Proton Exchange Membrane Fuel Cells Modeling

The fuel cell is a potential candidate for energy storage andconversion in our future energy mix. It is able to directly convertthe chemical energy stored in fuel (e.g. hydrogen) intoelectricity, without undergoing different intermediary conversionsteps. In the field of mobile and stationary applications, it isconsidered to be one of the future energy solutions. Among the different fuel cell types, the proton exchange membrane(PEM) fuel cell has shown great potential in mobile applications,due to its low operating temperature, solid-state electrolyte andcompactness. This book presents a detailed state of art of PEM fuel cellmodeling, with very detailed physical phenomena equations indifferent physical domains. Examples and a fully coupledmulti-physical 1.2 kW PEMFC model are given help the reader betterunderstand how to use the equations.

This book examines the characteristics of Proton Exchange Membrane (PEM) Fuel Cells with a focus on deriving realistic finite element models. The book also explains in detail how to set up measuring systems, data analysis, and PEM Fuel Cells’ static and dynamic characteristics. Covered in detail are design and operation principles such as polarization phenomenon, thermodynamic analysis, and overall voltage; failure modes and mechanisms such as permanent faults, membrane degradation, and water management; and modelling and numerical simulation including semi-empirical, one-dimensional, two-dimensional, and three-dimensional models. It is appropriate for graduate students, researchers, and engineers who work with the design and reliability of hydrogen fuel cells, in particular proton exchange membrane fuel cells.

Although, the basic concept of a fuel cell is quite simple, creating new designs and optimizing their performance takes serious work and a mastery of several technical areas. PEM Fuel Cell Modeling and Simulation Using Matlab, provides design engineers and researchers with a valuable tool for understanding and overcoming barriers to designing and building the next generation of PEM Fuel Cells. With this book, engineers can test components and verify designs in the development phase, saving both time and money. Easy to read and understand, this book provides design and modelling tips for fuel cell components such as: modelling proton exchange structure, catalyst layers, gas diffusion, fuel distribution structures, fuel cell stacks and fuel cell plant. This book includes design advice and MATLAB and FEMLAB codes for Fuel Cell types such as: polymer electrolyte, direct methanol and solid oxide fuel cells. This book also includes types for one, two and three dimensional modeling and two-phase flow phenomena and microfluidics. *Modeling and design validation techniques *Covers most types of Fuel Cell including SOFC *MATLAB and FEMLAB modelling codes *Translates basic phenomena into mathematical equations

This book is a comprehensive introduction to the rapidly developing field of modeling and characterization of PEM fuel cells. It focuses on i) fuel cell performance modeling and performance characterization applicable from single cells to stacks, ii) fundamental and advanced techniques for structural and compositional characterization of fuel cell components and iii) electrocatalyst design. Written by experts in this field, this book is an invaluable tool for graduate students and professionals.

Water and Thermal Management of Proton Exchange Membrane Fuel Cells introduces the main research methods and latest advances in the water and thermal management of PEMFCs. The book introduces the transport mechanism of each component, including modeling methods at different scales, along with practical exercises. Topics include PEMFC fundamentals, working principles and transport mechanisms, characterization tests and diagnostic analysis, the simulation of multiphase transport and electrode kinetics, cell-scale modeling, stack-scale modeling, and system-scale modeling. This volume offers a practical handbook for researchers, students and engineers in the fields of proton exchange membrane fuel cells. Proton exchange membrane fuel cells (PEMFCs) are high-efficiency and low-emission electrochemical energy conversion devices. Inside the PEMFC complex, physical and chemical processes take place, such as electrochemical reaction, multiphase flow and heat transfer. This book explores these topics, and more. Introduces the transport mechanism for each component of PEMFCs Presents modeling methods at different scales, including component, cell, stack and system scales Provides exercises in PEMFC modeling, along with examples of necessary codes Covers the latest advances in PEMFCs in a convenient and structured manner Offers a solution to researchers, students and engineers working on proton exchange membrane fuel cells

The second edition of PEM Fuel Cell Modeling and Simulation provides design engineers and researchers with a valuable and completely updated tool for understanding and overcoming barriers to designing and building fuel cells and fuel cell systems. Starting from the basic concept of a fuel cell, this book presents tools for creating new designs and optimizing their performance. It provides information on how to test components and verify designs in the development phase, saving both time and money. Also included are design and modelling tips for fuel cell components such as exchange structure, catalyst layers, gas diffusion and fuel distribution structures, as well as for fuel cell stacks and fuel cell plants. MATLAB® and FEMLAB codes for polymer electrolyte, direct methanol and solid oxide fuel cells are made available, covering types for one, two and three dimensional modeling and two-phase flow phenomena and microfluidics. Chapters have been updated and/or expanded in this new edition. New sections have been added to bring more details on topics like degradation in the proton exchange membrane and the catalyst layer, effect of compression of the gas diffusion layer, hydrogen and oxygen crossover modeling, transient behavior modeling, fuel cell modeling assumptions and limitations, fuel cell systems design for vehicles and buildings. It is an indispensable reference for all those involved in fuel cell modeling, especially engineers involved in planning and simulating fuel cell systems or fuel cell integration into energy systems, energy researchers interested in modeling all aspects of fuel cells, from individual components to entire systems, and graduate students entering this field. This new edition has been updated to include the most current knowledge in the field, and its content has been expanded to cover several new topics, such as degradation in the proton exchange membrane and the catalyst layer, effect of compression of the gas diffusion layer, hydrogen and oxygen crossover modeling, transient behavior modeling, fuel cell modeling assumptions and limitations, fuel cell systems design for vehicles and buildings Includes MATLAB® and FEMLAB modelling codes applicable for polymer electrolyte, direct methanol and solid oxide fuel cells Translates basic phenomena into mathematical equations

The book presents the modeling and control of hydrogen-air PEM fuel cells, including simultaneous estimation of the parameters and states, fuzzy cluster modeling, SPM-based predictive control and advanced fuzzy control. MATLAB/Simulink-based modeling and control programs are discussed in detail. With simulations and experiments, it is an essential reference for both scientists and industrial engineers.

The expected end of the “oil age” will lead to increasing focus and reliance on alternative energy conversion devices, among which fuel cells have the potential to play an important role. Not only can phosphoric acid and solid oxide fuel cells already efficiently convert today’s fossil fuels, including methane, into electricity, but other types of fuel cells, such as polymer electrolyte membrane fuel cells, have the potential to become the cornerstones of a possible future hydrogen economy. This handbook offers concise yet comprehensive coverage of the current state of fuel cell research and identifies key areas for future investigation. Internationally renowned specialists provide authoritative introductions to a wide variety of fuel cell types and hydrogen production technologies, and discuss materials and components for these systems. Sustainability and marketing considerations are also covered, including comparisons of fuel cells with alternative technologies.