Next Generation Photovoltaics

The first comprehensive book on thin-film solar cells, potentially a key technology for solving the energy production problem in the 21st century in an environmentally friendly way. It covers a wide range of scientific and technological aspects of thin film semiconductors - deposition technologies, growth mechanisms and the basic properties of amorphous and nano-crystalline silicon - as well as the optimum design theory and device physics of high-efficiency solar cells, especially of single-junction and multi-junction solar cells. The development of large-area solar cell modules using single and multi-junction solar cells is also considered. Examples of recent photovoltaic systems are presented and analysed.

This book presents new concepts for a next generation of PV. Among these concepts are: Multijunction solar cells, multiple excitation solar cells (or how to take benefit of high energy photons for the creation of more than one electron hole-pair), intermediate band solar cells (or how to take advantage of below band-gap energy photons) and related technologies (for quantum dots, nitrides, thin films), advanced light management approaches (plasmonics). Written by world-class experts in next generation photovoltaics this book is an essential reference guide accessible to both beginners and experts working with solar cell technology. The book deeply analyzes the current state-of-the-art of the new photovoltaic approaches and outlines the implementation paths of these advanced devices. Topics addressed range from the fundamentals to the description of state-of-the-art of the new types of solar cells.

Although photovoltaics are regarded by many as the most likely candidate for long term sustainable energy production, their implementation has been restricted by the high costs involved. Nevertheless, the theoretical limit on photovoltaic energy conversion efficiency-above 85%-suggests that there is room for substantial improvement of current commercially available solar cells, both silicon and thin-film based. Current research efforts are focused on implementing novel concepts to produce a new generation of low-cost, high-performance photovoltaics that make improved use of the solar spectrum. Featuring contributions from pioneers of next generation photovoltaic research, Next Generation Photovoltaics: High Efficiency through Full Spectrum Utilization presents a comprehensive account of the current state-of-the-art in all aspects of the field. The book first discusses topics, such as multi-junction solar cells (the method closest to commercialization), quantum dot solar cells, hot carrier solar cells, multiple quantum well solar cells, and thermophotovoltaics. The final two chapters of the book consider the materials, fabrication methods, and concentrator optics used for advanced photovoltaic cells. This book will be an essential reference for graduate students and researchers working with solar cell technology.

The papers included in this issue of ECS Transactions were originally presented in the symposium ¿Next Generation Photovoltaics¿, held during the 212th meeting of The Electrochemical Society, in Washington, DC, from October 7 to 12, 2007.

This book presents new concepts for a next generation of PV. Among these concepts are: Multijunction solar cells, multiple excitation solar cells (or how to take benefit of high energy photons for the creation of more than one electron hole-pair), intermediate band solar cells (or how to take advantage of below band-gap energy photons) and related technologies (for quantum dots, nitrides, thin films), advanced light management approaches (plasmonics). Written by world-class experts in next generation photovoltaics this book is an essential reference guide accessible to both beginners and experts working with solar cell technology. The book deeply analyzes the current state-of-the-art of the new photovoltaic approaches and outlines the implementation paths of these advanced devices. Topics addressed range from the fundamentals to the description of state-of-the-art of the new types of solar cells.

This book presents new concepts for a next generation of PV. Among these concepts are: Multijunction solar cells, multiple excitation solar cells (or how to take benefit of high energy photons for the creation of more than one electron hole-pair), intermediate band solar cells (or how to take advantage of below band-gap energy photons) and related technologies (for quantum dots, nitrides, thin films), advanced light management approaches (plasmonics). Written by world-class experts in next generation photovoltaics this book is an essential reference guide accessible to both beginners and experts working with solar cell technology. The book deeply analyzes the current state-of-the-art of the new photovoltaic approaches and outlines the implementation paths of these advanced devices. Topics addressed range from the fundamentals to the description of state-of-the-art of the new types of solar cells.

This book will guide Photovoltaics researchers in a new way of thinking about harvesting light energy from all wavelengths of the solar spectrum. It closes the gap between general solar cells books and photovoltaics journal articles, by focusing on the latest developments in our understanding of solid-state device physics. The material presented is experimental and based on II-VI thin-film materials, mainly CdTe-based solar cells. The authors describe the use of new device design, based on multilayer graded bandgap configuration, using CdTe-based solar cells. The authors also explain how the photo-generated currents can be enhanced using multi-step charge carrier production. The possibility of fabricating these devices using low-cost and scalable electroplating is demonstrated. The value of electroplating for large area electronic devices such as PV solar panels, display devices and nano-technology devices are also demonstrated. By enabling new understanding of the engineering of electroplated semiconductor materials and providing an overview of the semiconductor physics and technology, this practical book is ideal to guide researchers, engineers, and manufacturers on future solar cell device designs and fabrications. Discusses in detail the processes of growths, treatments, solar cell device fabrication and solid state physics, improving readers’ understanding of fundamental solid state physics; Enables future improvements in CdTe-based device efficiency; Explains the significance of defects in deposited semiconductor materials and interfaces that affect the material properties and resulting device performance.

Photovoltaics, the direct conversion of sunlight to electricity, is now the fastest growing technology for electricity generation. Present "first generation" products use the same silicon wafers as in microelectronics. "Second generation" thin-films, now entering the market, have the potential to greatly improve the economics by eliminating material costs. Martin Green, one of the world’s foremost photovoltaic researchers, argues in this book that "second generation" photovoltaics will eventually reach its own material cost constraints, engendering a "third generation" of high performance thin-films. The book explores, self-consistently, the energy conversion potential of advanced approaches for improving photovoltaic performance and outlines possible implementation paths.