On The Discovery Of The Periodic Law

By the English chemist whose work on the atomic weights of the elements anticipated the periodic table of Mendeleev, and who predicted the element germanium before its discovery by the latter.

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By the dawn of the nineteenth century, "elements" had been defined as basic building blocks of nature resistant to decomposition by chemical means. In 1869, the Russian chemist Dmitri Ivanovich Mendeleev organized the discord of the elements into the periodic table, assigning each element to a row, with each row corresponding to an elemental category. The underlying order of matter, hitherto only dimly perceived, was suddenly clearly revealed. This is the first English-language collection of Mendeleev's most important writings on the periodic law. Thirteen papers and essays, divided into three groups, reflect the period corresponding to the initial establishment of the periodic law (three papers: 1869-71), a period of priority disputes and experimental confirmations (five papers: 1871-86), and a final period of general acceptance for the law and increasing international recognition for Mendeleev (five papers: 1887-1905). A single, easily accessible source for Mendeleev's principle papers, this volume offers a history of the development of the periodic law, written by the law's own founder.

Excerpt from On the Discovery of the Periodic Law, and on Relations Among the Atomic Weights This little book contains an exact reprint of all the papers on Relations Among the Atomic Weights, and on the Periodic Law (provisionally termed the Law of Octaves written by myself, and printed in the Chemical News, some years before M. Mendelejeff had published anything on the subject of the Periodic Law. About the Publisher Forgotten Books publishes hundreds of thousands of rare and classic books. Find more at www.forgottenbooks.com This book is a reproduction of an important historical work. Forgotten Books uses state-of-the-art technology to digitally reconstruct the work, preserving the original format whilst repairing imperfections present in the aged copy. In rare cases, an imperfection in the original, such as a blemish or missing page, may be replicated in our edition. We do, however, repair the vast majority of imperfections successfully; any imperfections that remain are intentionally left to preserve the state of such historical works.

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As 2019 has been declared the International Year of the Periodic Table, it is appropriate that Structure and Bonding marks this anniversary with two special volumes. In 1869 Dmitri Ivanovitch Mendeleev first proposed his periodic table of the elements. He is given the major credit for proposing the conceptual framework used by chemists to systematically inter-relate the chemical properties of the elements. However, the concept of periodicity evolved in distinct stages and was the culmination of work by other chemists over several decades. For example, Newland’s Law of Octaves marked an important step in the evolution of the periodic system since it represented the first clear statement that the properties of the elements repeated after intervals of 8. Mendeleev’s predictions demonstrated in an impressive manner how the periodic table could be used to predict the occurrence and properties of new elements. Not all of his many predictions proved to be valid, but the discovery of scandium, gallium and germanium represented sufficient vindication of its utility and they cemented its enduring influence. Mendeleev’s periodic table was based on the atomic weights of the elements and it was another 50 years before Moseley established that it was the atomic number of the elements, that was the fundamental parameter and this led to the prediction of further elements. Some have suggested that the periodic table is one of the most fruitful ideas in modern science and that it is comparable to Darwin’s theory of evolution by natural selection, proposed at approximately the same time. There is no doubt that the periodic table occupies a central position in chemistry. In its modern form it is reproduced in most undergraduate inorganic textbooks and is present in almost every chemistry lecture room and classroom. This first volume provides chemists with an account of the historical development of the Periodic Table and an overview of how the Periodic Table has evolved over the last 150 years. It also illustrates how it has guided the research programmes of some distinguished chemists.