Chemical Modification Properties And Usage Of Lignin

One of the most significant challenges facing mankind in the twenty-first century is the development of a sustainable global economy. Within the scientific community, this calls for the development of processes and technologies that will allow the sustainable production of materials from renewable natural resources. Plant material, in particular lignin, is one such resource. During the annual production of about 100 million metric tons of chemical wood pulps worldwide, approximately 45 and 2 million metric tons/year of kraft lignin and lignosulfonates, respectively, are also generated. Although lignosulfonates have found many applications outside the pulp and paper industry, the majority of kraft lignin is being used internally as a low-grade fuel for the kraft pulping operation. A surplus of kraft lignin will become available as kraft mills increase their pulp production without expanding the capacity of their recovery boilers that utilize lignin as a fuel. There is a tremendous opportunity and an enormous economic incentive to find better uses of kraft lignin, lignosulfonates and other industriallignins. The pulp and paper industry not only produces an enormous amount of lignins as by products of chemical wood pulps, but it also utilizes about 10 million metric tons of lignin per year as a component of mechanical wood pulps and papers. Mechanical wood pulps, produced in a yield of 90-98% with the retention of lignin, are mainly used to make low-quality, non-permanent papers such as newsprint and telephone directories because of the light-induced photooxidation of lignin and the yellowing of the papers.

This book presents an overview of various types of lignin and their unique structures and properties, as well as utilizations of crude or modified technical lignin for high-value bioproducts such as lignin-based PF resins/adhesives, epoxy resins, PF foams, PU foams, rubber reinforcement and carbon fibers and as dispersants in drilling fluids in the oil and gas industry. It subsequently discusses various thermal/chemical modification techniques (pyrolysis, direct liquefaction and de-polymerization) for converting lignin into oils and chemical feedstocks, and the utilization of crude lignin, lignin-derived oils or depolymerized lignins (DLs) of reduced molecular weights and improved reactivity to produce lignin-based PF resins/adhesives, PF/PU foams and epoxy resins. The book will interest and benefit a broad readership (graduate students, academic researchers, industrial researchers and practitioners) in various fields of science and technology (chemical engineering, biotechnology, chemistry, material science, forestry, etc.). Chunbao (Charles) Xu, PhD, is currently a Professor of Chemical Engineering and NSERC/FPInnovations Industrial Research Chair in Forest Biorefinery at the University of Western Ontario, Canada. Fatemeh Ferdosian, PhD, is currently a postdoctoral fellow at the University of Waterloo, Canada.

Lignin Chemistry and Application systematically discusses the structure, physical and chemical modification of lignin, along with its application in the field of chemicals and materials. It presents the history of lignin chemistry and lignin-modified materials, describes recent progresses, applications and studies, and prospects the development direction of high value applications of lignin in the field of material science. In addition to covering the basic theories and technologies relating to the research and application of lignin in polymer chemistry and materials science, the book also summarizes the latest applications in rubber, engineering plastics, adhesives, films and hydrogels. Systematically discusses the structure, physical and chemical modification of lignin and its application in materials Presents the latest research results in the field of lignin Indicates the development direction of high value applications of lignin in a range of fields, including petrochemicals, household applications, medicine, agriculture, and more

This volume emphasizes the growing need for wood products with advanced engineering properties. It details the fundamental principles of cellulose technology and presents current techniques to modifying the basic chemistry of lignocellulosic materials. The work: discusses the cost-efficient use of cellulose derivatives in a variety of commodities; highlights the chemical modification of wood by methods such as etherification, esterification and thermoplasticization; considers recent progress in the lignocellulosic liquefaction of wood; and more.

This book presents a comprehensive overview on origin, structure, properties, modification strategies and applications of the biopolymer lignin. It is organized into four themed parts. The first part focuses on the analysis and characterization of the second most abundant biopolymer. The following part is devoted to the biological aspects of lignin such as biosynthesis and degradation. In the third part, chemical modification strategies and the preparation of composites as well as nano- and microparticles are discussed.The final part addresses the industrial application of lignin and its derivatives, as well as lignin materials. The usage for synthesis of biofuels, fine chemicals and in agriculture and food industry is covered. This book is a comprehensive source for researchers, scientists and engineers working in the field of biopolymers as well as renewable materials and sources.

This volume brings together the current research on all aspects of lignins, the second most abundant group of biopolymers. It covers recent progress in elucidating some of the more intractable aspects of lignin preparation. Among the topics covered in its 41 chapters are: various methods for studying the structure of lignins; discussions of polymer products derived from the modification of lignin; water-soluble polymers; organosolv pulping, wood adhesives, and enzymatic lignin modification; and various products from lignins, including polyols, polyurethanes, polyblends, grafts, epoxies, and acrylics

Lignin-based Materials for Biomedical Applications: Preparation, Characterization, and Implementation explores the emerging area of lignin-based materials as a platform for advanced biomedical applications, guiding the reader from source through to implementation. The first part of the book introduces the basics of lignin, including extraction methods, chemical modifications, structure and composition, and properties that make lignin suitable for biomedical applications. In addition, structural characterization techniques are described in detail. The next chapters focus on the preparation of lignin-based materials for biomedical applications, presenting methodologies for lignin-based nanoparticles, hydrogels, aerogels, and nanofibers, and providing in-depth coverage of lignin-based materials with specific properties—including antioxidant properties, UV absorbing capability, antimicrobial properties, and colloidal particles with tailored properties—and applications, such as drug and gene delivery, and tissue engineering. Finally, future perspectives and possible new applications are considered. This is an essential reference for all those with an interest in lignin-based materials and their biomedical applications, including researchers and advanced students across bio-based polymers, polymer science, polymer chemistry, biomaterials, nanotechnology, materials science and engineering, drug delivery, and biomedical engineering, as well as industrial R&D and scientists involved with bio-based polymers, specifically for biomedical applications. Unlocks the potential of lignin-based materials with advanced properties for cutting-edge applications in areas such as drug delivery, gene delivery and tissue engineering Presents state-of-the-art methodologies used in the development of lignin-based nanoparticles, hydrogels, aerogels and nanofibers Explains the fundamentals of lignin, including structure and composition, extraction and isolation methods, types and properties, chemical modifications, and characterization techniques

Lignin in Polymer Composites presents the latest information on lignin, a natural polymer derived from renewable resources that has great potential as a reinforcement material in composites because it is non-toxic, inexpensive, available in large amounts, and is starting to be deployed in various materials applications due to its advantages over more traditional oil-based materials. This book reviews the state-of-the-art on the topic and their applications to composites, including thermoplastic, thermosets, rubber, foams, bioplastics, nanocomposites, and lignin-based carbon fiber composites. In addition, the book covers critical assessments on the economics of lignin, including a cost-performance analysis that discusses its strengths and weaknesses as a reinforcement material. Finally, the huge potential applications of lignin in industry are explored with respect to its low cost, recyclable properties, and fully biodegradable composites, and the way they apply to the automotive, construction, and packaging industries. Reviews the state-of-the-art on the topic and their applications to composites, including thermoplastic, thermosets, rubber, foams, bioplastics, nanocomposites, and lignin-based carbon fiber composites Presents the essential processing and properties information for engineers and materials scientists, enabling the use of lignin in composites Provides critical insight into the applications and future trends of lignin-based composites, including advantages, shortcomings, and economics Includes a thorough coverage of extraction, modification, processing, and applications of the material