Organomagnesium Methods In Organic Chemistry
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Organomagnesium Methods in Organic Chemistry
Author | : Basil J. Wakefield |
Publsiher | : Academic Press |
Total Pages | : 249 |
Release | : 1995-03-16 |
Genre | : Science |
ISBN | : 0080538177 |
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The book opens with a general overview of the constitution and reactivity of organomagnesium compounds, followed by information on handling them and on their detection and estimation. Throughout, practical aspects aswell as principles are emphasized. The chapters on the synthesis of organomagnesium compounds cover the preparation of special forms of metallic magnesium and the reaction of magnesium with substrates such as dienes, as well as the traditional preparation of Grignard reagents. Preparations by metallation and metal-halogen exchanges are also included, as are newer methods such as hydromagnesiation of alkenes and alkynes. Systematic coverage is provided on synthetically useful reactions of organomagnesium compounds. Of fundamental importance in organic synthesis are carbon-carbon bond forming reactions; additions to carbon-carbon, carbon-nitrogen, carbon-oxygen, and carbon-sulfur multiple bonds; and nucleophilic substitution at carbon. The formation of carbon-heteroatom bonds in organic compounds is described, where the heteroatom is hydrogen, nitrogen, oxygen, sulfur, or halogen. Finally, the use of organomagnesium compounds in preparing other organometalloid and organometallic compounds is outlined. Representative experimental procedures are included throughout the book, and tables with references to well-described examples are provided. Presents a general overview of the constitution and reactivity of organomagnesium compounds Provides coverage on the detection and estimation of organomagnesium compounds Emphasizes practical aspects as well as principles Covers the preparation of special forms of metallic magnesium and the reaction of magnesium with substrates such as dienes Includes preparations by metallation and metal-halogen exchanges Reviews new preparation methods such as hydromagnesiation of alkenes and alkynes Outlines information on synthetically useful reactions of organomagnesium compounds Describes the formation of carbon-heteroatom bonds in organic compounds Addresses the use of organomagnesium compounds in preparing other organometalloid and organometallic compounds Includes representative procedures and tables with references to well-described examples
The Chemistry of Organomagnesium Compounds
Author | : Zvi Rappoport,Ilan Marek |
Publsiher | : Unknown |
Total Pages | : 474 |
Release | : 2008 |
Genre | : Organomagnesium compounds |
ISBN | : CORNELL:31924108469606 |
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Magnesium remains almost unique among the metals in its ability to react directly with a wide variety of compounds. This organic chemistry field has seen steady progress, and a volume on this topic is long overdue. In the tradition of the "Patai Series", this title treats all aspects of functional groups, containing chapters on the theoretical and computational foundations; on analytical and spectroscopic aspects with dedicated chapters on Mass Spectrometry, NMR, IR/UV, etc.; on reaction mechanisms; and, on applications in syntheses. Depending on the functional group there are also chapters on industrial use, on effects in biological and/or environmental systems. Since the area of Organomagnesium Chemistry continues to grow far beyond the classical Grignard Reagents, this is an essential resource to help the reader keep abreast of the latest developments.
The Chemistry of Organomagnesium Compounds 2 Volume Set
Author | : Zvi Rappoport,Ilan Marek |
Publsiher | : John Wiley & Sons |
Total Pages | : 488 |
Release | : 2008-04-14 |
Genre | : Science |
ISBN | : CORNELL:31924108469598 |
Download The Chemistry of Organomagnesium Compounds 2 Volume Set Book in PDF, Epub and Kindle
Magnesium remains almost unique among the metals in its ability to react directly with a wide variety of compounds. This organic chemistry field has seen steady progress, and a volume on this topic is long overdue. In the tradition of the Patai Series this title treats all aspects of functional groups, containing chapters on the theoretical and computational foundations; on analytical and spectroscopic aspects with dedicated chapters on Mass Spectrometry, NMR, IR/UV, etc.; on reaction mechanisms; on applications in syntheses. Depending on the functional group there are also chapters on industrial use, on effects in biological and/or environmental systems. Since the area of Organomagnesium Chemistry continues to grow far beyond the classical Grignard Reagents, this is an essential resource to help the reader keep abreast of the latest developments.
Houben Weyl Methods of Organic Chemistry Vol XIII 2a 4th Edition
Author | : Anonim |
Publsiher | : Georg Thieme Verlag |
Total Pages | : 1056 |
Release | : 2014-05-14 |
Genre | : Science |
ISBN | : 9783131806543 |
Download Houben Weyl Methods of Organic Chemistry Vol XIII 2a 4th Edition Book in PDF, Epub and Kindle
Houben-Weyl is the acclaimed reference series for preparative methods in organic chemistry, in which all methods are organized accor ding to the class of compound or functional group to be synthesized. The Houben-Weyl volumes contain 146 000 product-specific experi mental procedures, 580 000 structures, and 700 000 references. The preparative significance of the methods for all classes of compou nds is critically evaluated. The series includes data from as far back as the early 1800s to 2003. // The content of this e-book was originally published in 1973.
Organomagnesium Compounds in Synthetic Chemistry
Author | : Clarence Jay West,Henry Gilman |
Publsiher | : Unknown |
Total Pages | : 112 |
Release | : 1922 |
Genre | : Chemistry, Organic |
ISBN | : WISC:89097687313 |
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Modern Methods of Organic Synthesis South Asia Edition
Author | : W Carruthers,Iain Coldham |
Publsiher | : Cambridge University Press |
Total Pages | : 506 |
Release | : 2015-04-10 |
Genre | : Science |
ISBN | : 9781107567450 |
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Textbook on modern methods of organic synthesis.
Organomagnesium Compounds in Synthetic Chemistry
Author | : Clearance Jay West |
Publsiher | : Unknown |
Total Pages | : 114 |
Release | : 1922 |
Genre | : Organomagnesium compounds |
ISBN | : UOM:39015018129158 |
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Organic Chemistry
Author | : Pierre Vogel,Kendall N. Houk |
Publsiher | : John Wiley & Sons |
Total Pages | : 2876 |
Release | : 2019-08-08 |
Genre | : Science |
ISBN | : 9783527819270 |
Download Organic Chemistry Book in PDF, Epub and Kindle
Provides the background, tools, and models required to understand organic synthesis and plan chemical reactions more efficiently Knowledge of physical chemistry is essential for achieving successful chemical reactions in organic chemistry. Chemists must be competent in a range of areas to understand organic synthesis. Organic Chemistry provides the methods, models, and tools necessary to fully comprehend organic reactions. Written by two internationally recognized experts in the field, this much-needed textbook fills a gap in current literature on physical organic chemistry. Rigorous yet straightforward chapters first examine chemical equilibria, thermodynamics, reaction rates and mechanisms, and molecular orbital theory, providing readers with a strong foundation in physical organic chemistry. Subsequent chapters demonstrate various reactions involving organic, organometallic, and biochemical reactants and catalysts. Throughout the text, numerous questions and exercises, over 800 in total, help readers strengthen their comprehension of the subject and highlight key points of learning. The companion Organic Chemistry Workbook contains complete references and answers to every question in this text. A much-needed resource for students and working chemists alike, this text: -Presents models that establish if a reaction is possible, estimate how long it will take, and determine its properties -Describes reactions with broad practical value in synthesis and biology, such as C-C-coupling reactions, pericyclic reactions, and catalytic reactions -Enables readers to plan chemical reactions more efficiently -Features clear illustrations, figures, and tables -With a Foreword by Nobel Prize Laureate Robert H. Grubbs Organic Chemistry: Theory, Reactivity, and Mechanisms in Modern Synthesis is an ideal textbook for students and instructors of chemistry, and a valuable work of reference for organic chemists, physical chemists, and chemical engineers.