Non Equilibrium Evaporation And Condensation Processes

This monograph presents a comprehensive treatment of analytical solutions to problems in the area of non-equilibrium evaporation and condensation processes. The book covers, among others, topics such as systems of conversation equations for molecular fluxes of mass, momentum and energy within the Knudsen layer, spherical growth of vapor bubbles in volumes of highly superheated liquid. The target audience primarily comprises research experts in the field of thermodynamics and fluid dynamics, but the book may also be beneficial for graduate students alike.

This present book is concerned with analytical approaches to statement and solution of problems of non-equilibrium evaporation and condensation. From analytical solutions, one is capable to understand and represent in a transparent form the principal laws, especially in the study of a new phenomenon or a process. This is why analytical methods are always employed on the first stage of mathematical modeling. Analytical solutions are also used as test models for validation of results numerical solutions. Non-equilibrium evaporation and condensation processes play an important role in a number of fundamental and applied problems: laser methods for processing of materials, depressurization of the protection cover of nuclear propulsion units, solar radiation on a comet surface, explosive boiling of superheated liquid, thermodynamic principles of superfluid helium. Analytical relations provide an adequate description of the essence of a physical phenomenon.

This advanced textbook for courses covering heat transfer with phase change, was developed based on the author's wide experience of teaching courses on the subject. In his comprehensive treatment, Carey offers, through illustrative examples and problems, a presentation of non-equilibrium thermodynamics and interfacial phenomena associated with vaporization and condensation processes, in addition to fundamentals of heat tranfer and fluid flow mechanisms. The sequence in which the material is presented is designed to facilitate instruction at the advanced undergraduate level in mechanical and chemical engineering. Tables of thermophysical properties are included in an appendix to aid in the solution to many of the homework problems.

This book presents information on the development of a non-equilibrium approach to the study of heat and mass transfer problems using vapor-liquid interfaces, and demonstrates its application to a broad range of problems. In the process, the following peculiarities become apparent: 1. At vapor condensation on the interface from gas-vapor mixture, non-condensable components can lock up the interface surface and condensation stops completely. 2. At the evolution of vapor film on the heater in superfluid helium (He-II), the boiling mass flux density from the vapor-liquid interface is effectively zero at the macroscopic scale. 3. In problems concerning the motion of He-II bridges inside capillaries filled by vapor, in the presence of axial heat flux the He-II bridge cannot move from the heater as would a traditional liquid, but in the opposite direction instead. Thus the heater attracts the superfluid helium bridge. 4. The shape of liquid-vapor interface at film boiling on the axis-symmetric heaters immersed in liquid greatly depends on heat flux in the interface. Thus a new type of hydrostatic problems appears when in contrast to traditional statements the shape of the liquid-vapor interface has a complex profile with a point of inflection and a smooth exit on a free liquid surface.

This brief explains in detail fundamental concepts in acoustic cavitation and bubble dynamics, and describes derivations of the fundamental equations of bubble dynamics in order to support those readers just beginning research in this field. Further, it provides an in-depth understanding of the physical basis of the phenomena. With regard to sonochemistry, the brief presents the results of numerical simulations of chemical reactions inside a bubble under ultrasound, especially for a single-bubble system and including unsolved problems. Written so as to be accessible both with and without prior knowledge of fundamental fluid dynamics, the brief offers a valuable resource for students and researchers alike, especially those who are unfamiliar with this field. A grasp of fundamental undergraduate mathematics such as partial derivative and fundamental integration is advantageous; however, even without any background in mathematics, readers can skip the equations and still understand the fundamental physics of the phenomena using the book’s wealth of illustrations and figures. As such, it is also suitable as an introduction to the field.

A translation of the 1984 Russian work. Nonequlibrium condensation is an important aspect of weather forecasting, aerosol formation, and the design of jet propulsion engines, steam turbines and nuclear reactors. It has recently taken on a new significance with the development of technologies such as the production of fine powders, cluster spraying, the development of laser media and isotope separation. This volume presents the general theory of condensation in high-speed gas flows, and the new theoretical, experimental and numerical methods necessary for solving the partial differential equations governing the flows. Annotation copyrighted by Book News, Inc., Portland, OR

Liquid-Vapor Phase-Change Phenomena presents the basic thermophysics and transport principles that underlie the mechanisms of condensation and vaporization processes. The text has been thoroughly updated to reflect recent innovations in research and to strengthen the fundamental focus of the first edition. Starting with an integrated presentation of the nonequilibrium thermodynamics and interfacial phenomena associated with vaporization and condensation, coverage follows of the heat transfer and fluid flow mechanisms in such processes. The second edition includes significant new material on the nanoscale and microscale thermophysics of boiling and condensation phenomena and the use of advanced computational tools to create new models of phase-change events. The importance of basic phenomena to a wide variety of applications is emphasized and illustrated throughout using examples and problems. Suitable for senior undergraduate and first-year graduate students in mechanical or chemical engineering, the book can also be a helpful reference for practicing engineers or scientists studying the fundamental physics of nucleation, boiling and condensation.