Mxene Based Hybrid Nano Architectures For Environmental Remediation And Sensor Applications

Approx.630 pages Covers fundamentals of MXene-based hybrid nanostructures, including synthesis and characterization methods Explores innovative and emerging applications, with a focus on environmental remediation and sensors Addresses challenges, such as environmental impact and lifecycle, as well as future possibilities

This book is concerned with functional nanomaterials, materials containing specific, predictable nanostructures whose chemical composition, or interfacial structure enables them to perform a specific job: to destroy, sequester, or detect some material that constitutes an environmental threat. Nanomaterials have a number of features that make them ideally suited for this job: they have a high surface area, high reactivity, easy dispersability, and rapid diffusion,to name a few. The purpose of this book is to showcase how these features can be tailored to address some of the environmental remediation and sensing/detection problems faced by mankind today. A number of leading researchers have contributed to this volume, painting a picture of diverse synthetic strategies, structures, materials, and methods. The intent of this book is to showcase the current state of environmental nanomaterials in such a way as to be useful either as a research resource, or as a graduate level textbook. We have organized this book into sections on nanoparticle-based remediation strategies, nanostructured inorganic materials (e.g. layered materials like the apatites), nanostructured organic/inorganic hybrid materials, and the use of nanomaterials to enhance the performance of sensors.

Functional and structural nanomaterials are emerging materials that display interesting physical and chemical properties because of their size and surface area to volume ratio. Applications for these materials include uses in removing pollutants from the environment. Looking at the current state-of-the-art as well as future trends in the use of nanomaterials for tackling environmental issues this book covers everything from the synthesis and characterisation of these materials to their use in the removal of specific contaminants. Functional Hybrid Nanomaterials for Environmental Remediation is a useful resource both for nanomaterial scientists interested in the real world application of hybrid nanomaterials and for environmental chemists and environmental engineers interested in novel materials for environmental remediation.

MXenes as Emerging Modalities for Environmental and Sensing Applications: Theories, Design and Approach explores how MXene-based hybrid nanostructures are used to remedy environmental pollutants. The book also explains how they assist in sensing and degradation/removal applications to protect the ecological system, both environmental and aquatic life, from various types of toxic pollutants released from industrial sectors. This book focuses on the design, fabrication, and application of MXene-based nanostructures and their integration with the biotechnological processes for monitoring and treatment of pollutants in environmental matrices and sensing applications. It aims to increase scientific and technological awareness of the urgency required to tackle life-threatening pollutants arising from various industrial and biotechnological sectors of the modern world.

This book is concerned with functional nanomaterials, materials containing specific, predictable nanostructures whose chemical composition, or interfacial structure enables them to perform a specific job: to destroy, sequester, or detect some material that constitutes an environmental threat. Nanomaterials have a number of features that make them ideally suited for this job: they have a high surface area, high reactivity, easy dispersability, and rapid diffusion, to name a few. The purpose of this book is to showcase how these features can be tailored to address some of the environmental remediation and sensing/detection problems faced by mankind today. A number of leading researchers have contributed to this volume, painting a picture of diverse synthetic strategies, structures, materials, and methods. The intent of this book is to showcase the current state of environmental nanomaterials in such a way as to be useful both as a research resource and as a graduate level textbook. We have organized this book into sections on nanoparticle-based remediation strategies, nanostructured inorganic materials (e.g. layered materials like the apatites), nanostructured organic/inorganic hybrid materials, and the use of nanomaterials to enhance the performance of sensors. Contents:Nanoparticle-based Approaches:Nanoparticle Metal Oxides for Chlorocarbon and Organophosphonate Remediation (Olga B Koper, Shyamala Rajagopalan, Slawomir Winecki and Kenneth J Klabunde)Nanoscale Zero-Valent Iron (nZVI) for Site Remediation (Daniel W Elliott, Hsing-Lung Lien and Wei-xian Zhang)Synthesis, Characterization, and Properties of Zero-Valent Iron Nanoparticles (Donald R Baer, Paul G Tratnyek, You Qiang, James E Amonette, John Linehan, Vaishnavi Sarathy, James T Nurmi, Chongmin Wang and J Antony)Nanostructured Inorganic Materials:Formation of Nanosized Apatite Crystals in Sediment for Containment and Stabilization of Contaminants (Robert C Moore, Jim Szecsody, Michael J Truex, Katheryn B Helean, Ranko Bontchev and Calvin Ainsworth)Functionalized Nanoporous Sorbents for Adsorption of Radioiodine from Groundwater and Waste Glass Leachates (Shas V Mattigod, Glen E Fryxell and Kent E Parker)Nanoporous Organic/Inorganic Hybrid Materials:Nature's Nanoparticles: Group IV Phosphonates (Abraham Clearfield)Twenty-five Years of Nuclear Waste Remediation Studies (Abraham Clearfield)Synthesis of Nanostructured Hybrid Sorbent Materials Using Organosilane Self-assembly on Mesoporous Ceramic Oxides (Glen E Fryxell)Chemically Modified Mesoporous Silicas and Organosilicas for Adsorption and Detection of Heavy Metal Ions (Oksana Olkhovyk and Mietek Jaroniec)Hierarchically Imprinted Adsorbents (Hyunjung Kim, Chengdu Liang and Sheng Dai)Functionalization of Periodic Mesoporous Silica and Its Application to the Adsorption of Toxic Anions (Hideaki Yoshitake)Layered Semi-crystalline Polysilsesquioxane: A Mesostructured and Stoichiometric Organic-Inorganic Hybrid Solid for the Removal of Environmentally Hazardous Ions (Hideaki Yoshitake)A Thiol-functionalized Nanoporous Silica Sorbent for Removal of Mercury from Actual Industrial Waste (Shas V Mattigod, Glen E Fryxell and Kent E Parker)Functionalized Nanoporous Silica for Oral Chelation Therapy of a Broad Range of Radionuclides (Wassana Yantasee, Wilaiwan Chouyyok, Robert J Wiacek, Jeffrey A Creim, R Shane Addleman, Glen E Fryxell and Charles Timchalk)Amine-functionalized Nanoporous Materials for Carbon Dioxide (CO2) Capture (Feng Zheng, R Shane Addleman, Christopher L Aardahl, Glen E Fryxell, Daryl R Brown and Thomas S Zemanian)Carbon Dioxide Capture from Post-combustion Streams Using Amine-functionalized Nanoporous Materials (Rodrigo Serna-Guerrero and Abdelhamid Sayari)Nanomaterials that Enhance Sensing/Detection of Environmental Contaminants:Nanostructured ZnO Gas Sensors (Huamei Shang and Guozhong Cao)Synthesis and Properties of Mesoporous-based Materials for Environmental Applications (Jianlin Shi, Hangrong Chen, Zile Hua and Lingxia Zhang)Electrochemical Sensors Based on Nanomaterials for Environmental Monitoring (Wassana Yantasee, Yuehe Lin and Glen E Fryxell)Nanomaterial-based Environmental Sensors (Dosi Dosev, Mikaela Nichkova and Ian M Kennedy)Carbon Nanotube- and Graphene-based Sensors for Environmental Applications (Dan Du)One-dimensional Hollow Oxide Nanostructures: A Highly Sensitive Gas-sensing Platform (Jong-Heun Lee)Preparation and Electrochemical Application of Titania Nanotube Arrays (Peng Xiao, Guozhong Cao and Yunhuai Zhang) Readership: Graduate students and researchers in nanomaterials and nanostructures. Keywords:Nanomaterials;Nanoporous Sorbents;Chemical Separations;Environmental Clean-Up;Heavy Metals;Radionuclides;Nanoparticles;SensorsKey Features:The materials and methods described herein offer exciting new possibilities in the remediation and/or detection of a wide variety of environmental concerns, including chemical warfare agents, dense non-aqueous phase liquids (DNAPLs), heavy metals, radionuclides, biological threats, carbon dioxide, carbon monoxide and more. The approaches described run the gamut from laboratory design and synthesis of the nanomaterial, to final application/deployment of the technology to clean up hazardous wasteThe contributing authors are leading experts in the field of environmental nanomaterialsStrategies cover a wide variety of chemistries and structural morphologies, including nanoparticles, nanotubes and nanoporous materials, thereby providing a valuable overview of the state-of-the-art

Sustainable Nanotechnology for Environmental Remediation provides a single-source solution to researchers working in environmental, wastewater management, biological and composite nanomaterials applications. It addresses the potential environmental risks and uncertainties surrounding the use of nanomaterials for environmental remediation, giving an understanding of their impact on ecological receptors in addition to their potential benefits. Users will find comprehensive information on the application of state-of-the-art processes currently available to synthesize advanced green nanocomposite materials and biogenic nanomaterials. Other sections explore a wide range of promising approaches for green nanotechnologies and nanocomposites preparations. Case study chapters connect materials engineering and technology to the social context for a sustainable environment. Applications and different case studies provide solutions to the challenges faced by industry, thus minimizing negative social impacts. Provides information on the use of biologically mediated synthetic protocols to generate nanomaterials Discusses a wide range of promising?approaches?for?green nanotechnologies and nanocomposites preparations Presents novel fabrication techniques for bionanocomposites, paving the way for the development of a new generation of advanced materials that can cope with spatiotemporal multi-variant environments

MXenes offer single step processing, excellent electrical conductivity, easy heat dissipation behavior, and capacitor-like properties and are used in photodetectors, lithium-ion batteries, solar cells, photocatalysis, electrochemiluminescence sensors, and supercapacitors. Because of their superior electrical and thermal conductivities, these composites are an ideal choice in electromagnetic interference (EMI) shielding. MXene Nanocomposites: Design, Fabrication, and Shielding Applications presents a comprehensive overview of these emerging materials, including their underlying chemistry, fabrication strategies, and cutting-edge applications in EMI shielding. Covers modern fabrication technologies, processing, properties, nanostructure formation, and mechanisms of reinforcement Discuss biocompatibility, suitability, and toxic effects Details innovations, applications, opportunities, and future directions in EMI shielding applications This book is aimed at researchers and advanced students in materials science and engineering and is unique in its detailed coverage of MXene-based polymer composites for EMI shielding.

Environmental Applications of Carbon Nanomaterials-Based Devices Explore this insightful treatment of the function and fabrication of high-performance devices for environmental applications Environmental Applications of Carbon Nanomaterials-Based Devices delivers an overview of state-of-the-art technology in functionalized carbon nanomaterials-based devices for environmental applications. The book provides a powerful foundation, based in materials science, on functionalized carbon nanomaterials in general, and environmental science and device fabrication in particular. The book focuses on the chemical and physical methods of functionalization of carbon nanomaterials and the technology of device fabrication, including lab-on-a-chip approaches and applications such as wastewater purification and gas sensing. It provides readers with a thorough understanding of effective environmental remediation techniques performed with carbon nanomaterials-based devices. In addition to topics such as cross-linked graphene oxide membranes assembled with graphene oxide nanosheets, free-standing graphene oxide-chitin nanocrystal composite membranes for dye adsorption and oil/water separation, and in-situ grown covalent organic framework nanosheets on graphene for membrane-based dye/salt separation, readers will also benefit from the inclusion of: A thorough introduction to charge-gated ion transport through polyelectrolyte intercalated amine reduced graphene oxide membranes An exploration of hydrotalcite/graphene oxide hybrid nanosheets functionalized nanofiltration membrane for desalination A discussion of the incorporation of attapulgite nanorods into graphene oxide nanofiltration membranes for efficient dyes wastewater treatment An examination of attapulgite nanofibers and graphene oxide composite membranes for high-performance molecular separation Perfect for materials scientists, analytical chemists, and environmental chemists, Environmental Applications of Carbon Nanomaterials-Based Devices will also earn a place in the libraries of sensor developers seeking a one-stop resource for high-performance devices and sensors useful for environmental applications.