Terahertz Quantum Cascade Lasers For Spectroscopic Applications

Quantum cascade lasers (QCLs) are attractive for high-resolution spectroscopy because they can provide high power and a narrow linewidth. They are particularly promising in the terahertz (THz) range since they can be used as local oscillators for heterodyne detection as well as transmitters for direct detection. However, THz QCL-based technologies are still under development and are limited by the lack of frequency tunability as well as the frequency and output power stability for free-running operation. In this dissertation, frequency tuning and linewidth of THz QCLs are studied in detail by using rotational spectroscopic features of molecular species. In molecular spectroscopy, the Doppler eff ect broadens the spectral lines of molecules in the gas phase at thermal equilibrium. Saturated absorption spectroscopy has been performed that allows for sub-Doppler resolution of the spectral features. One possible application is QCL frequency stabilization based on the Lamb dip. Since the tunability of the emission frequency is an essential requirement to use THz QCL for high-resolution spectroscopy, a new method has been developed that relies on near-infrared (NIR) optical excitation of the QCL rear-facet. A wide tuning range has been achieved by using this approach. The scheme is straightforward to implement, and the approach can be readily applied to a large class of THz QCLs. The frequency and output stability of the local oscillator has a direct impact on the performance and consistency of the heterodyne spectroscopy. A technique has been developed for a simultaneous stabilization of the frequency and output power by taking advantage of the frequency and power regulation by NIR excitation. The results presented in this thesis will enable the routine use of THz QCLs for spectroscopic applications in the near future.

Learn how the rapidly expanding area of mid-infrared and terahertz photonics has been revolutionized in this comprehensive overview. State-of-the-art practical applications are supported by real-life examples and expert guidance. Also featuring fundamental theory enabling you to improve performance of both existing and future devices.

A state-of-the-art overview of this rapidly expanding field, featuring fundamental theory, practical applications, and real-life examples.

A quantum cascade (QC) laser is a specific type of semiconductor laser that operates through principles of quantum mechanics. In less than a decade QC lasers are already able to outperform previously designed double heterostructure semiconductor lasers. Because there is a genuine lack of compact and coherent devices which can operate in the far-infrared region the motivation exists for designing a terahertz QC laser. A device operating at this frequency is expected to be more efficient and cost effective than currently existing devices. It has potential applications in the fields of spectroscopy, astronomy, medicine and free-space communication as well as applications to near-space radar and chemical/biological detection. The overarching goal of this research was to find QC laser parameter combinations which can be used to fabricate viable structures. To ensure operation in the THz region the device must conform to the extremely small energy level spacing range from Æ10-15 meV. The time and expense of the design and production process is prohibitive, so an alternative to fabrication was necessary. To accomplish this goal a model of a QC laser, developed at Worchester Polytechnic Institute with sponsorship from the Air Force Research Laboratory Sensors Directorate, and the General Multiobjective Parallel Genetic Algorithm (GenMOP), developed at the Air Force Institute of Technology, were integrated to form a computer simulation which stochastically searches for feasible solutions.

The book highlights recent developments in the field of spectroscopy by providing the readers with an updated and high-level of overview. The focus of this book is on the introduction to concepts of modern spectroscopic techniques, recent technological innovations in this field, and current examples of applications to molecules and materials relevant for academia and industry. The book will be beneficial to researchers from various branches of science and technology, and is intended to point them to modern techniques, which might be useful for their specific problems. Spectroscopic techniques, that are discussed include, UV-Visible absorption spectroscopy, XPS, Raman spectroscopy, SERS, TERS, CARS, IR absorption spectroscopy, SFG, LIBS, Quantum cascade laser (QCL) spectroscopy, fluorescence spectroscopy, ellipsometry, cavity-enhanced absorption spectroscopy, such as cavity ring-down spectroscopy (CRDS) and evanescent wave-CRDS both in gas and condensed phases, time-resolved spectroscopy etc. Applications introduced in the different chapters demonstrates the usefulness of the spectroscopic techniques for the characterization of fundamental properties of molecules, e.g. in connection with environmental impact, bio-activity, or usefulness for pharmaceutical drugs, and materials important e.g. for nano-science, nuclear chemistry, or bio-applications. The book presents how spectroscopic techniques can help to better understand substances, which have also great impact on questions of social and economic relevance (environment, alternative energy, etc.).

Terahertz (THz) and Mid-Infrared (MIR) radiation (TERA-MIR) can be transmitted through nearly any material without causing biological harm. Novel and rapid methods of detection can be created with devices operation in these spectral ranges allowing scanning for weapons, detecting hidden explosives (including plastic landmines), controlling the quality of food and a host of other exciting applications. This book focuses on mathematical and physical aspects of the field, on unifying these two spectral domains (THz and MIR) with regard to common sources, detectors, materials and applications, and on key interdisciplinary topics. The main THz and MIR source is the quantum cascade laser (QCL). Thus significant attention is paid to the challenge of turning this advanced technology into affordable commercial devices so as to exploit its enormous potential. However other alternatives to THz QCLs are also presented, e.g. sub-terahertz imaging from avalanching GaAs bipolar transistors, Josephson junctions as THz sources, semiconductor materials for pulsed THz sources, superconducting THz electronics with Josephson vortices. In summary this book delivers a global picture of the state of the art in TERA-MIR generation, detection and applications.

Terahertz waves, which lie in the frequency range of 0.1–10 THz, have long been investigated in a few limited fields, such as astronomy, because of a lack of devices for their generation and detection. Several technical breakthroughs made over the last couple of decades now allow us to radiate and detect terahertz waves more easily, which has triggered the search for new uses of terahertz waves in many fields, such as bioscience, security, and information and communications technology. The book covers some of the technical breakthroughs in terms of device technologies. It discusses not only the theoretical details and typical features of the technology described, but also some issues and challenges related to it. In addition, it is shown what can actually be done with the terahertz-wave technologies by introducing several successful demonstrations, such as wireless communications, industrial uses, remote sensing, chemical analysis, and 2D/3D imaging.

These proceedings comprise invited papers from highly experienced researchers in THz technology and security applications. THz detection of explosives represents one of the most appealing technologies to have recently emerged in dealing with terrorist attacks encountered by civil security and military forces throughout the world. Discussed are the most advanced technologies and developments, the various points of operational strength and weaknesses as well as are suggestions and predictions the best technological solutions to overcome current operational limits. The current status of various levels of cooling in THz detectors, sources and associated electronics are also addressed. The goal was to provide a clear view on the current technologies available and the required advances needed in order to achieve more efficient systems. This goal was outlined in part by establishing the baseline of current uncertainty estimations in physics-based modelling and the identification of key areas which require additional research and development.