Metal Organic Frameworks Mofs For Environmental Applications

Metal-Organic Frameworks for Environmental Applications examines this important topic, looking at potential materials and methods for the remediation of pressing pollution issues, such as heavy-metal contaminants in water streams, radioactive waste disposal, marine oil-spillage, the treatment of textile and dye industry effluents, the clean-up of trace amounts of explosives in land and water, and many other topics. This survey of the cutting-edge research and technology of MOFs is an invaluable resource for researchers working in inorganic chemistry and materials science, but it is also ideal for graduate students studying MOFs and their applications. Examines the applications of metal-organic frameworks for the remediation of environmental pollutants Features leading experts who research the applications of MOFs from around the world, including contributions from the United States, India and China Explores possible solutions to some of today’s most pressing environmental challenges, such as heavy-metal contamination in bodies of water, oil spills and clean-up of explosives hidden in land and water Provides an excellent reference for researchers and graduate students studying in the areas of inorganic chemistry, materials chemistry and environmental science

This book joins an international and interdisciplinary group of leading experts on the biomedical, energy and environmental applications of Metal-Organic Frameworks (MOFs). The resulting overview covers everything from the environmentally friendly and scale up synthesis of MOFs, their application in green energy generation and storage, and water purification to their use as drug delivery systems, biosensors, and their association with relevant macromolecules (genes, enzymes). This book is focused on the interest of MOFs in applications such as the leading –edge environmental (energy-related) and biomedical fields. The potential of MOFs in these areas is currently progressing at a fast pace, since the wide possibilities that MOFs offer in terms of composition, topology, incorporation of active species (in their porosity, on their external surface or within the framework), and post-synthetic modifications, among others. The aim here is to provide future research goals that emphasize relevant nuances to this class of materials as a whole.

Metal–organic frameworks (MOFs) are porous crystalline polymers con­structed by metal sites and organic building blocks. Since the discovery of MOFs in the 1990s, they have received tremendous research attention for various applications due to their high surface area, controllable mor­phology, tunable chemical properties, and multifunctionalities, including MOFs as precursors and self-sacrificing templates for synthesizing metal oxides, heteroatom-doped carbons, metal-atoms encapsulated carbons, and others. Thus, awareness and knowledge about MOFs and their derived nanomaterials with conceptual understanding are essential for the advanced material community. This breakthrough new volume aims to explore down-to-earth applications in fields such as bio­medical, environmental, energy, and electronics. This book provides an overview of the structural and fundamental properties, synthesis strate­gies, and versatile applications of MOFs and their derived nanomaterials. It gives an updated and comprehensive account of the research in the field of MOFs and their derived nanomaterials. Whether as a reference for industry professionals and nanotechnologists or for use in the classroom for graduate and postgraduate students, faculty members, and research and development specialists working in the area of inorganic chemistry, materials science, and chemical engineering, this is a must-have for any library.

A comprehensive volume on photocatalytic functional materials for environmental remediation As the need for removing large amounts of pollution and contamination in air, soil, and water grows, emerging technologies in the field of environmental remediation are of increasing importance. The use of photocatalysis—a green technology with enormous potential to resolve the issues related to environmental pollution—breaks down toxic organic compounds to mineralized products such as carbon dioxide and water. Due to their high performance, ease of fabrication, long-term stability, and low manufacturing costs, photofunctional materials constructed from nanocomposite materials hold great potential for environmental remediation. Photocatalytic Functional Materials for Environmental Remediation examines the development of high performance photofunctional materials for the treatment of environmental pollutants. This timely volume assembles and reviews a broad range of ideas from leading experts in fields of chemistry, physics, nanotechnology, materials science, and engineering. Precise, up-to-date chapters cover both the fundamentals and applications of photocatalytic functional materials. Semiconductor-metal nanocomposites, layered double hydroxides, metal-organic frameworks, polymer nanocomposites, and other photofunctional materials are examined in applications such as carbon dioxide reduction and organic pollutant degradation. Providing interdisciplinary focus to green technology materials for the treatment of environmental pollutants, this important work: Provides comprehensive coverage of various photocatalytic materials for environmental remediation useful for researchers and developers Encompasses both fundamental concepts and applied technology in the field Focuses on novel design and application of photocatalytic materials used for the removal of environmental contaminates and pollution Offers in-depth examination of highly topical green-technology solutions Presents an interdisciplinary approach to environmental remediation Photocatalytic Functional Materials for Environmental Remediation is a vital resource for researchers, engineers, and graduate students in the multi-disciplinary areas of chemistry, physics, nanotechnology, environmental science, materials science, and engineering related to photocatalytic environmental remediation.

Metal-organic frameworks (MOFs) are some of the most discussed materials of the last decade. Their extraordinary porosity and functionality from metals and organic linkers make them one of the most promising materials for a vast array of applications. The easy tunability of their pore size and shape from the micro- to meso-scale by changing the connectivity of the inorganic moiety and the nature of the organic linkers makes these materials special. Moreover, by combining with other suitable materials, the properties of MOFs can be improved further for enhanced functionality/stability, ease of preparation, and selectivity of operation. Emerging Applications and Implementations of Metal-Organic Frameworks combines the latest empirical research findings with relevant theoretical frameworks in this area in order to improve the reader’s understanding of MOFs and their different applications in areas that include drug delivery, heavy metal removal from water, and gas storage. The design and synthesis of MOFs are also investigated along with the preparation of composites of MOFs. While covering applications that include water defluoridation, rechargeable batteries, and pharmaceutically adapted drug delivery systems, the book’s target audience is comprised of professionals, researchers, academicians, and students working in the field of physical and polymer chemistry, physics, engineering science, and environmental science.

Metal–organic frameworks are among the most promising novel materials. The concept of MOFs was first introduced in 1990. They were actually initially used in catalysis, gas separation, membranes, electrochemical sensors. Later on, they were introduced as SPE sorbents for PAHs (Polycyclic Aromatic Hydrocarbons) in environmental water samples, then the range expanded to the field of analytical chemistry, both in chromatographic separation and sample preparation, with great success in, e.g., SPE and SPME (Solid Phase Mico-extraction). Since then, the number of analytical applications implementing MOFs as sorbents in sorptive sample preparation approaches is increasing. Τhis is reinforced by the fact that, at least theoretically, an infinite number of structures can be designed and synthesized, thus making tuneability one of the most unique characteristics of MOF materials. Moreover, they have been designed in various shapes, such as columns, fibers, and films, so that they can meet more analytical challenges with improved analytical features.Their exceptional properties attracted the interest of analytical chemists who have taken advantage of the unique structures and properties and have already introduced them in several sample pretreatment techniques, such as solid phase extraction, dispersive SPE, magnetic solid phase extraction, solid phase microextraction, stir bar sorptive extraction, etc.