Refinery Feedstocks

Over the last several decades, the petroleum industry has experienced significant changes in resource availability, petro-politics, and technological advancements dictated by the changing quality of refinery feedstocks. However, the dependence on fossil fuels as the primary energy source has remained unchanged. Refinery Feedstocks addresses the problems of changing feedstock availability and properties; the refining process; and solids deposition during refining. This book will take the reader through the various steps that are necessary for crude oil evaluation and refining including the potential for the use of coal liquids, shale oil, and non-fossil fuel materials (biomass) as refinery feedstocks. Other features: Describes the various types of crude oil and includes a discussion of extra heavy oil and tar sand bitumen Includes basic properties and specifications of crude oil and the significance in refinery operations This book is a handy reference for engineers, scientists, and students who want an update on crude oil refining and on the direction the industry must take to assure the refinability of various feedstocks and the efficiency of the refining processes in the next fifty years. Non-technical readers, with help from the extensive glossary, will also benefit from reading this book.

As feedstocks to refineries change, there must be an accompanying change in refinery technology. This means a movement from conventional means of refining heavy feedstocks using (typically) coking technologies to more innovative processes that will coax the last drips of liquid fuels from the feedstock. This book presents the evolution of refinery processes during the last century and as well as the means by which refinery processes will evolve during the next three-to-five decades. Chapters contain material relevant to (1) comparisons of current feedstocks with heavy oil and bio-feedstocks; (2) evolution of refineries since the 1950s, (3) properties and refinability of heavy oil and bio-feedstocks, (4) thermal processes vs. hydroprocesses, and (5) evolution of products to match the environmental market. Process innovations that have influenced refinery processing over the past three decades are presented, as well as the relevant patents that have the potential for incorporation into future refineries. • Comparison of current feedstocks with heavy oil and bio-feedstocks. • Evolution of refineries over the past three decades. • Properties and refinability of heavy oil and bio-feedstocks. • Thermal processes vs. Hydroprocesses. • Evolution of products to match the environmental market. Investigates the engineering and plant design challenges presented by heavy oil and bio-feedstocks Explores the legislatory and regulatory climate, including increasingly stringent environmental requirements Examines the trade-offs of thermal processes vs. hydroprocesses

Fundamentals of Petroleum Refining presents the fundamentals of thermodynamics and kinetics, and it explains the scientific background essential for understanding refinery operations. The text also provides a detailed introduction to refinery engineering topics, ranging from the basic principles and unit operations to overall refinery economics. The book covers important topics, such as clean fuels, gasification, biofuels, and environmental impact of refining, which are not commonly discussed in most refinery textbooks. Throughout the source, problem sets and examples are given to help the reader practice and apply the fundamental principles of refining. Chapters 1-10 can be used as core materials for teaching undergraduate courses. The first two chapters present an introduction to the petroleum refining industry and then focus on feedstocks and products. Thermophysical properties of crude oils and petroleum fractions, including processes of atmospheric and vacuum distillations, are discussed in Chapters 3 and 4. Conversion processes, product blending, and alkylation are covered in chapters 5-10. The remaining chapters discuss hydrogen production, clean fuel production, refining economics and safety, acid gas treatment and removal, and methods for environmental and effluent treatments. This source can serve both professionals and students (on undergraduate and graduate levels) of Chemical and Petroleum Engineering, Chemistry, and Chemical Technology. Beginners in the engineering field, specifically in the oil and gas industry, may also find this book invaluable. Provides balanced coverage of fundamental and operational topics Includes spreadsheets and process simulators for showing trends and simulation case studies Relates processing to planning and management to give an integrated picture of refining

World gasification capacity is expected to grow by more than 70% by 2015. While gasification is not a new process, the higher price in crude has lead operators and refineries to look at all possible coal-based technologies for energy conversion, and with the flow of heavy oil, tar sands and other unconventional feedstocks making their way to the refineries for processing, refinery managers and engineers alike must be made aware of how to process these uncommon energy sources. Gasification of Unconventional Feedstocks addresses these unfamiliar feeds and provides a quick and up-to-date reference on the background, process technology and downstream applications required to help refineries maximize profits turning low-value feedstock to beneficial syngas and other fuel products. Clear and comprehensive, Gasification of Unconventional Feedstocks provides engineers and refinery managers with the tools needed to quickly adapt to the more unconventional feedstocks and still maximize their refineries potential. Get up to speed on how to adjust your refinery's processing to unconventional feedstocks Understand the technology necessary to safely and effectively manage unfamiliar feeds Turn low-value product to profit quickly with must-have tips and rules of thumb

Fouling in Refineries is an important and ongoing problem that directly affects energy efficiency resulting in increased costs, production losses, and even unit shutdown, requiring costly expenditures to clean up equipment and return capacity to positive levels. This text addresses this common challenge for the hydrocarbon processing community within each unit of the refinery. As refineries today face a greater challenge of accepting harder to process heavier crudes and the ongoing flow of the lighter shale oil feedstocks, resulting in bigger challenges to balance product stability within their process equipment, this text seeks to inform all relative refinery personnel on how to monitor fouling, characterize the deposits, and follow all available treatments. With basic modeling and chemistry of fouling and each unit covered, users will learn how to operate at maximum production rates and elongate the efficiency of their refinery’s capacity. Presents an understanding of the breakdown of fouling per refinery unit, including distillation and coking units Provides all the factors, crude types, and refining blends that cause fouling, especially the unconventional feedstocks and high acid crudes used today Helps users develop an analysis-based treatment and control strategy that empowers them to operate refinery equipment at a level that prevents fouling from occurring

Unconventional reservoirs of oil and gas represent a huge additional global source of fossil fuels. However, there is much still to be done to improve techniques for their processing to make recovery and refining of these particular energy sources more cost-effective. Brief but readable, Heavy and Extra-heavy Oil Upgrading Technologies provide readers with a strategy for future production (the up-stream) and upgrading (the down-stream). The book provides the reader with an understandable overview of the chemistry and engineering behind the latest developments and technologies in the industry as well as the various environmental regulations. Clear and rigorous, Heavy and Extra-heavy Oil Upgrading Technologies will prove tool for those scientists and engineers already engaged in fossil fuel science and technology as well as scientists, non-scientists, engineers, and non-engineers who wish to gain a general overview or update of the science and technology of unconventional fossil fuels in general and upgrading technologies in particular. The use of microorganisms and a number of physical methods, such as ultrasound, median microwave, cold plasma, electrokinetic and monocrystalline intermetallics, etc., will be discussed for the first time. Overview of the chemistry, engineering, and technology of oil sands Microorganisms and a number of physical methods such as ultrasound, median microwave, cold plasma, electrokinetic and monocrystalline intermetallics Evolving and new environmental regulations regarding oil sands production processes

Petroleum refiners must face billion-dollar investments in equipment in order to meet ever-changing environmental requirements. Because the design and construction of new processing units entail several years’ lead time, refiners are reluctant to commit these dollars for equipment that may no longer meet certain conditions when the units come on stream. Written by experts with both academic and professional experience in refinery operation, design, and evaluation, Petroleum Refining Technology and Economics, Fifth Edition is an essential textbook for students and a vital resource for engineers. This latest edition of a bestselling text provides updated data and addresses changes in refinery feedstock, product distribution, and processing requirements resulting from federal and state legislation. Providing a detailed overview of today’s integrated fuels refinery, the book discusses each major refining process as they relate to topics such as feedstock preparation, operating costs, catalysts, yields, finished product properties, and economics. It also contains end-of-chapter problems and an ongoing case study.

Guide to Practical Use of Chemicals in Refineries and Pipelines delivers a well-rounded collection of content, references, and patents to show all the practical chemical choices available for refinery and pipeline usage, along with their purposes, benefits, and general characteristics. Covering the full spectrum of downstream operations, this reference solves the many problems that engineers and managers currently face, including corrosion, leakage in pipelines, and pretreatment of heavy oil feedstocks, something that is of growing interest with today's unconventional activity. Additional coverage on special refinery additives and justification on why they react the way they do with other chemicals and feedstocks is included, along with a reference list of acronyms and an index of chemicals that will give engineers and managers the opportunity to recognize new chemical solutions that can be used in the downstream industry. Presents tactics practitioners can use to effectively locate and utilize the right chemical application specific to their refinery or pipeline operation Includes information on how to safely perform operations with coverage on environmental issues and safety, including waste stream treatment and sulfur removal Helps readers understand the composition and applications of chemicals used in oil and gas refineries and pipelines, along with where they should be applied, and how their structure interacts when mixed at the refinery