Membrane Separation Processes

Membrane Separation Processes: Theories, Problems, and Solutions provides graduate and senior undergraduate students and membrane researchers in academia and industry with the fundamental knowledge on the topic by explaining the underlying theory that is indispensable for solving problems that occur in membrane separation processes. All major membrane processes are discussed, and an economic analysis is provided. Separation processes such as RO, UF, MF, RO, PRO and MD are thoroughly discussed. During the last two decades, the scope of the R&D of membrane separation processes has been significantly broadened. Other sections in the book cover membrane contactor and membrane adsorption. In addition, hybrid systems in which two or more membrane systems are combined are now being investigated for large-scale applications. Written by renowned experts with extensive experience with industry, education and R&D who have complementary expertise In-depth coverage of the most important conventional and emerging membrane processes Provides fundamental membrane theories for solving problems in separation processes without using complicated software

Synthetic Membranes and Membrane Separation Processes addresses both fundamental and practical aspects of the subject. Topics discussed in the book cover major industrial membrane separation processes, including reverse osmosis, ultrafiltration, microfiltration, membrane gas and vapor separation, and pervaporation. Membrane materials, membrane preparation, membrane structure, membrane transport, membrane module and separation design, and applications are discussed for each separation process. Many problem-solving examples are included to help readers understand the fundamental concepts of the theory behind the processes. The book will benefit practitioners and students in chemical engineering, environmental engineering, and materials science.

This concise and systematically organized text, now in its second edition, gives a clear insight into various membrane separation processes. It covers the fundamentals as well as the recent developments of different processes along with their industrial applications and the products. It includes the basic principles, operating parameters, membrane hardware, flux equation, transport mechanism, and applications of membrane-based technologies. Membrane separation processes are largely rate-controlled separations which require rate analysis for complete understanding. Moreover, a higher level of mathematical analysis, along with the understanding of mass transfer, is also required. These are amply treated in different chapters of the book to make the students comprehend the membrane separation principles with ease. This textbook is primarily designed for undergraduate students of chemical engineering, biochemical engineering and biotechnology for the course in membrane separation processes. Besides, the book will also be useful to process engineers and researchers. KEY FEATURES • Provides sufficient number of examples of industrial applications related to chemical, metallurgical, biochemical and food processing industries. • Focuses on important biomedical applications of membrane-based technologies such as blood oxygenator, controlled drug delivery, plasmapheresis, and bioartificial organs. • Includes chapter-end short questions and problems to test students’ comprehension of the subject. NEW TO THIS EDITION • A new section on membrane cleaning is included. Membrane fabrication methods are supplemented with additional information (Chapter 2). • Additional information on silt density index, forward osmosis and sea water desalination (Chapter 3). • Physicochemical parameters affecting nanofiltration, determination of various resistances using resistance in series model and few more industrial applications with additional short questions (Chapter 4). • Membrane cross-linking methods used in pervaporation, factors affecting pervaporation and few more applications (Chapter 9). • Membrane distillation, membrane reactor with different modules, types of membranes and reactions for membrane reactor (Chapter 13).

Today, membranes and membrane processes are used as efficient tools for the separation of liquid mixtures or gases in the chemical and biomedical industry, in water desalination and wastewater purification. Despite the fact that various membrane processes, like reverse osmosis, are described in great detail in a number of books, processes involving ion-exchange membranes are only described in a fragmented way in scientific journals and patents; even though large industrial applications, like electrodialysis, have been around for over half a century. Therefore, this book is emphasizing on the most relevant aspects of ion-exchange membranes. This book provides a comprehensive overview of ion-exchange membrane separation processes covering the fundamentals as well as recent developments of the different products and processes and their applications. The audience for this book is heterogeneous, as it includes plant managers and process engineers as well as research scientists and graduate students. The separate chapters are based on different topics. The first chapter describes the relevant Electromembrane processes in a general overview. The second chapter explains thermodynamic and physicochemical fundamentals. The third chapter gives information about ion-exchange membrane preparation techniques, while the fourth and fifth chapter discusses the processes as unit operations giving examples for the design of specific plants. First work on the principles and applications of electrodialysis and related separation processes Presently no other comprehensive work that can serve as both reference work and text book is available Book is suited for teaching students and as source for detailed information

The present book contains a comparison of existing theoretical models developed in order to describe membrane separation processes. In general, the permeation equations resulting from these models give inaccurate predictions of the mutual effects of the permeants involved, due to the simplifications adopted in their derivation. It is concluded that an optimum description of transport phenomena in tight (diffusion-type) membranes is achieved with the "solution-diffusion" model. According to this model each component of a fluid mixture to be separated dissolves in the membrane and passes through by diffusion in response to its gradient in the chemical potential. A modified Flory-Huggins equation has been derived to calculate the solubility of the permeants in the membrane material. Contrary to the original Flory-Huggins equation, the modified equation accounts for the large effect on solubility of crystallinity and elastic strain of the polymer chains by swelling. The equilibrium sorption of liquids computed with this equation was found to be in good agreement with experimental results. Also, the sorption of gases in both rubbery and glassy polymers could be described quan titatively with the modified Flory-Huggins equation without any need of the arbitrary Langmuir term, as required in the conventional "dual-mode" sorption model. Furthermore, fewer parameters are required than with the at least identical accuracy.

Membrane science and technology is an expanding field and has become a prominent part of many activities within the process industries. It is relatively easy to identify the success stories of membranes such as desali nation and microfiltration and to refer to others as developing areas. This, however, does not do justice to the wide field of separations in which membranes are used. No other 'single' process offers the same potential and versatility as that of membranes. The word separation classically conjures up a model of removing one component or species from a second component, for example a mass transfer process such as distillation. In the field of synthetic membranes, the terminology 'separation' is used in a wider context. A range of separations of the chemical/mass transfer type have developed around the use of membranes including distillation, extraction, absorption, adsorption and stripping, as well as separations of the physical type such as filtration. Synthetic membranes are an integral part of devices for analysis, energy generation and reactors (cells) in the electrochemical industry.

Thermal Induced Membrane Separation Processes describes the fundamental and advanced areas associated with the field of thermal induced membrane separation processes. It includes extensive coverage of material selection, types, and theory of thermal induced membrane fabrication, characterization, and modification. This book focuses on the applications of various thermal induced membrane processes and discusses ancillary topics related to the subject, such as membrane modules, membrane contactors and reactors, preparation and characterization techniques, smart membranes, fouling and its mitigation, and economic analysis of the thermal induced membrane separation processes. Thermal Induced Membrane Separation Processes elaborates on every aspect on the thermal induced membranes in a simple and straightforward manner, helping readers ranging from students to researchers in academia and the industry to understand the processes for successful execution and implementation into their research. Covers entire field of thermal induced membranes, providing basic to advanced knowledge of thermal induced membranes in a single source Presents state-of-art research in the field Includes the most up-to-date examples of the fabrication, modification, and applications of thermal induced membranes

The chapters of this book are based upon lectures presented at the NATO Advanced Study Institute on Membrane Processes in Separation and Purification (March 21 - April 2, 1993, Curia, Portugal), organized as a successor and update to a similar Institute that took place 10 years ago (p.M.Bungay, H.K. Lonsdale, M.N. de Pinho (Eds.): Synthetic Membranes: Science, Engineering and Applications, NATO ASI Series, Reidel, Dordrecht, 1986). The decade between the two NATO Institutes witnesses the transition from individually researched membrane processes to an applied and established membrane separation technology, as is reflected by the contents of the corresponding proceeding volumes. By and large, the first volume presents itself as a textbook on membrane processes, still valid, while the present volume focuses on areas of separation need as amenable to membrane processing: Biotechnology and Environmental Technology. Accordingly, the contributions to this volume are grouped into "Membranes in Biotechnology" (11 papers), "Membranes in Environmental Technology" (6 papers), and "New Concepts" (4 papers). This is followed by one contribution each on "Energy Requirements" and "Education", i.e., membrane processes within an academic curriculum. The book thus amounts to a state of the art of applied membrane processing and may well augment the more fundamental approach of its predecessor.