Corrosion And Surface Chemistry Of Metals

Textbook; grad.

Presents opportunities for making significant improvements in preventing harmful effects that can be caused by corrosion Describes concepts of molecular modeling in the context of materials corrosion Includes recent examples of applications of molecular modeling to corrosion phenomena throughout the text Details how molecular modeling can give insights into the multitude of interconnected and complex processes that comprise the corrosion of metals Covered applications include diffusion and electron transfer at metal/electrolyte interfaces, Monte Carlo simulations of corrosion, corrosion inhibition, interrogating surface chemistry, and properties of passive films Presents current challenges and likely developments in this field for the future

The book is concerned with understanding the fundamental mechanisms of high temperature alloy oxidation. It uses this understanding to develop methods of predicting oxidation rates and the way they change with temperature, gas chemistry and alloy composition. The focus is on designing (or selecting) alloy compositions which provide optimal resistance to attack by corrosive gases. . Emphasises quantitative calculations for predicting reaction rates and the effects of temperature, oxidant activities and alloy compositions. . Uses phase diagrams and diffusion paths to analyse and interpret scale structures and internal precipitation distributions . Provides a detailed examination of corrosion in industrial gases (water vapour effects, carburisation and metal dusting, sulphidation) . Text is well supported by numerous micrographs, phase diagrams and tabulations of relevant thermodynamic and kinetic data . Combines physical chemistry and materials science methodologies.

Organic Inhibitors of Corrosion of Metals provides a detailed review of the various theories advanced to explain the mechanisms of organic inhibitors. Author Yu.I. Kuznetsov explores the role of potential and charge of the metal, the nature of the organic species used as the inhibitor, and the function of the solvent. The author draws connections between these key elements and the processes of passivation, pitting, synergism, and complex formation. This unique volume brings together the mechanistic and practical aspects of corrosion control by organic inhibitors.

This textbook, suitable for students, researchers and engineers, gathers the experience of more than 20 years of teaching fracture mechanics, fatigue and corrosion to professional engineers and running experimental tests and verifications to solve practical problems in engineering applications. As such, it is a comprehensive blend of fundamental knowledge and technical tools to address the issues of fatigue and corrosion. The book initiates with a systematic description of fatigue from a phenomenological point of view, since the early signs of submicroscopic damage in few surface grains and continues describing, step by step, how these precursors develop to become mechanically small cracks and, eventually, macrocracks whose growth is governed by fracture mechanics. But fracture mechanics is also introduced to analyze stress corrosion and corrosion assisted fatigue in a rather advanced fashion. The author dedicates a particular attention to corrosion starting with an electrochemical treatment that mechanical engineers with a rather limited knowledge of electrochemistry will well digest without any pain. The electrochemical introduction is considered an essential requirement to the full understanding of corrosion that is essentially an electrochemical process. All stress corrosion aspects are treated, from the generalized film rupture-anodic dissolution process that is the base of any corrosion mechanism to the aggression occurring in either mechanically or thermally sensitized alloys up to the universe of hydrogen embrittlement, which is described in all its possible modes of appearance. Multiaxial fatigue and out-of-phase loading conditions are treated in a rather comprehensive manner together with damage progression and accumulation that are not linear processes. Load spectra are analyzed also in the frequency domain using the Fourier transform in a rather elegant fashion full of applications that are generally not considered at all in fatigue textbooks, yet they deserve a special place and attention. The issue of fatigue cannot be treated without a probabilistic approach unless the designer accepts the shame of one-out-of-two pieces failure. The reader is fully introduced to the most promising and advanced analytical tools that do not require a normal or lognormal distribution of the experimental data, which is the most common case in fatigue. But the probabilistic approach is also used to introduce the fundamental issue of process volume that is the base of any engineering application of fatigue, from the probability of failure to the notch effect, from the metallurgical variability and size effect to the load type effect. Fractography plays a fundamental role in the post mortem analysis of fatigue and corrosion failures since it can unveil the mystery encrypted in any failure.

Corrosion due to water is one of the most significant and complex causes of damage to metallic products. Written from the viewpoint of physical chemistry, this authoritative and established text deals with the aqueous corrosion of metals. Available for the first time in English, Corrosion of Metal addressing engineers, metallurgists, physicists and chemists. This self-contained, valuable reference comprehensively organizes and makes readily accessible the accumulated wealth of fundamental and applied knowledge. The concentration is on the underlying essentials of corrosion and failure, and the material is consistently presented in relation to practical applications to corrosion protection. The first chapters introducing the physicochemical principles are ideal for students. The following chapters provide an overview of the state of research for those familiar with the fundamentals. An exhaustive bibliography and appendices conclude the volume.