Numerical Methods For The Simulation Of A Corrosion Model In A Nuclear Waste Deep Repository

Teaches the application of Reactive Transport Modeling (RTM) for subsurface systems in order to expedite the understanding of the behavior of complex geological systems This book lays out the basic principles and approaches of Reactive Transport Modeling (RTM) for surface and subsurface environments, presenting specific workflows and applications. The techniques discussed are being increasingly commonly used in a wide range of research fields, and the information provided covers fundamental theory, practical issues in running reactive transport models, and how to apply techniques in specific areas. The need for RTM in engineered facilities, such as nuclear waste repositories or CO2 storage sites, is ever increasing, because the prediction of the future evolution of these systems has become a legal obligation. With increasing recognition of the power of these approaches, and their widening adoption, comes responsibility to ensure appropriate application of available tools. This book aims to provide the requisite understanding of key aspects of RTM, and in doing so help identify and thus avoid potential pitfalls. Reactive Transport Modeling covers: the application of RTM for CO2 sequestration and geothermal energy development; reservoir quality prediction; modeling diagenesis; modeling geochemical processes in oil & gas production; modeling gas hydrate production; reactive transport in fractured and porous media; reactive transport studies for nuclear waste disposal; reactive flow modeling in hydrothermal systems; and modeling biogeochemical processes. Key features include: A comprehensive reference for scientists and practitioners entering the area of reactive transport modeling (RTM) Presented by internationally known experts in the field Covers fundamental theory, practical issues in running reactive transport models, and hands-on examples for applying techniques in specific areas Teaches readers to appreciate the power of RTM and to stimulate usage and application Reactive Transport Modeling is written for graduate students and researchers in academia, government laboratories, and industry who are interested in applying reactive transport modeling to the topic of their research. The book will also appeal to geochemists, hydrogeologists, geophysicists, earth scientists, environmental engineers, and environmental chemists.

Understanding the behaviour of gases in the context of radioactive waste disposal is a fundamental requirement in developing a safety case for the disposal of radioactive waste. Of particular importance are the long-term performance of bentonite buffers and cement-based backfill materials that may be used to encapsulate and surround the waste in a repository, and the behaviour of plastic clays, indurated mudrocks and crystalline formations that may be the host rocks for a repository. The EC Euratom programme funded project, FORGE, has provided new insights into the processes and mechanisms governing gas generation and migration with the aim of reducing uncertainty. This volume brings together papers on aspects of this topic arising from both the FORGE project and work undertaken elsewhere. This has been achieved by the acquisition of new experimental data coupled with modelling, through a series of laboratory and field-scale experiments performed at a number of underground research laboratories throughout Europe.

Your Guide to Effective Groundwater Management Groundwater Assessment, Modeling, and Management discusses a variety of groundwater problems and outlines the solutions needed to sustain surface and ground water resources on a global scale. Contributors from around the world lend their expertise and provide an international perspective on groundwater management. They address the management of groundwater resources and pollution, waste water treatment methods, and the impact of climate change on groundwater and water availability (specifically in arid and semi-arid regions such as India and Africa). Incorporating management with science and modeling, the book covers all areas of groundwater resource assessment, modeling, and management, and combines hands-on applications with relevant theory. For Water Resource Managers and Decision Makers The book describes techniques for the assessment of groundwater potential, pollution, prevention, and remedial measures, and includes a new approach for groundwater modeling based on connections (network theory). Approximately 30 case studies and six hypothetical studies are introduced reflecting a range of themes that include: groundwater basics and the derivation of groundwater flow equations, exploration and assessment, aquifer parameterization, augmentation of aquifer, water and environment, water and agriculture, the role of models and their application, and water management policies and issues. The book describes remote sensing (RS) applications, geographical information systems (GIS), and electrical resistivity methods to delineate groundwater potential zones. It also takes a look at: Inverse modeling (pilot-points method) Simulation optimization models Radionuclide migration studies through mass transport modeling Modeling for mapping groundwater potential Modeling for vertical 2-D and 3-D groundwater flow Groundwater Assessment, Modeling, and Management explores the management of water resources and the impact of climate change on groundwater. Expert contributors provide practical information on hydrologic engineering and groundwater resources management for students, researchers, scientists, and other practicing professionals in environmental engineering, hydrogeology, irrigation, geophysics, and environmental science.

In the different disposal concepts for high-level nuclear waste, corrosion of the metallic barriers and in particular the overpack/container is a major issue. It is imperative for performance assessment to predict the lifetime of these containers. In the lifetime prediction of metallic barriers for the disposal of high level nuclear waste (HLW) or of spent fuel, the presence of (reduced) sulphur species is an issue of growing importance, as the sulphur species are involved in localised corrosion phenomena. The international workshop on Sulphur-Assisted Corrosion in Nuclear Waste Disposal Systems (SACNUC2008) aimed to provide an exchange of information on the influence of sulphur species on the corrosion of metallic barriers. This workshop was a co-organisation of the Belgian Nuclear Research Centre, SCK*CEN, and the Belgian Agency for the Management of Radioactive Waste and Enriched Fissile Materials, ONDRAF/NIRAS, under the auspices of the European Federation of Corrosion (EFC event N 311). The proceedings are divided into five chapters: Chapter 1 provides a general overview of the disposal concepts of nuclear waste and the role of corrosion. Chapter 2 explains the mechanism of sulphur-induced corrosion processes. This chapter also contains information from outside the nuclear disposal field in which sulphur is known to act as a detrimental factor (e.g. oil and gas industry). Chapter 3 addresses the role of microbial processes in sulphur-assisted corrosion. Chapter 4 covers the modelling of sulphide-assisted corrosion. Chapter 5 is devoted to a panel discussion aiming to identify open issues in the investigation of sulphur-assisted corrosion phenomena and how to incorporate these in robust lifetime prediction of metallic barriers.