Characterization And Modification Of Graphene Based Interfacial Mechanical Behavior

This thesis shares new findings on the interfacial mechanics of graphene-based materials interacting with rigid/soft substrate and with one another. It presents an experimental platform including various loading modes that allow nanoscale deformation of atomically thin films, and a combination of atomic force microscopy (AFM) and Raman spectroscopy that allows both displacement and strain to be precisely measured at microscale. The thesis argues that the rich interfacial behaviors of graphene are dominated by weak van der Waals force, which can be effectively modulated using chemical strategies. The continuum theories are demonstrated to be applicable to nano-mechanics and can be used to predict key parameters such as shear/friction and adhesion. Addressing key interfacial mechanics issues, the findings in thesis not only offer quantitative insights in the novel features of friction and adhesion to be found only at nanoscale, but will also facilitate the deterministic design of high-performance graphene-based nanodevices and nanocomposites.

The fourth volume in a series of handbooks on graphene research and applications The Handbook of Graphene, Volume 4: Composites looks at composite materials exclusively. Topics covered include graphene composites and graphene-reinforced advanced composite materials. The following graphene-based subjects are discussed: ceramic composites; composite nanostructures; composites with shape memory effect; and scroll structures. Chapters also address: the fabrication and properties of copper–graphene composites; graphene–metal oxide composite as an anode material in li-ion batteries; supramolecular graphene-based systems for drug delivery; and other graphene-related areas of interest to scientists and researchers.

Innovations in Graphene-Based Polymer Composites reviews recent developments in this important field of research. The book's chapters focus on processing methods, functionalization, mechanical, electrical and thermal properties, applications and life cycle assessment. Leading researchers from industry, academia and government research institutions from across the globe have contributed to the book, making it a valuable reference resource for materials scientists, academic researchers and industrial engineers working on recent developments in the area of graphene-based materials, graphene-based polymer blends and composites. Readers will gain insights into what has been explored to-date, along with associated benefits and challenges for the future. Presents a strong emphasis on synthesis methods, functionalization, processing and properties Includes chapters on characterization, electrical conductivity and modeling and simulation Provides recent advances in applications, including drawbacks and future scope

Graphite, Graphene, and Their Polymer Nanocomposites presents a compilation of emerging research trends in graphene-based polymer nanocomposites (GPNC). International researchers from several disciplines share their expertise about graphene, its properties, and the behavior of graphene-based composites. Possibly the first published monograph of its kind, this book provides a comprehensive snapshot of graphite, graphene, and their PNCs, including the underlying physics and chemistry, and associated applications. Beginning with an introduction to natural and synthetic graphite, the precursors to graphene, the text describes their properties, characterization techniques, and prominent commercial applications. The focus then moves to graphene and its unique features, and techniques for its characterization. The chapters cover advances in electrochemical exfoliation of graphite, as well as exfoliation routes to produce graphene and graphite nanoplatelets for polymer composites. They also explore commercial use of graphene-based materials, such as emerging clean energy and pulse laser applications, and use as nanofillers in epoxy-based composites. The authors provide an overview of nanofillers and address two methods for GPNC preparation as well as specialized properties of GPNC. With its multidisciplinary approach, this book provides a broader scientific and engineering perspective necessary for meaningful advancements to take place.

A monograph that locates graphene within the carbon chemistry alternatives available to materials engineers and explains how it is incorporated into polymer-matrix, as well as ceramic - and metal-matrix composite materials. It also investigates emerging uses of graphene in films, coatings and colloidal suspensions.

This book describes the forcefields/interatomic potentials that are used in the atomistic-scale and molecular dynamics simulations. It covers mechanisms, salient features, formulations, important aspects and case studies of various forcefields utilized for characterizing various materials (such as nuclear materials and nanomaterials) and applications. This book gives many help to students and researchers who are studying the forcefield potentials and introduces various applications of atomistic-scale simulations to professors who are researching molecular dynamics.

This book contains a collection of the state-of-the-art reviews written by the leading researchers in the areas of nanoscale mechanics, molecular dynamics, nanoscale modeling of nanocomposites and mechanics of carbon nanotubes. No other book provides reviews of recent discoveries such as a nanoscale analog of the Pauli’s principle, i.e., effect of the spatial exclusion of electrons or the SEE effect, a new Registry Matrix Analysis for the nanoscale interfacial sliding and new data on the effective viscosity of interfacial electrons in nanoscale stiction at the interfaces. This volume is also an exceptional resource on the well tested nanoscale modeling of carbon nanotubes and nanocomposites, new nanoscale effects, unique evaluations of the effective thickness of carbon nanotubes under different loads, new data on which size of carbon nanotubes is safer and many other topics. Extensive bibliography concerning all these topics is included along with the lucid short reviews. Numerous illustrations are provided for molecular dynamic simulations, fascinating nanoscale phenomena and remarkable new effects. It is of interest to a wide range of researchers and students.

Polyurethane Polymers: Composites and Nanocomposites concentrates on the composites and nanocomposites of polyurethane based materials. Polyurethane composites are a very important class of materials widely used in the biomedical and industrial field that offer numerous potential applications in many areas. This book discusses current research and identifies future research needs in the area. Provides an elaborate coverage of the chemistry of polyurethane, its synthesis, and properties Includes available characterization techniques Relates types of polyurethanes to their potential properties Discusses composites, nanocomposites options, and PU recycling