Tropospheric Ozone Research

One of the principal concerns in recent years regarding the atmospheric environment has been the formation of ozone and other photo-oxidants over much of Europe in the summer. Ozone is formed in the atmosphere by a complex series of chemical reactions in the presence of sunlight from volatile organic compounds and nitrogen oxides. As the reactions take place in air flows determined by the detailed meteorological situation, the measurement, interpretation, understanding and modelling of the levels, fluxes and origins of the ozone are extremely difficult. The present volume reviews several of the currently important questions and presents detailed reports from investigators all over the continent. As such, it provides insight into the current scientific views about ozone in Europe.

This book presents updated and relevant information on the tropospheric ozone problem and its effects on the wellbeing of plants and human health. The contributions here present in-depth knowledge about history, pattern, sources, environmental factors and other necessary aspects of the tropospheric ozone problem. The book provides a balanced view of current developments on the effects of the tropospheric ozone on plant and human health, crop production and ecosystem services. In addition to the effects of the tropospheric ozone on growth and physiological and biochemical traits, it also considers the molecular basis of plant responses to ozone. The book encompasses a holistic view on various interconnected issues of ozone pollution, and will appeal to scientists from all over the world.

Despite more than 20 years of regulatory efforts, concern is widespread that ozone pollution in the lower atmosphere, or troposphere, threatens the health of humans, animals, and vegetation. This book discusses how scientific information can be used to develop more effective regulations to control ozone. Rethinking the Ozone Problem in Urban and Regional Air Pollution discusses: The latest data and analysis on how tropospheric ozone is formed. How well our measurement techniques are functioning. Deficiencies in efforts to date to control the problem. Approaches to reducing ozone precursor emissions that hold the most promise. What additional research is needed. With a wealth of technical information, the book discusses atmospheric chemistry, the role of oxides of nitrogen (NOx) and volatile organic compounds (VOCs) in ozone formation, monitoring and modeling the formation and transport processes, and the potential contribution of alternative fuels to solving the tropospheric ozone problem. The committee discusses criteria for designing more effective ozone control efforts. Because of its direct bearing on decisions to be made under the Clean Air Act, this book should be of great interest to environmental advocates, industry, and the regulatory community as well as scientists, faculty, and students.

The research and its outcomes presented here focuses on tropospheric or ground level ozone, in particular due to its surfacing as a major threat to crop productivity around the world. This book presents the ozone concentration data for a variety of geographical regions, examines the factors responsible for its increasing concentrations and its potential effects on physiological and biochemical responses culminating in crop productivity losses which, in turn may pose a serious threat to global food security. Beside this, certain ameliorative measures that could be adopted to assess ozone injury in plants are also discussed. Global climate change scenarios predict a significant increase in future tropospheric ozone concentration. Particular attention is therefore given to evaluate the effect of global climate change on ozone concentrations. Readers will also discover how yield losses due to ozone are related to changes in the socio-economic conditions of the society, especially in South Asian regions. Students and researchers studying crop and soil science, environmental scientists, risk assessment professionals and policy makers will find this book of interest.

Peter Fabian and Martin Dameris provide a concise yet comprehensive overview of established scientific knowledge about ozone in the atmosphere. They present both ozone changes and trends in the stratosphere, as well as the effects of overabundance in the troposphere including the phenomenon of photosmog. Aspects such as photochemistry, atmospheric dynamics and global ozone distribution as well as various techniques for ozone measurement are treated. The authors outline the various causes for ozone depletion, the effects of ozone pollution and the relation to climate change. The book provides a handy reference guide for researchers active in atmospheric ozone research and a useful introduction for advanced students specializing in this field. Non-specialists interested in this field will also profit from reading the book. Peter Fabian can look back on a life-long active career in ozone research, having first gained international recognition for his measurements of the global distribution of halogenated hydrocarbons. He also pioneered photosmog investigations in the metropolitan areas of Munich, Berlin, Athens and Santiago de Chile, and his KROFEX facility provided controlled ozone fumigation of adult tree canopies for biologists to investigate the effects of ozone increases on forests. Besides having published a broad range of scientific articles, he has also been the author or editor of numerous books. From 2002 to 2005 he served the European Geosciences Union (EGU) as their first and Founding President. Martin Dameris is a prominent atmospheric modeler whose interests include the impacts of all kinds of natural and man-made disturbances on the atmospheric system. His scientific work focuses on the connections between ozone and climate changes. For many years he has been an active contributor to the WMO scientific ozone depletion assessments, which have been used to monitor the depletion and recovery of the ozone layer in accordance with the Montreal Protocol.

These proceedings describe the current state-of-the-art of ozone research. A wide range of topics is discussed including: emissions, transport and transformation of precursors of ozone and of ozone itself, the distribution of ozone, the deposition of ozone at the earth's surface, and its effects on man and the environment. Attention is also given to the role of stratospheric ozone and the role of the ultraviolet radiation which is transmitted through the ozone layer. Finally it describes in detail present and future policy measures to reduce the ozone in the lower atmosphere and to protect the ozone layer in the stratosphere. Many of the papers describe recent developments and new research results. Research carried out in both in Europe and in the United States is described, as are the policy measures which are being taken by both European and U.S. governments.

The main objective of the workshop was to increase our knowledge of ozone formation and distribution in the troposphere, its relation to precursor (NO~ and HC species) distribution, how it is affected by transport processes in the troposphere, and to show how the increasing levels of ozone can cause environmental problem. The focus was on the interaction of ozone on regional and global scales. There is mounting evidence that such interactions occur and that the ozone levels are increasing in most of the Northern Hemisphere tropo sphere. A likely source of ozone increase is human activity. As result of this, tropospheric climate may change significantly within a few decades, either through direct effects by ozone itself or indirectly through its effect on other radiatively active trace species. Further more, ozone may have adverse effects on vegetation over large continental areas due to enhanced levels which have been measured to take place. As it is well known that ozone plays a key role in the oxidation of a large number of chemical species in the troposphere, natural as well as man-made, the atmospheric distribution of important trace species like sulfur dioxide, nitrogen oxides and hydrocarbons could be markedly changed as a result of ozone changes. The rapidly increasing interest in tropospheric ozone, and the key role ozone plays in several atmospheric areas as well the obvious increase in the tropospheric concentration of ozone made ozone a natural choice as a topic for the workshop.