The Effects Of High Pressure High Temperature Hydrogen On Steel

This report deals with the deleterious effects of hydrogen gas on steel at elevated temperatures and/or pressures. Hydrogen attack on steels is manifest as decarburization, intergranular fissuring, or blistering. These conditions result in lowered tensile strength, ductility, and impact strength. The reaction of hydrogen with iron carbide to form methane is probably the most important chemical reaction involved in the attack on steel by hydrogen. Attack of steel at elevated temperatures and pressures is limited or prevented by the following measures: (1) use of steel alloyed with strong carbide-forming elements, (2) use of liners of resistant alloy steels, and (3) substitution of resistant nonferrous alloys.

Hydrogen in Steel: Effect of Hydrogen on Iron and Steel During Production, Fabrication, and Use focuses on the effect of hydrogen on iron and steel during production, fabrication, and use. Topics covered range from the solubility of hydrogen in iron and ferrous alloys to the diffusion and permeation of hydrogen through iron and steel. Electrochemical problems related to the ability of iron to absorb hydrogen from aqueous solutions are also considered. Comprised of 19 chapters, this book begins with a detailed treatment of the nature and properties of metal-hydrogen systems, paying particular attention to the behavior of hydrogen in the bulk of the metal phase and the mechanism of reactions between metals and hydrogen or hydrogen-producing compounds. The reader is then introduced to the solubility of hydrogen in iron and ferrous alloys as well as the nature of the final product of the hydrogen-iron interaction. Subsequent chapters deal with dimensional changes and stresses produced in steel by cathodically evolved hydrogen; the effects of hydrogen on the physical, mechanical, and chemical properties of iron and steel; influence of welding on hydrogen; and sulfide corrosion cracking of steel. The effects of pickling on steel are also examined, along with the blistering and embrittlement caused by hydrogen on the base metal during electroplating. This book will be of value to students and practitioners in the field of physical chemistry.

Materials covered include carbon, alloy and stainless steels; alloy cast irons; high-alloy cast steels; superalloys; titanium and titanium alloys; refractory metals and alloys; nickel-chromium and nickel-thoria alloys; structural intermetallics; structural ceramics, cermets, and cemented carbides; and carbon-composites.

This book is designed to help metallurgical, chemical, mechanical and reliability engineers responsible for the safe operation and maintenance of equipment made of steel.

George Lai's 1990 book, High-Temperature Corrosion of Engineering Alloys, is recognized as authoritative and is frequently consulted and often cited by those in the industry. His new book, almost double in size with seven more chapters, addresses the new concerns, new technologies, and new materials available for those engaged in high-temperature applications. As we strive for energy efficiency, the realm of high-temperature environments is expanding and the need for information on high temperature materials applications was never greater. In addition to extensive expansion on most of the content of the original book, new topics include erosion and erosion-corrosion, low NOx combustion in coal-fired boilers, fluidized bed combustion, and the special demands of waste-to-energy boilers, waste incinerators, and black liquor recovery boilers in the pulp and paper industry. The corrosion induced by liquid metals is discussed and protection options are presented.