Solidification

“Principles of Solidification” offers comprehensive descriptions of liquid-to-solid transitions encountered in shaped casting, welding, and non-biological bulk crystal growth processes. The book logically develops through careful presentation of relevant thermodynamic and kinetic theories and models of solidification occurring in a variety of materials. Major topics encompass the liquid-state, liquid-solid transformations, chemical macro- and microsegregation, purification by fractional crystallization and zone refining, solid-liquid interfaces, polyphase freezing, and rapid solidification processing. Solid-liquid interfaces are discussed quantitatively both as sharp and diffuse entities, with supporting differential geometric descriptions. The book offers: • Detailed mathematical examples throughout to guide readers • Applications of solidification and crystal growth methodologies for preparation and purification of metals, ceramics, polymers and semiconductors • Appendices providing supporting information on special topics covered in the chapters. Readers in materials, metallurgical, chemical, and mechanical engineering will find this to be a useful source on the subjects of solidification and crystal growth. Chemists, physicists, and geologists concerned with melting/freezing phenomena will also find much of value in this book.

Solidification is one of the oldest processes for producing useful implements and remains one of the most important modern commercial processes. This text describes the fundamentals of the technology in a coherent way, using consistent notation.

The 3rd edition of this popular textbook covers current topics in all areas of casting solidification. Partial differential equations and numerical analysis are used extensively throughout the text, with numerous calculation examples, to help the reader in achieving a working knowledge of computational solidification modeling. The features of this new edition include: • new chapters on semi-solid and metal matrix composites solidification • a significantly extended treatment of multiscale modeling of solidification and its applications to commercial alloys • a survey of new topics such as solidification of multicomponent alloys and molecular dynamic modeling • new theories, including a theory on oxide bi-films in the treatment of shrinkage problems • an in-depth treatment of the theoretical aspects of the solidification of the most important commercial alloys including steel, cast iron, aluminum-silicon eutectics, and superalloys • updated tables of material constants.

All metallic materials are prepared from the liquid state as their parent phase. Solidification is therefore one of the most important phase transformation in daily human life. Solidification is the transition from liquid to solid state of matter. The conditions under which material is transformed determines the physical and chemical properties of the as-solidified body. The processes involved, like nucleation and crystal growth, are governed by heat and mass transport. Convection and undercooling provide additional processing parameters to tune the solidification process and to control solid material performance from the very beginning of the production chain. To develop a predictive capability for efficient materials production the processes involved in solidification have to be understood in detail. This book provides a comprehensive overview of the solidification of metallic melts processed and undercooled in a containerless manner by drop tube, electromagnetic and electrostatic levitation, and experiments in reduced gravity. The experiments are accompanied by model calculations on the influence of thermodynamic and hydrodynamic conditions that control selection of nucleation mechanisms and modify crystal growth development throughout the solidification process.

This monograph comprehensively describes phenomena of heat flow during phase change as well as the dynamics of liquid solidification, i.e. the development of a solidified layer. The book provides the reader with basic knowledge for practical designs, as well as with equations which describe processes of energy transformation. The target audience primarily comprises researchers and experts in the field of heat flow, but the book may also be beneficial for both practicing engineers and graduate students.

The processes of freezing and melting were present at the beginnings of the Earth and continue to dominate the natural and industrial worlds. The solidification of a liquid or the melting of a solid involves a complex interplay of many physical effects. This 2001 book presents in a systematic way the field of continuum solidification theory based on instability phenomena. An understanding of the physics is developed by using examples of increasing complexity with the object of creating a deep physical insight applicable to more complex problems. Applied mathematicians, engineers, physicists, and materials scientists will all find this volume of interest.

The phase transformation from liquid to solid is a phenomenon central to a wide range of manufacturing and natural processes. The presence of phase transformation can drive convection in the melt through the liberation of latent heat, the rejection of solute, and the change of density upon freezing. The fluid mechanics itself can playa central role; the phase transformation can be strongly altered by convective transport in the liquid through the modification of the thermal and solutal environment of the solid-liquid interface; these local fields control the freezing characteristics at the interface. The convection can be generated naturally by buoyancy forces arising from gradients of temperature and concentration in the liquid, by density changes upon freezing, and by thermocapillary and solutocapillary forces on liquid-solid interfaces. The interactive coupling between solidification and convection forms the subject of this volume. Such coupled processes are significant on a large range of scales. Among the applications of interest are the manufacture of single crystals, the processing of surfaces using laser or molecular beams, and the processes of soldering and welding. One wants to understand and predict macrosegregation in castings, transport and fractionation in geological and geophysical systems, and heat accumulation in energy redistribution and storage systems. This volume contains papers presented at the NATO Advanced Research Workshop on "Interactive Dynamics of Convection and Solidification" held in Chamonix, France, March 8-13, 1992.

Written by leading experts in their respective fields, Solidification and Casting provides a comprehensive review of topics fundamental to metallurgy and materials science as well as indicates recent trends. From an industrial perspective, the book begins with chapters on the casting techniques most commonly used in industry today. It then d