Chalcogen Chemistry

Up until a few decades ago, chalcogen chemistry was mainly represented by the chemistry of sulfur-containing compounds. However, with the rise in research around selenium and tellurium compound chemistry, the field has developed significantly as it continues to uncover and understand the peculiarities chalcogens exhibit. Taking an introductory approach, this book is the foundation to the subject that has been long needed. Covering organic and inorganic synthesis, structural properties, coordination chemistry and computational modelling, all key classes of chalcogen compounds are illustrated. Applications across materials science, biology, pharmaceutical science and environmental topics highlight to readers the impact of chalcogen chemistry in many aspects of research. Edited by international leaders in the field, Chalcogen Chemistry brings together contributions from acclaimed researchers around the world. This book is ideal for newcomers and established researchers, and provides the first building block to uncovering this fascinating field.

Provides an overview of the developments on the chemistry of the chalcogen group elements (S, Se and Te). Organised into two parts, this book deals systematically with the chemistry of chalcogens in relation to other group elements in the periodic table, and also includes an overview of metal-chalcogenides and metal-polychalcogenides.

This is a handy textbook comprised of chapters introducing the fundamentals of chalcogen chemistry with a focus on chalcogens and selected derived compounds and/or materials with illustrative practical applications. These low-valent chemistry elements of Group 16 or group VI- in the modern periodic table include oxygen (O), sulfur (S), selenium (Se), tellurium (Te), and polonium (Po), and they exhibit extremely interesting properties. They are endowed with supramolecular and structure bonding reactivities that allow them to form a variety of new compounds with sophisticated characteristics, thus making their way into a new era of materials development. It is hoped that readers of this textbook with a general background knowledge in chemistry, biogeochemistry, biochemistry, biology, food, agriculture, and also medicine, as well as pharmacy, will find the chapters enriching in new knowledge. An introductory chapter orients readership in this particular field of chemistry with a summative focus on the multidisciplinary approach employed in the compilation of the chapters. As such, the text is suitable for scientists, technologists, students, as well as those whose major interest is chalcogen chemistry, with particular interests in the chalcogen compounds and materials.

The Handbook of Chalcogen Chemistry: New Perspectives in Sulfur, Selenium and Tellurium provides an overview of recent developments, particularly from the last decade, on the chemistry of the chalcogen group elements (S, Se and Te). While up to a few decades ago, chalcogen chemistry was mainly centred on sulphur, in recent years the research based on Se and Te has increased dramatically, and has created huge scope for the use of compounds based on this type of chemistry. The Handbook is organised into two parts, the first of which deals systematically with the chemistry of chalcogens in relation to other group elements in the periodic table. It also includes an overview of metal-chalcogenides and metal-polychalcogenides. The second part reflects the interdisciplinary nature of chalcogen chemistry and focuses on biological, materials and supramolecular aspects of the field. This Handbook gives a comprehensive overview on recent developments over the last decade and is ideal for researchers in the field.

Chalcogen-nitrogen chemistry involves the study of compounds that exhibit a linkage between nitrogen and sulfur, selenium or tellurium atoms. Since the publication of A Guide to Chalcogen-Nitrogen Chemistry in 2005, the emphasis of investigations of chalcogen-nitrogen compounds has advanced from a focus on fundamental studies to the development of practical applications, as indicated by the title of this new edition. Pharmaceutical applications of organic sulfur-nitrogen compounds include drugs for the treatment of various diseases, as well as probes for locating tumour cells. From a materials perspective, carbon-containing chalcogen-nitrogen heterocycles have applications in everyday devices such as LEDs and solar cells. A new technology based on binary sulfur nitrides is being used for fingerprint detection in forensic science. As a result, this book includes seven new chapters and updates the others with extensive literature coverage of developments since 2005 while retaining earlier seminal results. This comprehensive text is essential for anyone working in the field, and the four introductory chapters emphasise general concepts that will be helpful to the non-specialist. The treatment is unique in providing a comparison of sulfur, selenium and tellurium compounds. Each chapter is designed to be self-contained, and there are extensive cross-references between chapters.

This is a handy textbook comprised of chapters introducing the fundamentals of chalcogen chemistry with a focus on chalcogens and selected derived compounds and/or materials with illustrative practical applications. These low-valent chemistry elements of Group 16 or group VI- in the modern periodic table include oxygen (O), sulfur (S), selenium (Se), tellurium (Te), and polonium (Po), and they exhibit extremely interesting properties. They are endowed with supramolecular and structure bonding reactivities that allow them to form a variety of new compounds with sophisticated characteristics, thus making their way into a new era of materials development. It is hoped that readers of this textbook with a general background knowledge in chemistry, biogeochemistry, biochemistry, biology, food, agriculture, and also medicine, as well as pharmacy, will find the chapters enriching in new knowledge. An introductory chapter orients readership in this particular field of chemistry with a summative focus on the multidisciplinary approach employed in the compilation of the chapters. As such, the text is suitable for scientists, technologists, students, as well as those whose major interest is chalcogen chemistry, with particular interests in the chalcogen compounds and materials.

' Chalcogen-nitrogen chemistry involves the study of compounds that exhibit a linkage between nitrogen and sulfur, selenium or tellurium atoms. Such studies have both fundamental and practical importance. A Guide to Chalcogen-Nitrogen Chemistry examines the role of chalcogen-nitrogen compounds in areas ranging from solid-state inorganic chemistry to biochemistry. The discussion covers fundamental questions concerning the bonding in electron-rich systems, as well as potential practical applications of polymers and materials with novel magnetic or electrical properties. This book is the only account of this important topic to appear in the last twenty–five years, and coupled with its extensive literature coverage of very recent developments, this comprehensive guide is essential for anyone working in the field. The treatment is unique in providing a comparison of sulfur, selenium and tellurium systems, with an approach intended to emphasize general concepts that will be helpful to the non-specialist. Each chapter is designed to be self–contained, and there are extensive cross–references between chapters. Contents:Formation of Chalcogen–Nitrogen BondsApplications of Physical MethodsElectronic Structures and Reactivity PatternsBinary SystemsCyclic Chalcogen ImidesMetal ComplexesChalcogen–Nitrogen HalidesChalcogen–Nitrogen OxidesAcyclic Organochalcogen–Nitrogen CompoundsFive–Membered Carbon–Nitrogen–Chalcogen Ring Systems: From Radicals to Functional MaterialsSix–Membered and Larger Carbon–Nitrogen–Chalcogen Ring SystemsHeterocyclothia– and Selena–AzenesChalcogen–Nitrogen Chains and PolymersWeak Intramolecular Chalcogen–Nitrogen Interactions Readership: Scientists interested in the chemistry of sulfur, selenium or tellurium compounds, and upper level undergraduates in inorganic (main group) chemistry courses. Keywords:Sulfur;Selenium;Tellurium;Nitrogen;Heterocycles;Electron-Rich Compounds;Chemical Bonding;Metal ComplexesKey Features:Focuses on important developments in the last 25 yearsCompares Sulfur, Selenium and Tellurium CompoundsTargets the non-specialist as well as experts in the fieldSupplements standard textbook treatments of this subjectDiscusses theoretical concepts and practical applicationsReviews:“Although each chapter is designed to be self–contained, there is detailed cross-referencing between them … the focused nature of the chapters together with an adequate subject index makes finding particular compounds relatively easy … the introductory chapters will be of significant interest to upper level undergraduates as well as to graduate students … The comprehensive listing of reactions and reaction types found in the later chapters will be of more benefit to specialists in the arena of main group chemistry. This modestly priced resource should be a welcome addition to researchers in the field or to those interested in entering the area.”Journal of the American Chemical Society '

Comprehensive Inorganic Chemistry II, Nine Volume Set reviews and examines topics of relevance to today’s inorganic chemists. Covering more interdisciplinary and high impact areas, Comprehensive Inorganic Chemistry II includes biological inorganic chemistry, solid state chemistry, materials chemistry, and nanoscience. The work is designed to follow on, with a different viewpoint and format, from our 1973 work, Comprehensive Inorganic Chemistry, edited by Bailar, Emeléus, Nyholm, and Trotman-Dickenson, which has received over 2,000 citations. The new work will also complement other recent Elsevier works in this area, Comprehensive Coordination Chemistry and Comprehensive Organometallic Chemistry, to form a trio of works covering the whole of modern inorganic chemistry. Chapters are designed to provide a valuable, long-standing scientific resource for both advanced students new to an area and researchers who need further background or answers to a particular problem on the elements, their compounds, or applications. Chapters are written by teams of leading experts, under the guidance of the Volume Editors and the Editors-in-Chief. The articles are written at a level that allows undergraduate students to understand the material, while providing active researchers with a ready reference resource for information in the field. The chapters will not provide basic data on the elements, which is available from many sources (and the original work), but instead concentrate on applications of the elements and their compounds. Provides a comprehensive review which serves to put many advances in perspective and allows the reader to make connections to related fields, such as: biological inorganic chemistry, materials chemistry, solid state chemistry and nanoscience Inorganic chemistry is rapidly developing, which brings about the need for a reference resource such as this that summarise recent developments and simultaneously provide background information Forms the new definitive source for researchers interested in elements and their applications; completely replacing the highly cited first edition, which published in 1973