Multiparameter Equations Of State

As a basis for printed property charts and tables, empirical multiparameter equa tions of state have been the most important source of accurate thermodynamic property data for more than 30 years now. However, due to increasing demands on the accuracy of thermodynamic property data in computerised calculations as well as the availability of appropriate software tools, and the ever increasing computer power, such formulations are nowadays becoming a valuable tool for everyday work. This development has substantially increased the number of scientists, engi neers, and students who are working with empirical multiparameter equations of state, and it continues to do so. Nevertheless, common knowledge on this kind of thermodynamic property models and on the ongoing progress in this scientific discipline is still very limited. Multiparameter equations of state do not belong to the topics which are taught intensively in thermodynamic courses in engineering and natural sciences and the books and articles where they are published mainly deal with the thermodynamic properties of certain substances rather than with the theoretical background of the used equations of state. In contrast to this, my concern mainly was to give a survey of the theoretical background of multiparameter equations of state both with regard to their application and their development.

This book has been prepared under the auspices of Commission I.2 on Thermodynamics of the International Union of Pure and Applied Chemistry (IUPAC). The authors of the 18 chapters are all recognized experts in the field. The book gives an up-to-date presentation of equations of state for fluids and fluid mixtures. All principal approaches for developing equations of state are covered. The theoretical basis and practical use of each type of equation is discussed and the strength and weaknesses of each is addressed. Topics addressed include the virial equation of state, cubic equations and generalized van der Waals equations, perturbation theory, integral equations, corresponding stated and mixing rules. Special attention is also devoted to associating fluids, polydisperse fluids, polymer systems, self-assembled systems, ionic fluids and fluids near critical points.

Volumetric properties play an important role in research at the interface of physical chemistry and chemical engineering, but keeping up with the latest developments in the field demands a broad view of the literature. Presenting a collection of concise, focused chapters, this book offers a comprehensive guide to the latest developments in the field and a starting point for more detailed research. The chapters are written by acknowledged experts, covering theory, experimental methods, techniques, and results on all types of liquids and vapours. The editors work at the forefront of thermodynamics in mixtures and solutions and have brought together contributions from all areas related to volume properties, offering a synergy of ideas across the field. Graduates, researchers and anyone working in the field of volumes will find this book to be their key reference.

Organic Rankine Cycle (ORC) Power Systems: Technologies and Applications provides a systematic and detailed description of organic Rankine cycle technologies and the way they are increasingly of interest for cost-effective sustainable energy generation. Popular applications include cogeneration from biomass and electricity generation from geothermal reservoirs and concentrating solar power installations, as well as waste heat recovery from gas turbines, internal combustion engines and medium- and low-temperature industrial processes. With hundreds of ORC power systems already in operation and the market growing at a fast pace, this is an active and engaging area of scientific research and technical development. The book is structured in three main parts: (i) Introduction to ORC Power Systems, Design and Optimization, (ii) ORC Plant Components, and (iii) Fields of Application. Provides a thorough introduction to ORC power systems Contains detailed chapters on ORC plant components Includes a section focusing on ORC design and optimization Reviews key applications of ORC technologies, including cogeneration from biomass, electricity generation from geothermal reservoirs and concentrating solar power installations, waste heat recovery from gas turbines, internal combustion engines and medium- and low-temperature industrial processes Various chapters are authored by well-known specialists from Academia and ORC manufacturers

The corresponding-states principle helps the understanding and calculating of thermodynamic, transport, and surface properties of substances in various states, required by our modern lifestyle. The Corresponding-States Principle and its Practice: Thermodynamic, Transport and Surface Properties of Fluids describes the origins and applications of the principle from a universal point of view with comparisons to experimental data where possible. It uses the universal theory to explain present theories. Emphasis is on the properties of pure systems, and the corresponding-states theory can also be extended to mixtures, which are treated as pure systems. Furthermore, the author discusses current progress, and shows technicians how to derive practical equations from molecular modeling. The Corresponding-States Principle and its Practice: Thermodynamic, Transport and Surface Properties of Fluids is the ideal handbook for those in chemical science and engineering related to energy, environment, natural gas, and petroleum. * Describes the origins and applications from a universal viewpoint* Includes experimental data for comparisons * Suitable for researchers, applied engineers, and those interested in the corresponding states theory

Provides an essential treatment of the subject and rigorous methods to solve all kinds of energy engineering problems.

This book comprises five chapters on developed research activities on organic Rankine cycles. The first section aims to provide researchers with proper modelling (Chapter 1) and experimental (Chapter 2) tools to calculate and empirically validate thermophysical properties of ORC working fluids. The second section introduces some theoretical and experimental studies of organic Rankine cycles for waste heat recovery applications: a review of different supercritical ORC (Chapter 3), ORC for waste heat recovery from fossil-fired power plants (Chapter 4), the experimental detailed characterization of a small-scale ORC of 3 kW operating with either pure fluids or mixtures (Chapter 5).