Corrosion Of Magnesium Alloys

The use of magnesium alloys is increasing in a range of applications, and their popularity is growing wherever lightweight materials are needed. This book provides a comprehensive account of the corrosion of magnesium alloys. It covers not only the corrosion performances and mechanisms of Mg alloys in conventional environments, such as sodium chloride solutions, but also looks at their corrosion behaviours in special media, like engine coolants and simulated body fluids. Part one covers fundamentals such as the corrosion electrochemistry, activity and passivity of magnesium and its alloys. Part two then considers the metallurgical effect in relation to the corrosion of magnesium alloys, including the role of micro-structure and earth-rare elements, the corrosion behaviour of magnesium-based bulk metallic glasses, and the corrosion of innovative magnesium alloys. Part three goes on to describe environmental influences on the corrosion of magnesium alloys, such as atmospheric corrosion, stress corrosion cracking, creep and fatigue behaviour, and galvanic corrosion. Finally, part four is concerned with various means of protecting magnesium alloys against corrosion through the use of aluminium electrodeposition, conversion and electrophoretic coatings, and anodisation. With its distinguished editor and team of contributors, this book is an invaluable resource for metallurgists, engineers and designers working with magnesium and its alloys, as well as professionals in the aerospace and automotive industries. Provides a comprehensive account of the corrosion of magnesium alloys covering fundamentals such as the corrosion electrochemistry, activity and passivityReviews the metallurgical effect in relation to the corrosion of magnesium alloys, including the role of micro-structure and earth-rare elementsAssesses environmental influences such as atmospheric corrosion, stress corrosion cracking, creep and fatigue behaviour, and galvanic corrosion

The use of magnesium alloys is increasing in a range of applications, and their popularity is growing wherever lightweight materials are needed. This book provides a comprehensive account of the corrosion of magnesium alloys. It covers not only the corrosion performances and mechanisms of Mg alloys in conventional environments, such as sodium chloride solutions, but also looks at their corrosion behaviours in special media, like engine coolants and simulated body fluids. Part one covers fundamentals such as the corrosion electrochemistry, activity and passivity of magnesium and its alloys. Part two then considers the metallurgical effect in relation to the corrosion of magnesium alloys, including the role of micro-structure and earth-rare elements, the corrosion behaviour of magnesium-based bulk metallic glasses, and the corrosion of innovative magnesium alloys. Part three goes on to describe environmental influences on the corrosion of magnesium alloys, such as atmospheric corrosion, stress corrosion cracking, creep and fatigue behaviour, and galvanic corrosion. Finally, part four is concerned with various means of protecting magnesium alloys against corrosion through the use of aluminium electrodeposition, conversion and electrophoretic coatings, and anodisation. With its distinguished editor and team of contributors, this book is an invaluable resource for metallurgists, engineers and designers working with magnesium and its alloys, as well as professionals in the aerospace and automotive industries.

Valuable information on corrosion fundamentals and applications of aluminum and magnesium Aluminum and magnesium alloys are receiving increased attention due to their light weight, abundance, and resistance to corrosion. In particular, when used in automobile manufacturing, these alloys promise reduced car weights, lower fuel consumption, and resulting environmental benefits. Meeting the need for a single source on this subject, Corrosion Resistance of Aluminum and Magnesium Alloys gives scientists, engineers, and students a one-stop reference for understanding both the corrosion fundamentals and applications relevant to these important light metals. Written by a world leader in the field, the text considers corrosion phenomena for the two metals in a systematic and parallel fashion. The coverage includes: The essentials of corrosion for aqueous, high temperature corrosion, and active-passive behavior of aluminum and magnesium alloys The performance and corrosion forms of aluminum alloys The performance and corrosion forms of magnesium alloys Corrosion prevention methods such as coatings for aluminum and magnesium Electrochemical methods of corrosion investigation and their application to aluminum and magnesium alloys Offering case studies and detailed references, Corrosion Resistance of Aluminum and Magnesium Alloys provides an essential, up-to-date resource for graduate-level study, as well as a working reference for professionals using aluminum, magnesium, and their alloys.

Magnesium and magnesium alloys provide unique properties for engineering applications. Magnesium alloys are popular as a structural material because of their combination of light weight and strength. They are desirable for portable tools, appliances, electronic devices, airplanes, space vehicles, and land transportation. This book is written for engineers, scientists, teachers, and students engaged in the design process of material selection and material elimination. While focused on mechanical properties for structural design, the physical properties that are germane to corrosion behavior and electrical applications are represented. Two-thirds of the book is devoted to datasheets for individual alloys which provide a handy quick reference to specific properties and performance. The remainder of the book addresses topics common to all magnesium alloys such as the alloy designation system and product forms. Casting alloys and wrought alloys are compared. The alloy performance at elevated temperature is presented, as are fatigue properties. Finally, a summary of the corrosion behavior of selected alloys is discussed along with how these corrosion mechanisms can be applied for beneficial results.

Magnesium (Mg) alloys are receiving increasing attention due to their abundance, light weight, castability, formability, mechanical properties and corrosion performance. By selecting the appropriate combination of materials, coatings and surface modifications, their corrosion resistance can be greatly enhanced. Corrosion prevention of magnesium alloys is a comprehensive guide to the effective prevention of corrosion in these important light metals. Part one discusses alloying, inhibition and prevention strategies for magnesium alloys as well as corrosion and prevention principles. Part two reviews surface treatment and conversion. Beginning with an overview of surface cleaning and pre-conditioning, the book goes on to discuss the use of surface processing and alloying, laser treatments, chemical conversion and electrochemical anodization to improve the corrosion resistance of magnesium alloys. Coatings are then the focus of part three, including varied plating techniques, cold spray coatings, gel and electroless electrophoresis coatings. Finally, the book concludes in part four with a selection of case studies investigating the application of preventative techniques for both automotive and medical applications. With its distinguished editor and international team of expert contributors, Corrosion prevention of magnesium alloys is a key reference tool for all those working with magnesium and its alloys, including scientists, engineers, metallurgists, aerospace and automotive professionals, and academics interested in this field. Chapters provide an overview of surface cleaning and pre-conditioning Examines processes to improve the corrosion resistance of magnesium alloys, including laser treatments and chemical conversion and electrochemical anodization Discusses cold spray, sol-gel and electrophoretic coatings

Magnesium (Mg) alloys have low corrosion resistance and exhibit unusual corrosion behavior in aqueous environments. Because of this unique corrosion performance, some special corrosion prevention techniques have to be employed for Mg alloys in their applications. This chapter briefly summarizes the corrosion characteristics of Mg alloys, and also presents a strategy and methodologies to mitigate the corrosion damage of Mg alloys in applications.

Despite their tremendous potential, Mg and its alloys are not yet used in biomedical applications. This book aims to provide scientific insights into the challenges of the materials, and give an overview of the research regarding their mechanical properties, corrosion behaviour and biological performances. The authors intend to put the reader into the position to accurate discern the proper Mg-based material for his/her applications and to choose the proper improvement strategy to his/her cause. To this aim, the manuscript is structured as follow: in Section 2, the main challenges hampering the use of magnesium in biomedical applications and the common improvement strategies are listed. In Section 3, the most investigated Mg alloys are reported in separate sub-sections, detailing their mechanical properties, corrosion behaviour and biotoxicity. High-pure and ultra-high-pure Mg, Al-based Mg alloys, Zn-based Mg alloys, Ca-based alloys and RE-based Mg alloys have been considered. In Section 4, the alloys’ performances with respect to the challenges is summarized providing the reader with useful information and suggestions on the potentially most suited choice. Finally, in Section 5, an outlook portraying the authors’ opinion of the future development of the field will be provided. This book will allow biomedical engineers, surface scientists, material scientists, implant manufacturers and companies working on implant approval an overview of the state-of-the-art technologies adopted so far to overcome the drawbacks of Mg for biomedical applications. Particular emphasis is put on explaining the link between mechanical, corrosion and biocompatible properties of Mg and its alloys as well as their pros and cons. In doing so, the authors intend to put the reader into the position to accurate discern the proper Mg-based material for his/her applications and to choose the proper improvement strategy to his/her cause.

Classical magnesium alloys are a combination of aluminium, magnesium, manganese and zinc. Magnesium combined with lithium forms ultralight alloys that have many uses. Since it is a reasonable material, it offers great possibilities and is constantly tested at various angles of applications and properties. Magnesium, previously used for military purposes, seems to fit perfectly to the requirements of the currently prevailing technology. Low density with appropriate mechanical properties (strength, high operating temperature), good foundry properties (high castability and low shrinkage), vibration damping ability and cost-effectiveness of recycling seem to be an ideal response to market needs. All things considered, magnesium alloys are the perfect material used in various industries starting from the automotive industry, through sport, electronics up to the space industry and defence. This book is written by experts in various areas of magnesium science and technology. It gives a general idea of modern advancements in theory and practical purposes of magnesium alloys. The book reports fundamental aspects of corrosion types and details about magnesium alloys designed to work in elevated temperatures and superplastic behaviour. Fundamentals, broad experience, theory as well as complex technological aspects make this work helpful for engineers and scientists from all over the world.