The Atomistic Nature Of Crystal Growth

This textbook is for graduate students and young scientists, who are looking for an introduction to the physics and physical chemistry of crystal growth and nucleation phenomena.

This is the first-ever textbook on the fundamentals of nucleation, crystal growth and epitaxy. It has been written from a unified point of view and is thus a non-eclectic presentation of this interdisciplinary topic in materials science. The reader is required to possess some basic knowledge of mathematics and physics. All formulae and equations are accompanied by examples that are of technological importance. The book presents not only the fundamentals but also the state of the art in the subject. The second revised edition includes two separate chapters dealing with the effect of the Enrich-Schwoebel barrier for down-step diffusion, as well as the effect of surface active species, on the morphology of the growing surfaces. In addition, many other chapters are updated accordingly. Thus, it serves as a valuable reference book for both graduate students and researchers in materials science.

Volume IA Handbook of Crystal Growth, 2nd Edition (Fundamentals: Thermodynamics and Kinetics) Volume IA addresses the present status of crystal growth science, and provides scientific tools for the following volumes: Volume II (Bulk Crystal Growth) and III (Thin Film Growth and Epitaxy). Volume IA highlights thermodynamics and kinetics. After historical introduction of the crystal growth, phase equilibria, defect thermodynamics, stoichiometry, and shape of crystal and structure of melt are described. Then, the most fundamental and basic aspects of crystal growth are presented, along with the theories of nucleation and growth kinetics. In addition, the simulations of crystal growth by Monte Carlo, ab initio-based approach and colloidal assembly are thoroughly investigated. Volume IB Handbook of Crystal Growth, 2nd Edition (Fundamentals: Transport and Stability) Volume IB discusses pattern formation, a typical problem in crystal growth. In addition, an introduction to morphological stability is given and the phase-field model is explained with comparison to experiments. The field of nanocrystal growth is rapidly expanding and here the growth from vapor is presented as an example. For the advancement of life science, the crystal growth of protein and other biological molecules is indispensable and biological crystallization in nature gives many hints for their crystal growth. Another subject discussed is pharmaceutical crystal growth. To understand the crystal growth, in situ observation is extremely powerful. The observation techniques are demonstrated. Volume IA Explores phase equilibria, defect thermodynamics of Si, stoichiometry of oxides and atomistic structure of melt and alloys Explains basic ideas to understand crystal growth, equilibrium shape of crystal, rough-smooth transition of step and surface, nucleation and growth mechanisms Focuses on simulation of crystal growth by classical Monte Carlo, ab-initio based quantum mechanical approach, kinetic Monte Carlo and phase field model. Controlled colloidal assembly is presented as an experimental model for crystal growth. Volume IIB Describes morphological stability theory and phase-field model and comparison to experiments of dendritic growth Presents nanocrystal growth in vapor as well as protein crystal growth and biological crystallization Interprets mass production of pharmaceutical crystals to be understood as ordinary crystal growth and explains crystallization of chiral molecules Demonstrates in situ observation of crystal growth in vapor, solution and melt on the ground and in space

A definitive new investigation of the science of snowflakes by the world’s leading expert A snowflake’s sophisticated symmetry emerges when crystalline ice grows from water vapor within the winter clouds. While certain iconic snowflake shapes are visually familiar to us, microscopic close-ups of falling snow reveal a rich menagerie of lesser-known forms, including slender needle clusters, hollow columns, bullet rosettes, triangular crystals, and exotic capped columns. What explains the myriad and unusual structures of snowflakes that materialize under different atmospheric conditions? In Snow Crystals, Kenneth Libbrecht delves into the science of snowflakes, examining why ice crystals grow the way they do, how patterns emerge, and what they illuminate about the fundamental physics of crystal growth, structure formation, and self-assembly. Libbrecht—the world’s foremost expert on snowflakes—describes the full range of physical processes underlying their occurrence. He explores such topics as the centuries-long development of snow crystal science, the crystalline structure of ice, molecular dynamics at the ice surface, diffusion-limited growth, surface attachment kinetics, computational models of snow crystal growth, laboratory techniques for creating and studying snow crystals, different types of natural snowflakes, and photographing snow crystals. Throughout, Libbrecht’s extensive detailed discussions are accompanied by hundreds of beautiful full-color images. From the molecular dynamics of surface premelting to the aerodynamics of falling snow, Snow Crystals chronicles the continuing quest to fully understand this fascinating phenomenon.

In this book, a variety of topics related to crystal growth is extensively discussed. The topics encompass the physics of growing single crystals of different functional materials, single-crystalline thin films, and even the features of crystallization of biofats and oils. It is intended to provide information on advancements in technologies for crystal growth to physicists, researches, as well as engineers working with single-crystalline functional materials.

This is the first-ever textbook on the fundamentals of nucleation, crystal growth and epitaxy. It has been written from a unified point of view and is thus a non-eclectic presentation of this interdisciplinary topic in materials science. The reader is required to possess some basic knowledge of mathematics and physics. All formulae and equations are accompanied by examples that are of technological importance. The book presents not only the fundamentals but also the state of the art in the subject. The second revised edition includes two separate chapters dealing with the effect of the Ehrlich-Schwoebel barrier for down-step diffusion, as well as the effect of surface active species, on the morphology of the growing surfaces. In addition, many other chapters are updated accordingly. Thus, it serves as a valuable reference book for both graduate students and researchers in materials science. Sample Chapter(s). Crystal-Ambient Phase Equilibrium (396 KB). Contents: Crystal OCo Ambient Phase Equilibrium; Nucleation; Crystal Growth; Epitaxial Growth. Readership: Graduate students, academics and researchers in materials engineering, microelectronics, new materials, semiconductors and related areas."

This book presents a new and promising technique to grow single crystalline compound semiconductor materials with defined stoichometry. The technique is based on the high-precision experimental determination of the boundaries of the single-phase volume of the solid in the pressure-temperature-composition P-T-X phase space. Alongside test results obtained by the author and his colleagues, the P-T-X diagrams of other important materials (e.g., III-V, V-VI semiconductors) are also discussed.