Prussian Blue Based Batteries

This book reviews the structure and composition of Prussian Blue materials. It presents the state-of-the-art of their application to metal-ion batteries, highlighting the benefits derived from the integration of electrochemical energy storage with clean energies. It concludes with future perspectives including prototyping and large-scale production.

This book covers both the fundamental and applied aspects of advanced Na-ion batteries (NIB) which have proven to be a potential challenger to Li-ion batteries. Both the chemistry and design of positive and negative electrode materials are examined. In NIB, the electrolyte is also a crucial part of the batteries and the recent research, showing a possible alternative to classical electrolytes – with the development of ionic liquid-based electrolytes – is also explored. Cycling performance in NIB is also strongly associated with the quality of the electrode-electrolyte interface, where electrolyte degradation takes place; thus, Na-ion Batteries details the recent achievements in furthering knowledge of this interface. Finally, as the ultimate goal is commercialization of this new electrical storage technology, the last chapters are dedicated to the industrial point of view, given by two startup companies, who developed two different NIB chemistries for complementary applications and markets.

Nanochemistry tools aid the design of Prussian blue and its analogue nanoparticles and nanocomposites. The use of such nanomaterials is now widely regarded as an alternative to other inorganic nanomaterials in a variety of scientific applications. This book, after addressing Prussian blue and its analogues in a historical context and their numerous applications over time, compiles and details the latest cutting-edge scientific research on these nanomaterials. It compiles and deatils the latest cutting-edge scientific research on these nanomaterials. The book provides an overview of the methodological concepts of the nanoscale synthesis of Prussian blue and its analogues, as well as the study and understanding of their properties and of the extent and diversity of application fields in relation to the major societal challenges of the 21st century on energy, environment, and health.

Presents uparalleled coverage of Na-ion battery technology, including the most recent research and emerging applications Na-ion battery technologies have emerged as cost-effective, environmentally friendly alternatives to Li-ion batteries, particularly for large-scale storage applications where battery size is less of a concern than in portable electronics or electric vehicles. Scientists and engineers involved in developing commercially viable Na-ion batteries need to understand the state-of-the-art in constituent materials, electrodes, and electrolytes to meet both performance metrics and economic requirements. Sodium-Ion Batteries: Materials, Characterization, and Technology provides in-depth coverage of the material constituents, characterization, applications, upscaling, and commercialization of Na-ion batteries. Contributions by international experts discuss the development and performance of cathode and anode materials and their characterization - using methods such as NMR spectroscopy, magnetic resonance imaging (MRI), and computational studies - as well as ceramics, ionic liquids, and other solid and liquid electrolytes. Discusses the development of battery technology based on the abundant alkali ion sodium Features a thorough introduction to Na-ion batteries and their comparison with Li-ion batteries Reviews recent research on the structure-electrochemical performance relationship and the development of new solid electrolytes Includes a timely overview of commercial perspectives, cost analysis, and safety issues of Na-ion batteries Covers emerging technologies including Na-ion capacitors, aqueous sodium batteries, and Na-S batteries The handbook Sodium-Ion Batteries: Materials, Characterization, and Technology is an indispensable reference for researchers and development engineers, materials scientists, electrochemists, and engineering scientists in both academia and industry.

Battery technology is constantly changing, and the concepts and applications of these changes are rapidly becoming increasingly more important as more and more industries and individuals continue to make “greener” choices in their energy sources. As global dependence on fossil fuels slowly wanes, there is a heavier and heavier importance placed on cleaner power sources and methods for storing and transporting that power. Battery technology is a huge part of this global energy revolution. Potassium-ion batteries were first introduced to the world for energy storage in 2004, over two decades after the invention of lithium-ion batteries. Potassium-ion (or “K-ion”) batteries have many advantages, including low cost, long cycle life, high energy density, safety, and reliability. Potassium-ion batteries are the potential alternative to lithium-ion batteries, fueling a new direction of energy storage research in many applications and across industries. Potassium-ion Batteries: Materials and Applications explores the concepts, mechanisms, and applications of the next-generation energy technology of potassium-ion batteries. Also included is an in-depth overview of energy storage materials and electrolytes. This is the first book on this technology and serves as a reference guide for electrochemists, chemical engineers, students, research scholars, faculty, and R&D professionals who are working in electrochemistry, solid-state science, material science, ionics, power sources, and renewable energy storage fields.

The need for batteries has grown exponentially in response to the increase in global energy demand and to the ambitious goals that governments have set up for sustainable energy development worldwide, especially in developed countries. While lithium-ion batteries currently dominate the energy storage market, the limited and unevenly distributed lithium resources have caused huge concerns over the sustainability of the lithium-ion battery technology. Sodium-ion batteries have significant benefits over lithium-ion batteries, including sodium’s abundance in the Earth’s crust. These batteries have therefore gained research interest, and efforts are being made to use them in place of lithium-ion batteries. While the past decade has witnessed significant research advances and breakthroughs in developing the sodium-ion battery technology, there still remain fundamental challenges that must be overcome to push the technology forward. This book comprises 13 chapters that discuss the fundamental challenges, electrode materials, electrolytes, separators, advanced instrumental analysis techniques, and computational methods for sodium-ion batteries from renowned scientists. The book is a unique combination of all aspects associated with sodium-ion batteries and can therefore be used as a handbook.

The book covers basic theory, progress and applications of sodium-ion batteries. It intoduces the reader to anode, cathode, electrolyte battery materials and properties. It also describes compatibility and stability of the whole battery system. It is a valuable resource for anyone interested in energy storage.

Practice-oriented guide systematically summarizing and condensing the development, directions, potential, and core issues of sodium-ion batteries Sodium-Ion Batteries begins with an introduction to sodium-ion batteries (SIBs), including their background, development, definition, mechanism, and classification/configuration, moving on to summarize cathode and anode materials, discuss electrolyte, separator, and other key technologies and devices, and review practical applications and conclusions/prospects of sodium-ion batteries. The text promotes the idea that SIBs can be a good complement, or even a strong competitor, to more mainstream energy technologies in specific application scenarios, including but not limited to large-scale grid energy storage, distributed energy storage, and low-speed electric vehicles, by virtue of considerable advantages in cost-effectiveness compared with lithium-ion, lead-acid, and vanadium redox flow batteries. This book delves into what we have done, where we are, and how we should proceed in regards to the advancement of SIBs, in order to make the technology more applicable in real-world situations. Specific sample topics covered in Sodium-Ion Batteries include: Electrochemical test techniques, including cyclic voltammetry, galvanostatic charge-discharge, and electrochemical impedance spectroscopy Advanced characterization techniques and theoretical calculation, covering imaging and microscopy, and the synchrotron radiation x-ray diffraction technique Designing and manufacturing SIBs, covering types of cells (cylindrical, soft-pack, and psitmatic), and design requirements for cells Performance tests and failure analysis, covering electrochemical and safety performances test, failure phenomenon, failure analysis method, and cost estimation Solid-state nuclear magnetic resonance spectroscopy, covering principles of ssNMR and shift ranges for battery materials A complete review of an exciting energy storage technology that is undergoing a crucial development stage, Sodium-Ion Batteries is an essential resource for materials scientists, inorganic and physical chemists, and all other academics, researchers, and professionals who wish to stay on the cutting edge of energy technology.