Organometallic Magnets

This volume highlights the recent advances and state of art in the experimental and theoretical studies of organometallic magnets. A plethora of organic ligands such as Mannich-base derivatives, redox-active chromophores, cyanides, Schiff base among others are used to coordinate to 3d transition metals, 4f lanthanides and 5f actinides to design the molecular magnets. Deep analysis of the coordination sphere symmetry, electronic distribution, luminescence are investigated to perform magneto-structural correlation leading to a better understanding of the magnetic properties. Furthermore, the rationalization of the magnetic behavior can be reached using ab initio calculations. The multiple applications that these molecular magnets offer could revolutionize the high-density data storage, spintronics and quantum computing technologies. This volume provides a discussion of these topics from leading international experts and will be a useful reference for researchers working in this field.

For several years, the two parallel worlds of Molecular Conductors in one hand and Molecular Magnetism in the other have grown side by side, the former essentially based on radical organic molecules, the latter essentially based on the high spin properties of metal complexes. Over the last few years however, organometallic derivatives have started to play an increasingly important role in both worlds, and have in many ways contributed to open several passages between these two worlds. This volume recognizes this important emerging evolution of both research areas. It is not intended to give a comprehensive view of all possible organometallic materials, and polymers for example were not considered here. Rather we present a selection of the most recent research topics where organometallic derivatives were shown to play a crucial role in the setting of conducting and/or magnetic properties in crystalline materials. First, the role of organometallic anions in tet- thiafulvalenium-based molecular conductors is highlighted by Schlueter, while Kubo and Kato describe very recent ortho-metalated chelating ligands appended to the TTF core and their conducting salts. The combination of conducting and magnetic properties and the search for p–d interactions are analyzed in two comp- mentary contributions by Myazaki and Ouahab, while Valade focuses on the only class of metal bis(dithiolene) complexes to give rise to superconductive molecular materials, in association with organic as well as organometallic cations.

Full coverage of materials and mechanical design in engineering Mechanical Engineers' Handbook, Fourth Edition provides a quick guide to specialized areas you may encounter in your work, giving you access to the basics of each and pointing you toward trusted resources for further reading, if needed. The accessible information inside offers discussions, examples, and analyses of the topics covered. This first volume covers materials and mechanical design, giving you accessible and in-depth access to the most common topics you'll encounter in the discipline: carbon and alloy steels, stainless steels, aluminum alloys, copper and copper alloys, titanium alloys for design, nickel and its alloys, magnesium and its alloys, superalloys for design, composite materials, smart materials, electronic materials, viscosity measurement, and much more. Presents comprehensive coverage of materials and mechanical design Offers the option of being purchased as a four-book set or as single books, depending on your needs Comes in a subscription format through the Wiley Online Library and in electronic and custom formats Engineers at all levels of industry, government, or private consulting practice will find Mechanical Engineers' Handbook, Volume 1 a great resource they'll turn to repeatedly as a reference on the basics of materials and mechanical design.

Traditionally, magnetic materials have been metals or, if inorganic compounds such as oxides, of continuous lattice type. However, in recent years chemists have synthesized increasing numbers of crystalline solids based on molecular building blocks in the form of coordination and organometallic complexes or purely organic molecules, which exhibit spontaneous magnetization. In striking contrast to conventional magnets, these materials are made from solutions close to room temperature rather than by metallurgical or ceramic methods. This book, which originates from contributions to a Discussion Meeting of The Royal Society of London, brings together many of the leading international practitioners in the field, who survey their own recent work and place it in the context of the wider fields of magnetism and supramolecular chemistry. All aspects of molecular-based magnets are addressed, including synthesis, structure-property relations and physical properties. Contents include details of the characterization of the first purely organic ferromagnet, the synthesis of high coercivity materials and a unique description of new materials with Curie temperatures well above ambient. A coherent survey of this rapidly developing field for the more general reader, Metal-Organic and Organic Molecular Magnets will also be welcomed by researchers and lecturers in materials science and inorganic or solid state chemistry.

Erstmals in einem Band werden Werkstoffe hier (in zwei getrennten Systemen) sowohl nach ihrer technischen Anwendung als auch nach ihren Eigenschaften geordnet. - Benutzer können deshalb zunächst nach der Gruppe von Materialen suchen, die für eine spezielle Anwendung geeignet sind, und anschließend Details über jedes einzelne Material finden - Suchkriterien sind Eigenschaften wie Wärmeleitfähigkeit, optisches Reflexionsvermögen, Elastizität usw. und Anwendungsgebiete wie Bauwesen, Biomedizin, Fahrzeugbau, Luftfahrttechnik, Elektrotechnik usw. - berücksichtigt werden sowohl herkömmliche Werkstoffe (Eisen- und Nichteisenmetalle, Kunststoffe, Klebstoffe) als auch Kompositwerkstoffe und synthetische Materialen wie Laminate, Fasern und Keramiken

This Specialist Periodical Report aims to reflect the growing interest in the potential of organometallic chemistry.

This volume covers both basic and advanced aspects of organometallic chemistry of all metals and catalysis. In order to present a comprehensive view of the subject, it provides broad coverage of organometallic chemistry itself. The catalysis section includes the challenging activation and fictionalization of the main classes of hydrocarbons and the industrially crucial heterogeneous catalysis. Summaries and exercises are provides at the end of each chapter, and the answers to these exercises can be found at the back of the book. Beginners in inorganic, organic and organometallic chemistry, as well as advanced scholars and chemists from academia and industry will find much value in this title.

Proceedings of the NATO Advanced Research Workshop, Cap d'Agde, France, September 9-14, 1990