Free Nitroxyl Radicals

In the short time since the first nitroxyl radical was obtained in 1959, a new branch of chemical science has arisen and taken shape-the chemistry of stable nitroxyl radicals. The present book was written by E. G. Rozantsev, one of the pioneers in this field and a prominent specialist on stable radicals at the Division of Chemical and Biological Processes of the Institute of Chemical Physics, Academy of Sciences of the USSR. His numerous papers have contributed greatly to the present situation, wherein nitroxyl radicals have acquired unusually wide popularity, including the fields of biology, medicine, chemis try, physics, biophysics, and instrument construction. A clear illustration of the astonishingly vigorous development of this new field of chemistry can be given by the enormous flow of information on the synthesis and use of nitroxyl radicals. There is no doubt that this monograph, which in part generalizes the results of many workers studying these radicals, will be received with interest by specialists working in this field. The author has not attempted to give an exhaustive account of the material. His aim is to introduce the reader to this new field and to show the wide possibilities for using radicals in scientific experiment. The voluminous bibliography, including many papers by the author himself which may not be well enough known to the American reader, will undoubtedly contribute to the usefulness of the monograph.

Our understanding of the quantitative aspects of free radical chemistry and the involvement of radicals in such areas as biology, medicine, the environment, etc., has developed spectacularly over recent years, yet the various topics are commonly discussed separately, in specific meetings and specialised publications. Free Radicals in Biology and Environment draws together two important areas of free radical chemistry, using as a bridge the fundamental physical chemistry of free radicals (spectroscopic detection of free radicals, evaluation of absolute rate constants, elucidation of mechanisms of free radical reactions and catalysis, photochemical and radiation processes, etc.). The most relevant topics covered are the EPR detection of radicals in biochemical systems and in pollutant formation and degradation, oxidation processes in biology and in the troposphere, radiation and induced damage, and atmospheric pollutants arising from incomplete combustion. Also covered are the chemistry and biochemistry of nitric oxide and peroxynitrite, the chemistry and biochemistry of DNA radicals, the role of radicals in myeloperoxidase, lignineperoxidase, radicals and cardiovascular injury, radiation and the fragmentation of cells and tissues.

Bioactive Spin Labels is a collection of contributions by leading experts on nitroxyl radicals and their application in biomedicine. These compounds are used as side specific contrast agents for in-vivo EPR techniques. Their potential as drugs is investigated. Bioactive Spin Labels is a must for researchers in bioorganic chemistry, pharmacology and biomedicine.

This book is based on two keywords: Bioradical and ESR. Bioradical is a newly coined word which encompasses paramagnetic species in biological systems, such as active oxygen radicals and transition metal ions. Research on the structure and function of bioradicals has been attrac ting growing attention in the field of biological science, and comprehensive investigations from many fields are helping to understand the real features of these species. ESR spectroscopy also has interdisciplinary features in that its techniques have been applied to many fields, ranging from physics to medicine. It was our hope, therefore, that this book would help to clarify many aspects of bioradicals and that significant progress would be achieved in combining basic research from many different fields. This book arises from the First International Conference on Bioradicals Detected by ESR Spectroscopy (ICBES), which was held in Yamagata, a city in the Yamagata Prefecture of Japan, in 1994. About 300 participants from 16 different countries attended this conference, and about 170 papers were presented. This book is a collection of contributions from the conference and also contains eleven chapters selected by the editorial board, based on sugges tions from the members of the international editorial board of ICBES. The Yamagata Technopolis Foundation is developing a biomedical technology for the 21st century based on life science fused with material and physical science. Based on such a techno logy, the Foundation plans to share its fruits all over the world.

Offering nearly 7000 references-3900 more than the first edition-Polymeric Biomaterials, Second Edition is an up-to-the-minute source for plastics and biomedical engineers, polymer scientists, biochemists, molecular biologists, macromolecular chemists, pharmacists, cardiovascular and plastic surgeons, and graduate and medical students in these disciplines. Completely revised and updated, it includes coverage of genetic engineering, synthesis of biodegradable polymers, hydrogels, and mucoadhesive polymers, as well as polymers for dermacosmetic treatments, burn and wound dressings, orthopedic surgery, artificial joints, vascular prostheses, and in blood contacting systems.

Third Edition brings acclaimed textthoroughly up to date with the latestorganic coatings technology Organic Coatings, Third Edition is an unparalleled reference and text for organic coatings technology and its myriad applications. It begins with discussions of key principles of coatings, then thoroughly explores raw materials, physical concepts, formulations, and applications. Scientists, engineers, and paint formulators all gain a deeper understanding of the principles underlying the technology and learn how to use these principles in the development, production, and application of organic coatings. The four authors, all leading industry experts, offer a unique approach to the topic that correlates the empirical technology of coatings with the underlying science. This Third Edition has been completely revised and updated to reflect numerous changes in the field, including changes driven by increasing pressure to lower VOC emissions, reduce energy requirements, and eliminate potential health hazards from organic coatings components. In addition, the authors have developed new material to make the text more accessible for scientists and engineers first entering the field, as well as for students taking coatings courses. At the same time, the hallmarks that distinguished the two previous editions have been retained, including: Troubleshooting guidance for coatings scientists and technologists Clear differentiation between established principles and hypotheses requiring further research Precise definitions of coatings industry terminology Extensive references to the current literature Hundreds of figures that help readers visualize key concepts and techniques Whether you are just entering the field of organic coatings and need a broad overview or you are an experienced professional who needs a sophisticated reference, you can depend on Organic Coatings to give you the information and answers you need.

Plastics offer a variety of environmental benefits. However, their production, applications, and disposal present many environmental concerns. Plastics and the Environment provides state-of-the-art technical and research information on the complex relationship between the plastic and polymer industry and the environment, focusing on the sustainability, environmental impact, and cost—benefit tradeoffs associated with different technologies. Bringing together the field’s leading researchers, Anthony Andrady’s innovative collection not only covers how plastics affect the environment, but also how environmental factors affect plastics. The relative benefits of recycling, resource recovery, and energy recovery are also discussed in detail. The first of the book’s four sections represents a basic introduction to the key subject matter of plastics and the environment; the second explores several pertinent applications of plastics with environmental implications–packaging, paints and coatings, textiles, and agricultural film use. The third section discusses the behavior of plastics in some of the environments in which they are typically used, such as the outdoors, in biotic environments, or in fires. The final section consists of chapters on recycling and thermal treatment of plastics waste. Chapters include: Commodity Polymers Plastics in Transportation Biodegradation of Common Polymers Thermal Treatment of Polymer Waste Incineration of Plastics The contributors also focus on the effectiveness of recent technologies in mitigating environmental impacts, particularly those for managing plastics in the solid waste stream. Plastic and design engineers, polymer chemists, material scientists, and ecologists will find Plastics and the Environment to be a vital resource to this critical industry.