Methods Of Making Polymer Blend Compositions

This book with software provides powerful tools for the analysis, prediction and creation of new polymer blends, an area of significant commercial potential. The R&D approaches and methods described in the book have attracted the interest of polymer R&D leaders in industry, and have been put into use in several major chemical companies. The companion set of computer programs speeds and facilitates work in this area. FROM THE AUTHORS' PREFACE: During the 1980's a steadily increasing number of compatible systems [polymer blends] have been reported. We believe that miscible mixtures will prove to be fairly common and the purpose of this book is to explore the circumstances in which single phase materials can be obtained. We will also describe a model for the phase behavior of these mixtures which we believe to have a predictive value, or be used as a practical guide to polymer miscibility. Our approach is based on the use of association models which have until recently been largely ignored in treating hydrogen bonding in polymer mixtures. They have most frequently been applied to mixtures of alcohols with simple hydrocarbons, where the equilibrium constants used to describe association have most frequently been determined by a fit to thermodynamic data (e.g., vapor pressures, heat of mixing). In our work we have sought to, first, adapt this approach to a description of the phase behavior of polymer mixtures; second, develop spectroscopic methods that provide an independent measurement of the equilibrium constants. Our purpose in this book is to explore and describe this approach and illustrate its broad utility. We address two overlapping yet different audiences. One would be primarily interested in the broad nature of this approach and the practical applications of a simple model. The second would be more interested in the derivations of the equations and some of the fundamental aspects of the spectroscopy of these systems. Accor

It has been well-recognized that polymer blends offer a key option in solving emerging application requirements. The ability to combine existing polymers into new compositions with commercializable properties offers the advantage of reduced research and development expense compared to the development of new monomers and polymers to yield a similar property profile. An additional advantage is the much lower capital expense involved with scale-up and commercialization. Another specific advantage of polymer blends versus new monomer/polymer compositions is that blends often offer property profile combinations not easily obtained with new polymeric structures. In the rapidly emerging technology landscape, polymer blend technology can quickly respond to developing needs. This book offers a comprehensive overview of this important field, in particular a unique and extensive literature research on all aspects of this technology. It can be utilized as a reference text as well as a textbook for a graduate level course on polymer blends.

Multicomponent polymeric systems, or polymeric blends, have recently created considerable interest and they represent a new and important challenge for research. These systems have already become technologically important, but the prospects for their applications have by no means been exhausted. For thermodynamic reasons polymer blends do not usually form homogeneous mixtures but exhibit micro or macrophase separation. This incompatibility has some inherent advantages as varying the composition and the processing conditions, materials with different structures and morphologies can be obtained whose properties may be superior to those of one of the components e. g. high impact resistant plastics. Investigations of multicomponent polymer systems constitute a new branch of macromolecular science which now claims as much interest as the behaviour of dilute solutions, crystallization, statistics of chain~~ tacticity, and single crystal formation did a few years ago. The complexity of the problems related to control led preparation and properties studies of mUlticomponent polymer systems is such that it is often more practicable to conduct them on an international basis. The aim of the first Joint Italian-Polish Seminar on Multicomponent Polymer Systems was to discuss recent results obtained in that field in both countries. As the range of topics to be covered was fairly wide, we thought it advisable to invite scientists from other countries to share with us some aspects of their own studies.

This book is a comprehensive introduction to "green" or environmentally friendly polymer composites developed using renewable polymers of natural origin such as starch, lignin, cellulose acetate, poly-lactic acid (PLA), polyhydroxylalkanoates (PHA), polyhydroxylbutyrate (PHB), etc., and the development of modern technologies for preparing green composites with various applications. The book also discusses major applications of green polymer composites in industries such as medicine, biotechnology, fine chemicals and engineering.

Biopolymers and biodegradable plastics are finding new applications in various sectors, from packaging, to medical, automotive and many more. As synthetic plastics are increasingly replaced by their bioplastic equivalents, engineers are facing new challenges including processing, costs, environmental sustainability and – ultimately – developing successful products. Biopolymers: Processing and Products, the second book of a trilogy dedicated to biopolymers, gives a detailed insight into all aspects of processing, seamlessly linking the science of biopolymers to the latest trends in the development of new products. Processes covered in the book include blending, compounding, treatment, and shaping, as well as the formation of biocomposites. Biopolymer coatings and adhesives are also investigated. This book unique in its coverage contains information retrieved mainly from patents, which form the bulk of the book. The coverage of processing will help engineers and designers to improve output and efficiency of every stage of the product development process, and will form an indispensable tool in selecting the right biopolymer and processing technique for any given application, covering medical, automotive, food packaging and more. It will assist also engineers, material scientists and researchers to improve existing biopolymer processes and deliver better products at lower cost. Multi-disciplinary approach and critical presentation of all available processing techniques and new products of biopolymers Contains information not to be found in any other book Self-contained chapters

The market is continuously looking for substitutes for expensive polymers or tailor made polymers for specific applications. Therefore, polymer blends are gaining more interest since they possess a great potential to fulfill these needs. Blending not only results in better final properties, but can also improve the processing behavior and reduce costs. In the field of polymer blends, there are numerous parameters that influence the morphology, e.g., viscosity ratio, blend composition, shear conditions, and blend ratio. There is still a great deal of potential to scientifically exploit the possibilities of blend technology, which is necessary to obtain a foundation based on science, engineering, technology, and applications in order to make it possible to tailor polymer blends as desired.However, combining two or more different polymers to receive favorable properties by blending often results in immiscible polymer blends. This immiscibility goes hand-in-hand with phase separation leading to weak mechanical properties. The high interfacial tension causing this can be reduced by compatibilization of polymer blends. There are different methods to achieve this, such as adding block and graft copolymers, reactive polymers to form block and graft copolymers, nanoparticles or organic molecules. Using suitable compatibilizers, not only is the interfacial adhesion between matrix and its blends reduced, but also the dispersion of the dispersed phase is improved, the adhesion between the phases is enhanced and the morphology is stabilized. This can lead to improved mechanical and morphological properties.Designing new polymer blends or improving the properties of immiscible polymer blends by compatibilization is very challenging, but an excellent way to exploit the full potential of polymers for applications and their varied needs.This Special Issue is a source of information on all recent aspects of polymer blend technology.

Written by an international group of highly respected contributors, this fundamental reference work covers all aspects of polymer blends: science, engineering, technology and applications.