Modelling Aqueous Corrosion

All significant studies agree that aqueous corrosion continues to cost nations dearly in almost every area of technological endeavour. Over the past ten years, microcomputers have facilitated an explosion in the power of modelling as a technique in science and engineering. In corrosion they have enabled better understanding of polarization curves, they have transformed the scope of electrochemical impedance measurements and they have placed a large range of electrochemistry at the fingertips of the corrosion scientist. This book focuses on the models, rather than the computing, which have been made possible during the past decade. Aimed at all those with an interest in corrosion and its control, the book draws together the range of new modelling strands, suggests new avenues of approach and generates further momentum for improvements to corrosion management, whether by increased understanding of atomistic processes or by control of large plant.

Corrosion Modelling with Cellular Automata bridges the gap between finer scales based on atomic physics and the larger-scale based on physico-chemical properties of materials and their environments. The book describes the simulation and modeling of corrosion phenomena by cellular automata and underlines the collaborative and interdisciplinary relationships that underpin them. It explores the major achievements that have been performed to date, covers basic knowledge on cellular automata and corrosion phenomena, and includes sections on CA modeling of generalized and uniform corrosion in 2D and 3D under various conditions, including aqueous environments and high temperature processes. Finals sections present examples on the use of cellular automata for modeling localized corrosion as well as recent developments on intergranular corrosion. There is also a review on the use of CA for modeling pitting corrosion. Focuses on the use of cellular automata for modeling corrosion Covers recent advances in modeling generalized corrosion with cellular automata Illustrates how cellular automata can be used to model localized corrosion (pitting and intergranular corrosion) Spans various length scales from atomistic to mesoscale

Presents opportunities for making significant improvements in preventing harmful effects that can be caused by corrosion Describes concepts of molecular modeling in the context of materials corrosion Includes recent examples of applications of molecular modeling to corrosion phenomena throughout the text Details how molecular modeling can give insights into the multitude of interconnected and complex processes that comprise the corrosion of metals Covered applications include diffusion and electron transfer at metal/electrolyte interfaces, Monte Carlo simulations of corrosion, corrosion inhibition, interrogating surface chemistry, and properties of passive films Presents current challenges and likely developments in this field for the future

Corrosion in nuclear power plants cause reductions in efficiency and increases in deposit build-up on plant surfaces, making for expensive maintentance and potential radiological health hazards. This book guides studies to predict and minimize corrosion, thus making nuclear power safer and more cost effective. Too often, reliance on empirical models and on-site testing of existing plants makes study and prediction of corrosive effects in nuclear reactors into a pricey and lengthy process. Introducing the experimental procedures, set up, sample preparation and computer modeling suggested in this book will save precious time and resources in a field where the significant time and expense to get and keep plants on-line are two of the chief concerns preventing broader commerical viability. * The only book to focus exclusively on preventing nuclear corrosion * Uses computer modelling to tie together chemical engineering, civil engineering, corrosion science, and nuclear engineering into a cohesive solution to a vexing nucelar problem * Includes all fundamental equations, example data sets and experimental techniques

Corrosion of nuclear materials, i.e. the interaction between these materials and their environments, is a major issue for plant safety as well as for operation and economic competitiveness. Understanding these corrosion mechanisms, the systems and materials they affect, and the methods to accurately measure their incidence is of critical importance to the nuclear industry. Combining assessment techniques and analytical models into this understanding allows operators to predict the service life of corrosion-affected nuclear plant materials, and to apply the most appropriate maintenance and mitigation options to ensure safe long term operation. This book critically reviews the fundamental corrosion mechanisms that affect nuclear power plants and facilities. Initial sections introduce the complex field of nuclear corrosion science, with detailed chapters on the different types of both aqueous and non aqueous corrosion mechanisms and the nuclear materials susceptible to attack from them. This is complemented by reviews of monitoring and control methodologies, as well as modelling and lifetime prediction approaches. Given that corrosion is an applied science, the final sections review corrosion issues across the range of current and next-generation nuclear reactors, and across such nuclear applications as fuel reprocessing facilities, radioactive waste storage and geological disposal systems. With its distinguished editor and international team of expert contributors, Nuclear corrosion science and engineering is an invaluable reference for nuclear metallurgists, materials scientists and engineers, as well as nuclear facility operators, regulators and consultants, and researchers and academics in this field. Comprehensively reviews the fundamental corrosion mechanisms that affect nuclear power plants and facilities Chapters assess different types of both aqueous and non aqueous corrosion mechanisms and the nuclear materials susceptible to attack from them Considers monitoring and control methodologies, as well as modelling and lifetime prediction approaches

Volume is indexed by Thomson Reuters CPCI-S (WoS). The editors of this special volume made every effort to invite all of those corrosion specialists working in the field of lightweight alloys and, specifically, their modeling. Their expertise provided a basis upon which to discuss corrosion problems and solutions for Military and Aerospace Systems and Facilities; thus laying a solid foundation for the tackling of yet-unsolved issues. The use of lightweight metals and composites to replace heavy structural materials for military hardware and weapons systems (ships, aircraft, ground vehicles, etc.) is a new strategic consideration for defence forces; falling under Naval S&T Strategic Plans. The objectives of the workshop were to seek state-of-the-art ideas, from outside of the continental United States, in the field of low-density metallic materials and composites for structural applications, as well as modeling and simulation software tools which are capable of generating and identifying damage evolution data for health monitoring, corrosion control, life prediction and assessment of civil and military hardware systems. The result is an invaluable guide to this increasingly important topic.

This four-volume reference work builds upon the success of past editions of Elsevier’s Corrosion title (by Shreir, Jarman, and Burstein), covering the range of innovations and applications that have emerged in the years since its publication. Developed in partnership with experts from the Corrosion and Protection Centre at the University of Manchester, Shreir’s Corrosion meets the research and productivity needs of engineers, consultants, and researchers alike. Incorporates coverage of all aspects of the corrosion phenomenon, from the science behind corrosion of metallic and non-metallic materials in liquids and gases to the management of corrosion in specific industries and applications Features cutting-edge topics such as medical applications, metal matrix composites, and corrosion modeling Covers the benefits and limitations of techniques from scanning probes to electrochemical noise and impedance spectroscopy