Fouling In Refineries

Fouling in Refineries is an important and ongoing problem that directly affects energy efficiency resulting in increased costs, production losses, and even unit shutdown, requiring costly expenditures to clean up equipment and return capacity to positive levels. This text addresses this common challenge for the hydrocarbon processing community within each unit of the refinery. As refineries today face a greater challenge of accepting harder to process heavier crudes and the ongoing flow of the lighter shale oil feedstocks, resulting in bigger challenges to balance product stability within their process equipment, this text seeks to inform all relative refinery personnel on how to monitor fouling, characterize the deposits, and follow all available treatments. With basic modeling and chemistry of fouling and each unit covered, users will learn how to operate at maximum production rates and elongate the efficiency of their refinery’s capacity. Presents an understanding of the breakdown of fouling per refinery unit, including distillation and coking units Provides all the factors, crude types, and refining blends that cause fouling, especially the unconventional feedstocks and high acid crudes used today Helps users develop an analysis-based treatment and control strategy that empowers them to operate refinery equipment at a level that prevents fouling from occurring

With production from unconventional rigs continuing to escalate and refineries grappling with the challenges of shale and heavier oil feedstocks, petroleum engineers and refinery managers must ensure that equipment used with today’s crude oil is protected from fouling deposits Crude Oil Fouling addresses this overarching challenge for the petroleum community with clear explanations on what causes fouling, current models and new approaches to evaluate and study the formation of deposits, and how today’s models could be applied from lab experiment to onsite field usability for not just the refinery, but for the rig, platform, or pipeline. Crude Oil Fouling is a must-have reference for every petroleum engineer’s library that gives the basic framework needed to analyze, model, and integrate the best fouling strategies and operations for crude oil systems. Defines the most critical variables and events that cause fouling Explains the consequences of fouling and its impact on operations, safety, and economics Provides the technical models available to better predict and eliminate the potential for fouling in any crude system

This book addresses corrosion problems and their solutions at facilities in the oil refining and petrochemical industry, including cooling water and boiler feed water units. Further, it describes and analyzes corrosion control actions, corrosion monitoring, and corrosion management. Corrosion problems are a perennial issue in the oil refining and petrochemical industry, as they lead to a deterioration of the functional properties of metallic equipment and harm the environment – both of which need to be protected for the sake of current and future generations. Accordingly, this book examines and analyzes typical and atypical corrosion failure cases and their prevention at refineries and petrochemical facilities, including problems with: pipelines, tanks, furnaces, distillation columns, absorbers, heat exchangers, and pumps. In addition, it describes naphthenic acid corrosion, stress corrosion cracking, hydrogen damages, sulfidic corrosion, microbiologically induced corrosion, erosion-corrosion, and corrosion fatigue occurring at refinery units. At last, fouling, corrosion and cleaning are discussed in this book.

Over the last several decades, the petroleum industry has experienced significant changes in resource availability, petro-politics, and technological advancements dictated by the changing quality of refinery feedstocks. However, the dependence on fossil fuels as the primary energy source has remained unchanged. Refinery Feedstocks addresses the problems of changing feedstock availability and properties; the refining process; and solids deposition during refining. This book will take the reader through the various steps that are necessary for crude oil evaluation and refining including the potential for the use of coal liquids, shale oil, and non-fossil fuel materials (biomass) as refinery feedstocks. Other features: Describes the various types of crude oil and includes a discussion of extra heavy oil and tar sand bitumen Includes basic properties and specifications of crude oil and the significance in refinery operations This book is a handy reference for engineers, scientists, and students who want an update on crude oil refining and on the direction the industry must take to assure the refinability of various feedstocks and the efficiency of the refining processes in the next fifty years. Non-technical readers, with help from the extensive glossary, will also benefit from reading this book.

PETROLEUM REFINING This fourth volume in the Petroleum Refining set, this book continues the most up-to-date and comprehensive coverage of the most significant and recent changes to petroleum refining, presenting the state-of-the-art to the engineer, scientist, or student. This book provides the design of heat exchanger equipment, crude oil fouling in pre-heat train exchangers, crude oil fouling models, fouling mitigation and monitoring, prevention and control of liquid and gas side fouling, using the Excel spreadsheet and UniSim design software for the design of shell and tube heat exchangers, double pipe heat exchangers, air-cooled exchangers, heat loss tracing for process piping, pinch analysis for hot and cold utility targets and process safety incidents involving these equipment items and pertinent industrial case studies. Use of UniSim Design (UniSim STE) software is illustrated in further elucidation of the design of shell and tube heat exchangers, condensers, and UniSim ExchangerNet R470 for the design of heat exchanger networks using pinch analysis. This is important for determining minimum cold and hot utility requirements, composite curves of hot and cold streams, the grand composite curve, the heat exchanger network, and the relationship between operating cost index target and the capital cost index target against ΔTmin. Useful as a textbook, this is also an excellent, handy go-to reference for the veteran engineer, a volume no chemical or process engineering library should be without. Written by one of the world’s foremost authorities, this book sets the standard for the industry and is an integral part of the petroleum refining renaissance. It is truly a must-have for any practicing engineer or student in this area. This groundbreaking new volume: Assists engineers in rapidly analyzing problems and finding effective design methods and select mechanical specifications Provides improved design manuals to methods and proven fundamentals of process design with related data and charts Covers a complete range of basic day–to–day petroleum refining operations topics with new materials on significant industry changes Extensive Excel spreadsheets for the design of process vessels for mechanical separation of two-phase and three-phase fluids, double-pipe heat exchanger, air-cooled exchanger, pinch analysis for hot and cold utility targets. Provides UniSim ®-based case studies for enabling simulation of key processes outlined in the book Helps achieve optimum operations and process conditions and shows how to translate design fundamentals into mechanical equipment specifications Has a related website that includes computer applications along with spreadsheets and concise applied process design flow charts and process data sheets Provides various case studies of process safety incidents in refineries and means of mitigating these from investigations by the US Chemical Safety Board Includes a vast Glossary of Petroleum and Technical Terminology

This unique and comprehensive text considers all aspects of heat exchanger fouling from the basic science of how surfaces become fouled to very practical ways of mitigating the problem and from mathematical modelling of different fouling mechanisms to practical methods of heat exchanger cleaning. The problems that restrict the efficient operation of equipment are described and the costs, some of them hidden costs, that are associated with the fouling of heat exchangers are discussed. Some simple concepts and models of the fouling processes are presented as part of the introduction to the subject. Advice on the selection, design, installation and commissioning of heat exchangers to minimise fouling is given. A large part of the text is devoted to the use of chemical and other additives to reduce or eliminate the problem of fouling. Another large section is designed to give information on both on-line and off-line cleaning of heat exchangers. One of the difficulties faced by designers and operators of heat exchangers is anticipating the likely extent of fouling problems to be encountered with different flow streams. Another large section addresses the question and describes methods that have been used in attempting to define fouling potential. The book concludes with a chapter on how fouling information can be obtained using plant data, field tests and laboratory studies.

Advanced Analytic Control Techniques for Thermal Systems with Heat Exchangers presents the latest research on sophisticated analytic and control techniques specific for Heat Exchangers (HXs) and heat Exchanger Networks (HXNs), such as Stability Analysis, Efficiency of HXs, Fouling Effect, Delay Phenomenon, Robust Control, Algebraic Control, Geometric Control, Optimal Control, Fuzzy Control and Artificial Intelligence techniques. Editor Libor Pekar and his team of global expert contributors combine their knowledge and experience of investigated and applied systems and processes in this thorough review of the most advanced networks, analyzing their dynamics, efficiency, transient features, physical properties, performance, feasibility, flexibility and controllability. The structural and dynamic analyses and control approaches of HXNs, as well as energy efficient manipulation techniques are discussed, in addition to the design of the control systems through the full life cycle. This equips the reader with an understanding of the relevant theory in a variety of settings and scenarios and the confidence to apply that knowledge to solve problems in an academic or professional setting.Graduate students and early-mid career professionals require a robust understanding of how to suitably design thermal systems with HXs and HXNs to achieve required performance levels, which this book offers in one consolidated reference. All examples and solved problems included have been tried and tested, and these combined with the research driven theory provides professionals, researchers and students with the most recent techniques to maximize the energy efficiency and sustainability of existing and new thermal power systems. Analyses several advanced techniques, the theoretical background of these techniques and includes models, examples and results throughout Focusses on advanced analytic and control techniques which have been investigated or applied to thermal systems with HXs and HXNs Includes practical applications and advanced ideas from leading experts in the field, as well as case studies and tested problems and solutions