Nanoporous Materials For Gas Storage

This book shows the promising future and essential issues on the storage of the supercritical gases, including hydrogen, methane and carbon dioxide, by adsorption with controlling the gas-solid interaction by use of designed nanoporous materials. It explains the reason why the storage of these gases with adsorption is difficult from the fundamentals in terms of gas-solid interaction. It consists of 14 chapters which describe fundamentals, application, key nanoporous materials (nanoporous carbon, metal organic frame works, zeolites) and their storage performance for hydrogen, methane, and carbon dioxide. Thus, this book appeals to a wide readership of the academic and industrial researchers and it can also be used in the classroom for graduate students focusing on clean energy technology, green chemistry, energy conversion and storage, chemical engineering, nanomaterials science and technology, surface and interface science, adsorption science and technology, carbon science and technology, metal organic framework science, zeolite science, nanoporous materials science, nanotechnology, environmental protection, and gas sensors.

Natural resources, such as zeolite minerals, have an inexhaustible potential for scientific research and application. Both natural and synthetic zeolites have application in many researched areas including water and soil industries, biochemistry, and medicine due to their environmental and economic acceptability, unique structure, and specific characteristics. Over three sections, this book presents a comprehensive overview of zeolites and their potential applications in science. Chapters cover such topics as the history of zeolites, their structure and properties, layered zeolites, and use of zeolites for gas storage and separation as well as in veterinary medicine.

This text discusses the synthesis, characterization, and application of metal-organic frameworks (MOFs) for the purpose of adsorbing gases. It provides details on the fundamentals of thermodynamics, mass transfer, and diffusion that are commonly required when evaluating MOF materials for gas separation and storage applications and includes a discussion of molecular simulation tools needed to examine gas adsorption in MOFs. Additionally, the work presents techniques that can be used to characterize MOFs after gas adsorption has occurred and provides guidance on the water stability of these materials. Lastly, applications of MOFs are considered with a discussion of how to measure the gas storage capacity of MOFs, a discussion of how to screen MOFs to for filtration applications, and a discussion of the use of MOFs to perform industrial separations, such as olefin/paraffin separations. Throughout the work, fundamental information, such as a discussion on the calculation of MOF surface area and description of adsorption phenomena in packed-beds, is balanced with a discussion of the results from research literature.

Porous materials are of scientific and technological importance because of the presence of voids of controllable dimensions at the atomic, molecular, and nanometer scales, enabling them to discriminate and interact with molecules and clusters. Interestingly the big deal about this class of materials is about the “nothingness” within — the pore space. International Union of Pure and Applied Chemistry (IUPAC) classifies porous materials into three categories — micropores of less than 2 nm in diameter, mesopores between 2 and 50 nm, and macropores of greater than 50 nm. In this book, nanoporous materials are defined as those porous materials with pore diameters less than 100 nm.Over the last decade, there has been an ever increasing interest and research effort in the synthesis, characterization, functionalization, molecular modeling and design of nanoporous materials. The main challenges in research include the fundamental understanding of structure-property relations and tailor-design of nanostructures for specific properties and applications. Research efforts in this field have been driven by the rapid growing emerging applications such as biosensor, drug delivery, gas separation, energy storage and fuel cell technology, nanocatalysis and photonics. These applications offer exciting new opportunities for scientists to develop new strategies and techniques for the synthesis and applications of these materials.This book provides a series of systematic reviews of the recent developments in nanoporous materials. It covers the following topics: (1) synthesis, processing, characterization and property evaluation; (2) functionalization by physical and/or chemical treatments; (3) experimental and computational studies on fundamental properties, such as catalytic effects, transport and adsorption, molecular sieving and biosorption; (4) applications, including photonic devices, catalysis, environmental pollution control, biological molecules separation and isolation, sensors, membranes, hydrogen and energy storage, etc./a

Nanoporous materials consist of a regular organic or inorganic framework supporting a porous structure. Nanoporous materials are separated into three subtypes: microporous materials, mesoporous materials and macroporous materials. In recent years, nanoporous materials have been recognized as promising candidates for the multifunctional applications such as catalysis, ion-exchange, gas storage low density magnetic storage, etc. In addition, nanoporous materials are also of scientific and technological importance because of their ability to absorb and co-operate with atoms, ions and molecules on their sizeable interior surfaces and pore space. This book proposes and reviews advances being made in the field of nanoporous materials.

Materials Science Forum Vol. 31

This four-volume handbook gives a state-of-the-art overview of porous materials, from synthesis and characterization and simulation all the way to manufacturing and industrial applications. The editors, coming from academia and industry, are known for their didactic skills as well as their technical expertise. Coordinating the efforts of 37 expert authors in 14 chapters, they construct the story of porous carbons, ceramics, zeolites and polymers from varied viewpoints: surface and colloidal science, materials science, chemical engineering, and energy engineering. Volumes 1 and 2 cover the fundamentals of preparation, characterisation, and simulation of porous materials. Working from the fundamentals all the way to the practicalities of industrial production processes, the subjects include hierarchical materials, in situ and operando characterisation using NMR, X-Ray scattering and tomography, state-of-the-art molecular simulations of adsorption and diffusion in crystalline nanoporous materials, as well as the emerging areas of bio-artificing and drug delivery. Volume 3 focuses on porous materials in industrial separation applications, including adsorption separation, membrane separation, and osmotic distillation. Finally, and highly relevant to tomorrow's energy challenges, Volume 4 explains the energy engineering aspects of applying porous materials in supercapacitors, fuel cells, batteries, electrolysers and sub-surface energy applications.The text contains many high-quality colourful illustrations and examples, as well as thousands of up-to-date references to peer-reviewed articles, reports and websites for further reading. This comprehensive and well-written handbook is a must-have reference for universities, research groups and companies working with porous materials.Related Link(s)

Nanoporous Materials for Molecule Separation and Conversion cover the topic with sections on nanoporous material synthesis and characterization, nanoporous materials for molecule separation, and nanoporous materials for energy storage and renewable energy. Typical nanoporous materials including carbon, zeolite, silica and metal-organic frameworks and their applications in molecule separation and energy related applications are covered. In addition, the fundamentals of molecule adsorption and molecule transport in nanoporous materials are also included, providing readers with a stronger understanding of the principles and topics covered. This is an important reference for anyone exploring nanoporous materials, including researchers and postgraduate students in materials science and chemical engineering. In addition, it is ideal for industry professionals working on a wide range of applications for nanoporous materials. Outlines the fundamental principles of nanoporous materials design Explores the application of nanoporous materials in important areas such as molecule separation and energy storage Gives real-life examples of how nanoporous materials are used in a variety of industry sector