization of carbon materials

Carbon materials are exceptionally diverse in their preparation, structure, texture, and applications. In Advanced Materials Science and Engineering of Carbon, noted carbon scientist Michio Inagaki and his coauthors cover the most recent advances in carbon materials, including new techniques and processes, carbon materials synthesis, and up-to-date descriptions of current carbon-based materials, trends and applications. Beginning with the synthesis and preparation of nanocarbons, carbon nanotubes, and graphenes, the book then reviews recently developed carbonization techniques, such as templating, electrospinning, foaming, stress graphitization, and the formation of glass-like carbon. The last third of the book is devoted to applications, featuring coverage of carbon materials for energy storage, electrochemical capacitors, lithium-ion rechargeable batteries, and adsorptive storage of hydrogen and methane for environmental protection, photocatalysis, spilled oil recovery, and nuclear applications of isotropic high-density graphite. A progression from synthesis through modern carbonization techniques to applications gives you a thorough understanding of carbon materials Covers a wide range of precursor materials, preparation techniques, and characteristics to inspire your own development of carbonization techniques, carbon materials and applications Applications-oriented chapters include timely content on hot topics such as the engineering of carbon nanofibers and carbon materials for various energy-related applications

Elemental carbon materials take numerous forms including graphite, carbon fiber, carbon nanotube, graphene, carbon black, activated carbon, fullerene and diamond. These forms differ greatly in the structure, properties, fabrication method, and applications. The applications of these carbon forms include electronic, electromagnetic, electrochemical, environmental and biomedical applications. Carbon materials are a subject of intense research, with strong relevance to both science and technology.This book provides a tutorial-style and up-to-date coverage of the carbon forms. In addition to an introductory chapter on carbon materials, the book includes chapters on graphite, graphene, carbon black, activated carbon, carbon fibers, and carbon nanofibers/nanotubes. For example, the chapter on graphite covers various materials in the graphite family, including polycrystalline graphite, pyrolytic graphite, turbostratic carbon, intercalated graphite, graphite oxide, exfoliated graphite and flexible graphite, in addition to their electronic and mechanical properties.This book is suitable for use as a textbook for undergraduate and graduate students in science and engineering, and as a reference book for professionals. It is dedicated to the memory of the author's PhD thesis advisor, Professor M S Dresselhaus (1930-2017) of Massachusetts Institute of Technology.

Emerging Carbon Materials for Catalysis covers various carbon-based materials with a focus on their utility for catalysis. Each chapter examines the photo and electrocatalytic applications of a material, including hybrid systems composed of carbon materials. The range of chemical reactions that can be catalyzed with each material—as well as the potential drawbacks of each—are discussed. Covering nanostructured systems, as well as other microstructured materials, the book reviews emerging carbon-based structures, including carbon organic frameworks. Written by a global team of experts, this volume is ideal for graduate students and researchers working in organic chemistry, catalysis, nanochemistry, and nanomaterials. Introduces novel and emerging carbon materials with utility for photocatalysis and electrocatalysis Covers a wide range of photochemical and electrochemical processes that can be catalyzed by carbon-based catalysts Addresses the hybrid systems composed of carbon materials for catalysis Serves as an ideal reference for graduate students and researchers working in organic chemistry, catalysis, nanochemistry, and nanomaterials.

The inspiration for this book came from an American Carbon Society Workshop entitled "Carbon Materials for Advanced Technologies" which was hosted by the Oak Ridge National Laboratory in 1994. Chapter 1 contains a review of carbon materials, and emphasizes the structure and chemical bonding in the various forms of carbon, including the four allotropes diamond, graphite, carbynes, and the fullerenes. In addition, amorphous carbon and diamond films, carbon nanoparticles, and engineered carbons are discussed. The most recently discovered allotrope of carbon, i.e., the fullerenes, along with carbon nanotubes, are more fully discussed in Chapter 2, where their structure-property relations are reviewed in the context of advanced technologies for carbon based materials. The synthesis, structure, and properties of the fullerenes and nanotubes, and modification of the structure and properties through doping, are also reviewed. Potential applications of this new family of carbon materials are considered. The manufacture and applications of adsorbent carbon fibers are discussed in Chapter 3. The manufacture, structure and properties of high performance fibers are reviewed in Chapter 4, and the manufacture and properties of vapor grown fibers and their composites are reported in Chapter 5. The properties and applications of novel low density composites developed at Oak Ridge National Laboratory are reported in Chapter 6. Coal is an important source of energy and an abundant source of carbon. The production of engineering carbons and graphite from coal via a solvent extraction route is described in Chapter 7. Applications of activated carbons are discussed in Chapters 8-10, including their use in the automotive arena as evaporative loss emission traps (Chapter 8), and in vehicle natural gas storage tanks (Chapter 9). The application of activated carbons in adsorption heat pumps and refrigerators is discussed in Chapter 10. Chapter 11 reports the use of carbon materials in the fast growing consumer electronics application of lithium-ion batteries. The role of carbon materials in nuclear systems is discussed in Chapters 12 and 13, where fusion device and fission reactor applications, respectively, are reviewed. In Chapter 12 the major technological issues for the utilization of carbon as a plasma facing material are discussed in the context of current and future fusion tokamak devices. The essential design features of graphite moderated reactors, (including gas-, water- and molten salt-cooled systems) are reviewed in Chapter 13, and reactor environmental effects such as radiation damage and radiolytic corrosion are discussed. The fracture behaviour of graphite is discussed in qualitative and quantitative terms in Chapter 14. The applications of Linear Elastic Fracture Mechanics and Elastic-Plastic Fracture Mechanics to graphite are reviewed and a study of the role of small flaws in nuclear graphites is reported.

The major areas of carbon-carbon materials and composites are described in this comprehensive volume. It presents data and technology on the materials and structures developed for the production of carbon-carbon materials and composites. The text is composed of papers by 13 noted authors in their areas of expertise relating to the processes and production of these material systems and structures. The subject matter in the book is arranged to lead the reader through materials processing, fabrication, structural analysis, and applications of typical carbon-carbon products. The information provided includes: fiber technology, matrix material, design of composite structures, manufacturing techniques, engineering mechanics, protective coatings, and structural applications using carbon-carbon materials and composites.

The discovery of fullerenes and nanotubes has greatly stimulated the interest of scientists and engineers in carbon materials, and has resulted in much scientific research. These materials have provided us with many interesting ideas and potential applications, some of them practical and some simply dreams for the future. In the early 1960s, carbon fibers, glass-like carbons and pyrolytic carbons were developed which were quite different from the carbon materials that had previously been used. Carbon fibers exhibited surprisingly good mechanical properties, glass-like carbons exhibited brittle fracture resulting in a conchoidal fracture surface similar to sodium glass, and giving no carbon dust, and pyrolytic carbons were produced by a new production process of chemical vapour deposition and showed very high anisotropy. These carbons materials made a great impact not only on the carbon community who had been working on carbon materials but also on people working in the fields of materials science and engineering. They were used to develop a variety of new applications in technological fields, such as semiconductors, microelectronics, aerospace and high temperature, etc. These newly developed carbon materials were called NEW CARBONS, in comparison with carbon materials such as artificial graphites represented by graphite electrodes, carbon blacks and activated carbons, which maybe thought of as CLASSICAL CARBONS. Later, other new carbons, such as activated carbons and those with novel functions, isotropic high-density graphites, intercalation compounds, various composites, etc., were developed. In 1994, Professor Michio Inagaki published a book entitled "New Carbon Materials — Structure and Functions" with his friend Professor Yoshihiro Hishiyama of Musashi Institute of Technology, published by Gihoudou Shuppan in Japanese. However, progress in the fields of these new carbons is so rapid that the previous book is already out of date. For this reason the author has decided to write an English text on New Carbons. The text focuses on New Carbons based on hexagonal networks of carbon-atoms, i.e. graphite-related materials. The fundamental concept underlying this book is that the structure and functions of these materials are principally governed by their texture. The aim is to give readers a comprehensive understanding of New Carbons through the description of their structure and texture, along with the properties that are largely dependent on them.