Solar Cell Device Physics

Solar Cell Device Physics offers a balanced, in-depth qualitative and quantitative treatment of the physical principles and operating characteristics of solar cell devices. Topics covered include photovoltaic energy conversion and solar cell materials and structures, along with homojunction solar cells. Semiconductor-semiconductor heterojunction cells and surface-barrier solar cells are also discussed. This book consists of six chapters and begins by introducing the reader to the basic physical principles and materials properties that are the foundations of photovoltaic energy conversion, with emphasis on various photovoltaic devices capable of efficiently converting solar energy into usable electrical energy. The electronic and optical properties of crystalline, polycrystalline, and amorphous materials with both organic and inorganic materials are considered, together with the manner in which these properties change from one material class to another and the implications of such changes for photovoltaics. Generation, recombination, and bulk transport are also discussed. The two mechanisms of photocarrier collection in solar cells, drift and diffusion, are then compared. The remaining chapters focus on specific solar cell device classes defined in terms of the interface structure employed: homojunctions, semiconductor-semiconductor heterojunctions, and surface-barrier devices. This monograph is appropriate for use as a textbook for graduate students in engineering and the sciences and for seniors in electrical engineering and applied physics, as well as a reference book for those actively involved in solar cell research and development.

This book provides a comprehensive introduction to the physics of the photovoltaic cell. It is suitable for undergraduates, graduate students, and researchers new to the field. It covers: basic physics of semiconductors in photovoltaic devices; physical models of solar cell operation; characteristics and design of common types of solar cell; and approaches to increasing solar cell efficiency. The text explains the terms and concepts of solar cell device physics and shows the reader how to formulate and solve relevant physical problems. Exercises and worked solutions are included.

This book contains detailed information on the types, structure, fabrication, and characterization of organic solar cells (OSCs). It discusses processes to improve efficiencies and the prevention of degradation in OSCs. It compares the cost-effectiveness of OSCs to those based on crystalline silicon and discusses ways to make OSCs more economical. This book provides a practical guide for the fabrication, processing, and characterization of OSCs and paves the way for further development in OSC technology.

Organic solar cells have emerged as new promising photovoltaic devices due to their potential applications in large area, printable and flexible solar panels. Organic Solar Cells: Materials and Device Physics offers an updated review on the topics covering the synthesis, properties and applications of new materials for various critical roles in devices from electrodes, interface and carrier transport materials, to the active layer composed of donors and acceptors. Addressing the important device physics issues of carrier and exciton dynamics and interface stability and novel light trapping structures, the potential for hybrid organic solar cells to provide high efficiency solar cells is examined and discussed in detail. Specific chapters covers key areas including: Latest research and designs for highly effective polymer donors/acceptors and interface materials Synthesis and application of highly transparent and conductive graphene Exciton and charge dynamics for in-depth understanding of the mechanism underlying organic solar cells. New potentials and emerging functionalities of plasmonic effects in OSCs Interface Degradation Mechanisms in organic photovoltaics improving the entire device lifetime Device architecture and operation mechanism of organic/ inorganic hybrid solar cells for next generation of high performance photovoltaics This reference can be practically and theoretically applied by senior undergraduates, postgraduates, engineers, scientists, researchers, and project managers with some fundamental knowledge in organic and inorganic semiconductor materials or devices.

As part of the effort to increase the contribution of solar cells (photovoltaics) to our energy mix, this book addresses three main areas: making existing technology cheaper, promoting advanced technologies based on new architectural designs, and developing new materials to serve as light absorbers. Leading scientists throughout the world create a fundamental platform for knowledge sharing that combines the physics, materials, and device architectures of high-efficiency solar cells. While providing a comprehensive introduction to the field, the book highlights directions for further research, and is intended to stimulate readers’ interest in the development of novel materials and technologies for solar energy applications.

The new edition of this highly regarded textbook provides a detailed overview of the most important characterization techniques for solar cells and a discussion of their advantages and disadvantages. It describes in detail all aspects of solar cell function, the physics behind every single step, as well as all the issues to be considered when improving solar cells and their efficiency. The text is now complete with examples of how the appropriate characterization techniques enable the distinction between several potential limitation factors, describing how quantities that have been introduced theoretically in earlier chapters become experimentally accessible. With exercises after each chapter to reinforce the newly acquired knowledge and requiring no more than standard physics knowledge, this book enables students and professionals to understand the factors driving conversion efficiency and to apply this to their own solar cell development.

This book covers in a textbook-like fashion the basics or organic solar cells, addressing the limits of photovoltaic energy conversion and giving a well-illustrated introduction to molecular electronics with focus on the working principle and characterization of organic solar cells. Further chapters based on the author’s dissertation focus on the electrical processes in organic solar cells by presenting a detailed drift-diffusion approach to describe exciton separation and charge-carrier transport and extraction. The results, although elaborated on small-molecule solar cells and with focus on the zinc phthalocyanine: C60 material system, are of general nature. They propose and demonstrate experimental approaches for getting a deeper understanding of the dominating processes in amorphous thin-film based solar cells in general. The main focus is on the interpretation of the current-voltage characteristics (J-V curve). This very standard measurement technique for a solar cell reflects the electrical processes in the device. Comparing experimental to simulation data, the author discusses the reasons for S-Shaped J-V curves, the role of charge carrier mobilities and energy barriers at interfaces, the dominating recombination mechanisms, the charge carrier generation profile, and other efficiency-limiting processes in organic solar cells. The book concludes with an illustrative guideline on how to identify reasons for changes in the J-V curve. This book is a suitable introduction for students in engineering, physics, material science, and chemistry starting in the field of organic or hybrid thin-film photovoltaics. It is just as valuable for professionals and experimentalists who analyze solar cell devices.

The book provides an explanation of the operation of photovoltaic devices from a broad perspective that embraces a variety of materials concepts, from nanostructured and highly disordered organic materials, to highly efficient devices such as the lead halide perovskite solar cells. The book establishes from the beginning a simple but very rich model of a solar cell, in order to develop and understand step by step the photovoltaic operation according to fundamental physical properties and constraints. It emphasizes the aspects pertaining to the functioning of a solar cell and the determination of limiting efficiencies of energy conversion. The final chapters of the book establish a more refined and realistic treatment of the many factors that determine the actual performance of experimental devices: transport gradients, interfacial recombination, optical losses and so forth. The book finishes with a short review of additional important aspects of solar energy conversion, such as the photonic aspects of spectral modification, and the direct conversion of solar photons to chemical fuel via electrochemical reactions.