Superhydrophobic Polymer Coatings

Superhydrophobic Polymer Coatings: Fundamentals, Design, Fabrication, and Applications offers a comprehensive overview of the preparation and applications of polymer coatings with superhydrophobicity, guiding the reader through advanced techniques and scientific principles. Sections present detailed information on the fundamental theories and methods behind the preparation of superhydrophobic polymer coatings and demonstrate the current and potential applications of these materials, covering a range of novel and marketable uses across industry, including coatings with properties such as foul resistance and self-cleaning, anti-icing and ice-release, corrosion inhibition, antibacterial, anti-reflection, slip and drag reduction, oil-water separation, and advanced medical applications. This book is a highly valuable resource for academic researchers, scientists and advanced students working on polymer coatings or polymer surface modifications, as well as professionals across polymer science, polymer chemistry, plastics engineering, and materials science. The detailed information in this book will also be of great interest to scientists, R&D professionals, product designers and engineers who are looking to develop products with superhydrophobic coatings. Presents in-depth information on the advanced methods required in the preparation of superhydrophobic polymer coatings Covers the latest advances in the design of polymer coatings with superhydrophobic properties, including nanofabrication Explains cutting-edge industrial and medical applications, including self-cleaning coatings, corrosion inhibition, anti-icing and ice-release, and oil-water separation

The explores the cutting-edge technology of polymer coatings. It discusses fundamentals, fabrication strategies, characterization techniques, and allied applications in fields such as corrosion, food, pharmaceutical, biomedical systems and electronics. It also discusses a few new innovative self-healing, antimicrobial and superhydrophobic polymer coatings. Current industrial applications and possible potential activities are also discussed.

Polymer Coatings: Technologies and Applications provides a comprehensive account of the recent developments in polymer coatings encompassing novel methods, techniques, and a broad spectrum of applications. The chapters explore the key aspects of polymer coatings while highlighting fundamental research, different types of polymer coatings, and technology advances. This book also integrates the various aspects of these materials from synthesis to application. Current status, trends, future directions, and opportunities are also discussed. FEATURES Examines the basics to the most recent advances in all areas of polymer coatings Serves as a one-stop reference Discusses polymer-coated nanocrystals and coatings based on nanocomposites Describes morphology, spectroscopic analysis, adhesion, and rheology of polymer coatings Explores conducting, stimuli-responsive, self-healing, hydrophobic and hydrophilic, antifouling, and antibacterial polymer coatings Covers modeling and simulation With contributions from the top international researchers from industry, academia, government, and private research institutions, both new and experienced readers will benefit from this applications-oriented book. Sanjay Mavinkere Rangappa is a research scientist at the Natural Composites Research Group Lab, Academic Enhancement Department, King Mongkut’s University of Technology North Bangkok, Thailand. Jyotishkumar Parameswaranpillai is a research professor at the Center of Innovation in Design and Engineering for Manufacturing, King Mongkut’s University of Technology North Bangkok, Thailand. Suchart Siengchin is a professor at and president of King Mongkut’s University of Technology North Bangkok, Thailand.

Focusing on a variety of coatings, this book provides detailed discussion on preparation, novel techniques, recent developments, and design theories to present the advantages of each function and provide the tools for better product performance and properties. • Presents advantages and benefits of properties and applications of the novel coating types • Includes chapters on specific and novel coatings, like nanocomposite, surface wettability tunable, stimuli-responsive, anti-fouling, antibacterial, self-healing, and structural coloring • Provides detailed discussion on recent developments in the field as well as current and future perspectives • Acts as a guide for polymer and materials researchers in optimizing polymer coating properties and increasing product performance

Surface properties play critical roles in determining the durability and overall performance of polymeric materials for applications in many different fields. Recent investigations on naturally superhydrophobic surfaces such as plant leaves and insect wings led to a clear understanding of the close relationship between surface topography, roughness, chemical structure and superhydrophobicity. This led to a dramatic increase in research efforts on the preparation and characterisation of polymeric systems with superhydrophobic surfaces. Current and potential uses of such materials in a wide range of applications also make them commercially very attractive.The main focus of this book is to provide a comprehensive overview of the new developments regarding the preparation and characterisation of superhydrophobic polymeric surfaces. A large number of methods used in the preparation of robust and durable superhydrophobic polymer surfaces and their advantages and disadvantages are discussed. Close relationship between the polymer composition, hierarchical micro/nano surface topography and superhydrophobic behavior are provided. In addition to the practical aspects, special emphasis is also given to the discussion of the theoretical foundations of the wetting behavior of rough surfaces.Nature is the ultimate guide for the preparation of functional materials and surfaces. As discussed in detail in the book, using biomimetic approaches it is possible to design and produce superhydrophobic surfaces with interesting functionalities. The most critical tasks for the scientists and engineers working in the field seem to be; (i) to clearly understand the relations between surface compositions, topography and surface properties; (ii) to develop simple laboratory techniques and commercially viable production methods to produce superhydrophobic surfaces and devices mimicking the natural systems; and (iii) to demonstrate novel applications in research laboratory and develop commercial applications for these materials with smart and multifunctional surfaces.This book provides a clear understanding of the theoretical foundations of superhydrophobicity together with practical experimental guidance for the preparation of such polymeric surfaces to researchers and application engineers working in the field.

A practical guide to polymer coatings that covers all aspects from materials to applications Polymer Coatings is a practical resource that offers an overview of the fundamentals to the synthesis, characterization, deposition methods, and recent developments of polymer coatings. The text includes information about the different polymers and polymer networks in use, resins for solvent- and water-based coatings, and a variety of additives. It presents deposition methods that encompass frequently used mechanical and electrochemical approaches, in addition to the physical-chemical aspects of the coating process. The author covers the available characterization methods including spectroscopic, morphological, thermal and mechanical techniques. The comprehensive text also reviews developments in selected technology areas such as electrically conductive, anti-fouling, and self-replenishing coatings. The author includes insight into the present status of the research field, describes systems currently under investigation, and draws our attention to yet to be explored systems. This important text: • Offers a thorough overview of polymer coatings and their applications • Covers different classes of materials, deposition methods, coating processes, and ways of characterization • Contains a text that is designed to be accessible and helps to apply the acquired knowledge immediately • Includes information on selected areas of research with imminent application potential for functional coatings Written for chemists in industry, materials scientists, polymer chemists, and physical chemists, Polymer Coatings offers a text that contains the information needed to gain an understanding of the charaterization and applications of polymer coatings.

The possibility of using supercritical carbon dioxide (scCO2) as the primary solvent in a spray process for producing superhydrophobic surfaces have been examined in this work. Using scCO2 as solvent will have considerably lower environmental impact compared to an organic solvent since scCO2 is considered a green solvent as it is non-toxic, non-flammable and recyclable. To be able to work at the pressures needed to reach the supercritical state of carbon dioxide, a high-pressure technique called rapid expansion of supercritical solutions (RESS) has been used to produce the coatings. Fluorinated compounds are often used when producing superhydrophobic coatings due to their intrinsic water repellent properties, but generally these compound do not degrade in nature. Due to this, a wax and a biodegradable polymer have been used as the coating materials in this work. Two RESS set-ups were used to spray a polymer from solutions of scCO2 and acetone. The first system was based on a continuous flow of the solvent mixture and the polymer particles were collected on silica surfaces. Some of the coatings had superhydrophobic properties and the limitation with this technique was the loss of particles between the nozzle and the surface. In the second set-up, RESS was combined with electrostatic deposition (ED) to improve the particle collection. Different processing parameters were examined and most of the RESS-ED sprayed surfaces were superhydrophobic. This was demonstrated by high contact angles against water, low contact angle hysteresis and low tilt angles at which a water droplet rolls off the surface. It was also shown that the surface structures created when spraying using RESS-ED induced the important two-level roughness that was needed to achieve superhydrophobicity. A semi-continuous process for scaling-up the RESS system when spraying the wax has been developed. Temperature and pressure was investigated to find the highest solubility of the wax in scCO2, and 250 bar and 67 °C resulted in the largest amount of sprayed wax. It was also shown that the system is suitable for spray-coating the wax on different substrates such as glass, paper, aluminium etc. since all of these surfaces showed superhydrophobic properties. The wear resistance of the coatings were examined by different methods. Scratch resistance, vertical compression and the friction between the surface and a finger were analysed. The polymer coated surfaces showed a larger robustness compared with the wax surfaces in the scratch tests. The superhydrophobicity was lost for the wax coatings exposed to compression loads above 59 kPa and in the frictions test, one finger stroke over the coating destroyed the surface roughness. Finally, the wax surfaces were investigated as coating barriers to protect steel from corrosion. The superhydrophobic coating was stable up to 10 days before corrosion of the steel started.