Metal To Nonmetal Transitions

Material undergoes the transformation from metal to non-metal or from non-metal to metal when environmental conditions, such as temperature and pressure, or the percentages of constituent components are changed. Such a transition is known as the metal-nonmetal (M-NM) transition. This book, 'The Physics of Metal – Nonmetal Transitions', explores the mechanisms so far discovered which cause the M-NM transition and presents a systematic discussion of them. All the mechanisms are discussed in terms of energy bands, and the band theory is introduced and explained in chapter 2. Once chapters 1 and 2 have been assimilated, the remaining chapters can be read independently of each other if required. The mechanisms discussed therein include the Peierls transition, the Bloch-Wilson transitions – types I and II respectively – the second of which was discovered by the author and her students. Subsequent chapters cover the Anderson transition and the Mott transition, and each chapter includes not only traditional theories, but also updated information about more recent research. The book can be used either as a textbook for undergraduate and postgraduate students of science and technology or as an introductory treatise for researchers in a wide variety of fields.

Metal-to-Nonmetal Transitions presents the current research in the field from both physical and chemical perspectives. Discussions of the macroscopic, microscopic and quantum aspects of these transitions make this a useful reference for researchers and students.

This book is devoted to nonmetal-to-metal transitions. The original ideas of Mott for such a transition in solids have been adapted to describe a broad variety of phenomena in condensed matter physics (solids, liquids, and fluids), in plasma and cluster physics, as well as in nuclear physics (nuclear matter and quark-gluon systems). The book gives a comprehensive overview of theoretical methods and experimental results of the current research on the Mott effect for this wide spectrum of topics. The fundamental problem is the transition from localized to delocalized states which describes the nonmetal-to-metal transition in these diverse systems. Based on the ideas of Mott, Hubbard, Anderson as well as Landau and Zeldovich, internationally respected scientists present the scientific challenges and highlight the enormous progress which has been achieved over the last years. The level of description is aimed to specialists in these fields as well as to young scientists who will get an overview for their own work. A common feature of all contribution is the extensive discussion of "bound states", i.e. their formation and dissolution due to medium effects. This applies to atoms and molecules in plasmas, fluids, and small clusters, excitons in semiconductors, or nucleons, deuterons, and alpha-particles in nuclear matter. In this way, the transition from delocalized to localized states and vice versa can be described on a common level.

This text surveys the various aspects of the fundamental problem related to the metallic and non-metallic states of matter, a question physicists have been studying for almost 100 years. The book poses questions and challenges in this area, as well as highlighting present understandings of the topic. Topics covered by the book include physics of dense ionized metal plasmas; metallic hydrogen; pressure-induced metallization; the M-I transition in doped semiconductors; transport studies in doped semiconductors near the metal-insulator transition; new results in old oxides; metal-insulator transition in 3d transition metal perovskite oxides investigated by high-energy spectroscopies; alkali metal-alkali halide melts; hopping conductivity in granular metals revisited; superconductor-insulator transition in cuprates; molecular metals and superconductors; shear induced chemical reactivity; shear, co-ordination and metallization; quantum diffusion and decoherence; the Mott transition; recent results, more and surprises; Mott-Hubbard-Anderson models.

This text surveys the various aspects of the fundamental problem related to the metallic and non-metallic states of matter, a question physicists have been studying for almost 100 years. The book poses questions and challenges in this area, as well as highlighting present understandings of the topic. Topics covered by the book include physics of dense ionized metal plasmas; metallic hydrogen; pressure-induced metallization; the M-I transition in doped semiconductors; transport studies in doped semiconductors near the metal-insulator transition; new results in old oxides; metal-insulator transition in 3d transition metal perovskite oxides investigated by high-energy spectroscopies; alkali metal-alkali halide melts; hopping conductivity in granular metals revisited; superconductor-insulator transition in cuprates; molecular metals and superconductors; shear induced chemical reactivity; shear, co-ordination and metallization; quantum diffusion and decoherence; the Mott transition; recent results, more and surprises; Mott-Hubbard-Anderson models.

This volume and its two companion volumes, entitled Tetrahedrally-Bonded Amorphous Semiconductors and Physics of Disordered Materials, are our way of paying special tribute to Sir Nevill Mott and to express our heartfelt wishes to him on the occasion of his eightieth birthday. Sir Nevill has set the highest standards as a physicist, teacher, and scientific leader. Our feelings for him include not only the respect and admiration due a great scientist, but also a deep affection for a great human being, who possesses a rare combination of outstanding personal qualities. We thank him for enriching our lives, and we shall forever carry cherished memories of this noble man. Scientists best express their thanks by contributing their thoughts and observations to a Festschrift. This one honoring Sir Nevill fills three volumes, with literally hundreds of authors meeting a strict deadline. The fact that contributions poured in from all parts of the world attests to the international cohesion of our scientific community. It is a tribute to Sir Nevill's stand for peace and understanding, transcending national borders. The editors wish to express their gratitude to Ghazaleh Koefod for her diligence and expertise in deciphering and typing many of the papers, as well as helping in numerous other ways. The blame for the errors that remain belongs to the editors.

Refractory Materials, Volume 7: Transition Metal Carbides and Nitrides discusses the developments in transition metal carbide and nitride research. This volume is organized into nine chapters that emphasize the mechanical and superconducting properties of these compounds. The introductory chapters deal with the general properties, preparation techniques, characterization, crystal chemistry, phase relationships, and thermodynamics of transition metal carbides and nitrides. The following chapter highlights the mechanical properties of these compounds, such as elastic and plastic deformation, fracture, strengthening mechanisms, and hardness. The discussion then shifts to specific electrical and magnetic properties, including electrical resistivity, Hall coefficient, and magnetic susceptibility. A separate chapter is devoted to carbides and nitrides as superconductors. The concluding chapters explore certain theories that explain the mechanisms of band structure and bonding in carbides and nitrides. This volume is of great value to research workers in metallurgy, ceramics, physics, chemistry, and related fields, as well as to advanced students investigating problems concerning high temperature materials or interstitial compounds.

Ionic liquids have attracted considerable interest in recent years. In this book the bulk and interfacial physico-chemical characteristics of various fluid systems dominated by Coulomb interactions are treated which includes molten salts, ionic liquids as well as metal-molten salt mixtures and expanded fluid metals. Of particular interest is the comparison of the different systems. Topics in the bulk phase concern the microscopic structure, the phase behaviour and critical phenomena, and the metal-nonmetal transition. Interfacial phenomena include wetting transitions, electrowetting, surface freezing, and the electrified ionic liquid/ electrode interface. With regard to the latter 2D and 3D electrochemical phase formation of metals and semi-conductors on the nanometer scale is described for a number of selected examples. The basic concepts and various experimental methods are introduced making the book suitable for both graduate students and researchers interested in Coulombic fluids.