Concise Chemical Thermodynamics 2nd Edition

The first edition of Concise Chemical Thermodynamics proved to be a very popular introduction to a subject many undergraduate students perceive as a difficult topic, because it presented thermodynamics with practical chemical examples in a way that used little mathematics. In this second edition the text has been carefully revised to ensure the same approach is maintained. Students are led to an understanding of Gibbs free energy early on, and the concept is demonstrated in several different fields. The book includes discussions of experimental equilibrium data, an introduction to electrochemistry, a brief survey of Ellingham diagrams, and a treatment of entropy without reference to the Carnot cycle. A new chapter on computer-based methods in thermodynamics has been added to reflect current technological trends and practices. Thermodynamic data has been revised in light of information provided by the work of the Scientific Group Thermodata Europe, to ensure that the symbols and units reflect the latest IUPAC rules. In addition, the problems and examples have been updated, replaced, and amplified to reflect current understanding and concerns. Undergraduate students of chemistry will find this an ideal introduction to chemical thermodynamics.

An applications-oriented text, this revised edition includes new techniques and now has expanded coverage of Van der Waals equations of state, behaviour of electrolytes in aqueous solutions, and applications of thermodynamics in biochemical engineering.

For first year students of chemistry and chemical engineering, this book presents thermodynamics using practical chemical examples in a way that uses very little mathematics.

The first two editions of Concise Chemical Thermodynamics proved to be a very popular introduction to a subject many undergraduate students perceive to be difficult due to the underlying mathematics. With its concise explanations and clear examples, the text has for the past 40 years clarified for countless students one of the most complicated branches of science. Following in the tradition of its predecessors, this Third Edition continues to offer a practical, example-based exploration of a critical topic, maintaining academic rigor but eschewing complicated calculations. Updated to reflect new concerns in the 21st century, this edition now includes: An extensive outlook on the world’s current energy consumption and the role of renewable energy in the future An example of an exothermic reaction through a discussion of the Mond process for extracting and purifying nickel The use of Mathcad® to calculate a plot of Gibbs energy for a reaction mixture versus the extent of reaction An explanation of the Lambda sensor, which reduces vehicle emissions The use of FactSage software to calculate and describe the production of silicon in an arc (oven) furnace This latest edition re-works problems that have proven to be the most difficult for students and adds several new ones to further amplify complex areas. The book also provides an updated list of suggested readings. Keeping pace with new technology and the shift in emphasis to green chemistry, this volume provides an up-to-date treatment of a foundational topic.

The first two editions of Concise Chemical Thermodynamics proved to be a very popular introduction to a subject many undergraduate students perceive to be difficult due to the underlying mathematics. With its concise explanations and clear examples, the text has for the past 40 years clarified for countless students one of the most complicated bran

Thermodynamics, like classical music, is an acquired taste. The initiation must be sensitively carried out, otherwise the mathematical rigour, like the formal structure of the music, acts to discourage a deeper relationship. It is sad but true that some students, both of thermodynamics and of Bach, never recover from the initial shock. In this, we are all losers. In this book, therefore, I have tried to pre sent thermodynamics in a way which uses little mathematics, but which includes many practical and lively examples. I hope it will provide a basis for an intro ductory course at Honours Degree level, and will also suffice for Higher National Diploma and Certificate students. In general, my aim has been to develop an understanding of Gibbs free energy fairly early on and then to apply this concept in several different fields. I have used many examples from chemical industry, in the firm belief that the basic usefulness of the subject must be demonstrated. I have therefore included a brief discussion of Ellingham diagrams in Chapter 10 and for a similar reason have omitted any mention of the Carnot cycle. I have used symbols consistent with the recommendations of the International Union of Pure and Applied Chemistry and have adopted units of the Systeme International d'Unites (SI).