Nanocomposite Structures And Dispersions

Nanocomposite Structures and Dispersions summarizes the fundamentals and mechanistic approaches in preparation and characterization of colloidal nanoparticles and dispersions, providing the readers a systematic and coherent picture of the field. The book serves as an introduction to the interesting field of nanoscience based on polymer and metal colloidal nanoparticles, and also presents the basic knowledge of polymer colloids preparation. It places a special emphasis on polymer, inorganic and metal nanomaterials classified as nanoparticles, nanocrystals, nanorods, nanotubes, nanobelts, etc. deals with the chemistry of the reaction approaches by which polymer and metal particles are synthesized. The book explores both organic (synthetic and natural) and inorganic materials, as well as their hybrids. It describes in detail terms, definitions, theories, experiments, and techniques dealing with synthesis of polymer and metal particles. It also discusses a variety of synthetic approaches including emulsion, miniemulsion and microemulsion approaches, homogeneous and heterogeneous nucleation approaches under mild and high temperatures. There is also a chapter on modification and passivation of colloidal particles. This book would be of interest to chemical engineers, polymer chemists, organic chemists, colloid chemists, materials scientists and nanotechnologists. Although the text discusses nanoscience and nanotechnology from the viewpoint of a chemist, it would also appeal to those just entering the field and experts seeking information in other sub-fields. Serves as a general introduction for those just entering the field and experts seeking information in other sub-fields Variety of synthetic approaches is described including emulsion, miniemulsion and microemulsion approaches, hogeneous and heterogeneous nucleation approaches under mild and high temperatures Focused on both the organic (synthetic and natural) and inorganic materials, and their hybrids

Nanocomposite Structures and Dispersions deals with the preparation of gelled, branched and crosslinked nanostructured polymers in the solution free radical polymerization and controlled/living radical polymerization and polymer and composite nanoparticles and nanostructures in disperse systems, the kinetics of direct and inverse disperse polymerizations (microemulsion, miniemulsion, emulsion, dispersion and suspension polymerization), the bottom-up approach building of functionalized nanoparticles, modelling of radical microemulsion polymerization, the characterization of traditional and non-traditional polymer dispersions, the collective properties of nanomaterials and their (bio)applications. This book is designed to bridge that gap and offers several unique features. First, it is written as an introduction to and survey of nanomaterials with a careful balance between basics and advanced topics. Thus, it is suitable for both beginners and experts, including graduate and upper-level undergraduate students. Second, it strives to balance the colloidal aspects of nanomaterials with physical principles. Third, the book highlights nanomaterial based architectures including composite or hybrid conjugates rather than only isolated nanoparticles. A number of ligands have been utilized to biodecorate the polymer and composite nanocarriers. Finally, the book provides an in depth discussion of important examples of reaction mechanisms of bottom-up building of functionalized nanoparticles, or potential applications of nanoarchitectures, ranging from physical to chemical and biological systems. Free radical (controlled) polymerization, branching, crosslinking and gelling Kinetics and mechanism of polymer nanoparticles formation Modelling of radical polymerization in disperse systems Polymer, composite and metal nanoparticles, nanostructures and nanomaterials Smart nanostructures, biodecorated particles, nanocarriers and therapeutics

Nanocomposites are attractive to researchers both from practical and theoretical point of view because of combination of special properties. Many efforts have been made in the last two decades using novel nanotechnology and nanoscience knowledge in order to get nanomaterials with determined functionality. This book focuses on polymer nanocomposites and their possible divergent applications. There has been enormous interest in the commercialization of nanocomposites for a variety of applications, and a number of these applications can already be found in industry. This book comprehensively deals with the divergent applications of nanocomposites comprising of 22 chapters.

Emphasizing the static and dynamic behaviors of nanocomposite single- or multilayered structures in the framework of continuum mechanics-based approaches, Mechanics of Nanocomposites: Homogenization and Analysis investigates mechanical behaviors of polymeric matrices strengthened via various nanofillers and nanoparticles such as carbon nanotubes (CNTs), graphene platelets (GPLs), and graphene oxides (GOs). It covers equivalent properties of nanocomposites that are obtained via homogenization techniques based on micromechanics approaches. In addition, this comprehensive book: Discusses the effects of various nanofillers and identifies the amount of the improvement that can be induced in the stiffness of the polymeric nanocomposites by adding a finite content of the aforementioned nanosize reinforcements Magnifies the effect of the number of the stacking plies of the multi-layered nanocomposite structures on both static and dynamic responses of the continuous systems manufactured from such sandwich structures Presents a wide range of analytical and numerical solution procedures Investigates the effects of porosity along with mechanical characteristics of nanocomposites Considers the time-dependency of the material properties of the viscoelastic polymeric nanocomposite structures Performs analyses using an energy-based approach incorporated with the strain-displacement relations of both classical and higher-order shear deformable beam, plate, or shell theorems Aimed at researchers, academics, and professionals working across mechanical, materials, and other areas of engineering, this work ensures that readers are equipped to fully understand the mechanical characteristics of nanocomposite structures so that they can design, develop, and apply these materials effectively.

The present book focuses on the preparation, properties, characterisation and applications of polymer nanocomposites. The various manufacturing techniques, analysis of morphology, filler dispersion, and interfacial interactions have been described are detail. In the case of polymer nanocomposites, filler dispersion, intercalation/exfoliation, orientation and filler-matrix interaction are the main parameters that determine the physical, thermal, transport, mechanical and rheological properties of the nanocomposites. In this book the ultimate properties of the nanocomposites have been correlated with the key parameters of filler dispersion and filler-matrix interaction. The use of various sophisticated instrument techniques for the characterisation of these nanocomposites are also reviewed.

Mechanics of Multiscale Hybrid Nanocomposites provides a practical and application-based investigation of both static and dynamic behaviors of multiscale hybrid nanocomposites. The book outlines how to predict the mechanical behavior and material characteristics of these nanocomposites via two-step micromechanical homogenization techniques performed in an energy-based approach that is incorporated with the strain-displacement relations of shear deformable beam, plate and shell theories. The effects of using various nanofillers are detailed, providing readers with the best methods of improving nanocomposite stiffness. Both numerical (Ritz, Rayleigh-Ritz, etc.) and analytical (Navier, Galerkin, etc.) solution methods are outlined, along with examples and techniques. Demonstrates the influences of carbon nanotube agglomerates and wave phenomena on the constitutive modeling of three-phase hybrid nanocomposites Analyzes nonlinear dynamic characteristics of hybrid nanocomposite systems, as well as how to monitor the system’s stability via linearization technique Discusses the stability of linear nanocomposite systems subjected to the dispersion of elastic waves and bending loads Outlines how to design three-phase nanocomposite structures for resistance against buckling-mode failure Instructs how to derive the governing equations of continuous systems in both linear and nonlinear regimes in the framework of various types of kinematic shell and plate theories

To have unimaginably outstanding useful properties (physical, mechanical, electrical, optical, chemical, and magnetic) in a single material design is a highly challenging task in the material science community, which can be achieved through nanocomposites. These nanocomposites can be produced from all conventional materials, which include polymers, metals/alloys, and ceramics, by modifying their internal structures. Due to modification of the structures of all kinds of conventional materials, at either the nano or ultra-fine level, the materials exhibit superior performance, which is a boon for all fields of science. In general, nanocomposite materials can be manufactured by solid-state processing techniques, liquid metallurgy, ex-situ and in-situ powder metallurgy, and other basic science synthesis routes. Furthermore, the possibility of making environmentally friendly materials is also possible with nanotechnology. Therefore, to investigate and demonstrate developments in the field of nanocomposites, this book is targeted at all the scientific personnel working in this field.

Advancements in the nanotechnology industry promise to offer improvements in capabilities across a spectrum of applications. This is of immense strategic importance to the high performance sector which has historically leveraged technological advances. The use of polymer nanocomposites in structures have several predictable impacts on structural design and applications, primarily by providing a safer, faster, and eventually cheaper transportation in the future. This books comprises reviews on the state-of-the-art, new research results, perspectives of future developments, and innovative applications relevant to structural materials, engineering structures, nanocomposites, modelling and simulations, and their related application areas.