Ozone In The Troposphere And The Stratosphere

Stratospheric processes play a signi?cant role in regulating the weather and c- mate of the Earth system. Solar radiation, which is the primary source of energy for the tropospheric weather systems, is absorbed by ozone when it passes through the stratosphere, thereby modulating the solar-forcing energy reaching into the t- posphere. The concentrations of the radiatively sensitive greenhouse gases present in the lower atmosphere, such as water vapor, carbon dioxide, and ozone, control the radiation balance of the atmosphere by the two-way interaction between the stratosphere and troposphere. The stratosphere is the transition region which interacts with the weather s- tems in the lower atmosphere and the richly ionized upper atmosphere. Therefore, this part of the atmosphere provides a long list of challenging scienti?c problems of basic nature involving its thermal structure, energetics, composition, dynamics, chemistry, and modeling. The lower stratosphere is very much linked dynamically, radiatively,and chemically with the upper troposphere,even though the temperature characteristics of these regions are different. The stratosphere is a region of high stability, rich in ozone and poor in water - por and temperature increases with altitude. The lower stratospheric ozone absorbs the harmful ultraviolet (UV) radiation from the sun and protects life on the Earth. On the other hand, the troposphere has high concentrations of water vapor, is low in ozone, and temperature decreases with altitude. The convective activity is more in the troposphere than in the stratosphere.

Peter Fabian and Martin Dameris provide a concise yet comprehensive overview of established scientific knowledge about ozone in the atmosphere. They present both ozone changes and trends in the stratosphere, as well as the effects of overabundance in the troposphere including the phenomenon of photosmog. Aspects such as photochemistry, atmospheric dynamics and global ozone distribution as well as various techniques for ozone measurement are treated. The authors outline the various causes for ozone depletion, the effects of ozone pollution and the relation to climate change. The book provides a handy reference guide for researchers active in atmospheric ozone research and a useful introduction for advanced students specializing in this field. Non-specialists interested in this field will also profit from reading the book. Peter Fabian can look back on a life-long active career in ozone research, having first gained international recognition for his measurements of the global distribution of halogenated hydrocarbons. He also pioneered photosmog investigations in the metropolitan areas of Munich, Berlin, Athens and Santiago de Chile, and his KROFEX facility provided controlled ozone fumigation of adult tree canopies for biologists to investigate the effects of ozone increases on forests. Besides having published a broad range of scientific articles, he has also been the author or editor of numerous books. From 2002 to 2005 he served the European Geosciences Union (EGU) as their first and Founding President. Martin Dameris is a prominent atmospheric modeler whose interests include the impacts of all kinds of natural and man-made disturbances on the atmospheric system. His scientific work focuses on the connections between ozone and climate changes. For many years he has been an active contributor to the WMO scientific ozone depletion assessments, which have been used to monitor the depletion and recovery of the ozone layer in accordance with the Montreal Protocol.

Abstract: The papers presented at the 1992 Quadrennial Ozone Symposium held in Charlottesville, Virginia, cover topics in both tropospheric and stratospheric research. These topics include ozone trends and climatology, ground based, aircraft, balloon, rocket and satellite measurements, artic and antarctic research, global and regional modeling, and volcanic effects.

The main objective of the workshop was to increase our knowledge of ozone formation and distribution in the troposphere, its relation to precursor (NO~ and HC species) distribution, how it is affected by transport processes in the troposphere, and to show how the increasing levels of ozone can cause environmental problem. The focus was on the interaction of ozone on regional and global scales. There is mounting evidence that such interactions occur and that the ozone levels are increasing in most of the Northern Hemisphere tropo sphere. A likely source of ozone increase is human activity. As result of this, tropospheric climate may change significantly within a few decades, either through direct effects by ozone itself or indirectly through its effect on other radiatively active trace species. Further more, ozone may have adverse effects on vegetation over large continental areas due to enhanced levels which have been measured to take place. As it is well known that ozone plays a key role in the oxidation of a large number of chemical species in the troposphere, natural as well as man-made, the atmospheric distribution of important trace species like sulfur dioxide, nitrogen oxides and hydrocarbons could be markedly changed as a result of ozone changes. The rapidly increasing interest in tropospheric ozone, and the key role ozone plays in several atmospheric areas as well the obvious increase in the tropospheric concentration of ozone made ozone a natural choice as a topic for the workshop.