Halogen Free Flame Retardant Polymers

This book presents an overview of recent academic and industrial research efforts concerning halogen-free flame-retardant (FR) polymers and their nanocomposites. It summarizes the synthesis methods for various types of halogen-free FR polymers and their nanocomposites, and critically reviews their flame-retardant behavior, toxic-gas evolution during combustion, and inhibition methods. In turn, the book discusses the importance of metal oxide nanoparticles, nanoclay, and graphene in flame inhibition and addresses the FR properties of various FR compounds containing polymers, their FR mechanisms, and fire toxicant releasing and inhibition methods in detail. It systematically covers the synergetic effects between different FR compounds, and explains the significance of thermal stability and melt dripping for polymers’ FR properties. The fundamental concepts described here are essential to understanding the FR behaviors of various polymers and their nanocomposites, and to developing efficient, environmentally friendly FR polymers and nanocomposites for a wide range of applications. This book is ideally suited for researchers in the fields of polymer science and engineering, and for graduate students in chemistry and materials science.

Polymer Green Flame Retardants covers key issues regarding the response of polymers during fire, the mechanisms of their flame retardation, the regulations imposed on their use, and the health hazards arising from their combustion. Presenting the latest research developments, the book focuses in particular on nanocomposites, believed to be the most promising approach for producing physically superior materials with low flammability and ecological impact. The fire properties of nanocomposites of various matrixes and fillers are discussed, the toxicological characteristics of these materials are analyzed, addressing also their environmental sustainability. Edited by distinguished scientists, including an array of international industry and academia experts, this book will appeal to chemical, mechanical, environmental, material and process engineers, upper-level undergraduate and graduate students in these disciplines, and generally to researchers developing commercially attractive and environmentally friendly fire-proof products. Provides recent findings on the manufacture of environmentally sustainable flame retardant polymeric materials Covers legislation and regulations concerning flame retarded polymeric material use Includes tables containing the fire properties of the most common polymeric materials

Due to the emphasis on replacing halogenated flame retardantswith alternate technologies, this handbook contains in one placeall of the current commercial non-halogenated flame retardanttechnologies, as well as experimental systems nearcommercialization. This book focuses on non-halogenated flame retardants in aholistic but practical manner. It starts with an overview ofthe regulations and customer perceptions driving non-halogenatedflame retardant selection over older halogenatedtechnologies. It then moves into separate chapters coveringthe known major classes of non-halogenated flame retardants. These chapters are written by known experts in those specificchemistries who are also industrial experts in how to apply thattechnology to polymers for fire safety needs. The handbookconcludes with some of the newer technologies in place that areeither niche performers or may be commercial in the nearfuture. Future trends in flame retardancy are alsodiscussed. The Non-Halogenated Flame Retardant Handbook book takes apractical approach to addressing the narrow subject ofnon-halogenated flame retardancy. This includes more emphasison flame retardant selection for specific plastics, practicalconsiderations in flame retardant material design, and what thestrengths and limits of these various technologies are. Previous flame retardant material science books have coverednon-halogenated flame retardants, but they focus more on how theywork rather than how to use them.

Novel Fire Retardant Polymers and Composite Materials reviews the latest scientific developments and technological advances in the design and manufacture of fire retardant polymers and composite materials. Fire retardant polymeric materials are used in a broad range of applications in fields such as aviation, automotive, computer, construction, electronics, and telecommunications. It is essential to have a better understanding of the scientific technology used in the design and manufacture of fire-resistant materials and their end products. This book includes the latest developments in fire retardant technologies for different polymeric material systems, such as PU, PP, PE, PLA, epoxy, rubber, textile, phenol resin, and PA, etc. Provides cutting-edge research in flame retardant materials, relevant to both scientific and industrial applications Presents the latest and most up-to-date fire retardant technologies Discusses the most popular fire retardant polymer systems Includes the latest developments in fire retardant technologies for different polymeric material systems, such as PU, PP, PE, PLA, epoxy, rubber, textile, phenol resin, and PA

Flammability has been recognized as an increasingly important social and scientific problem. Fire statistics in the United States (Report of the National Commission on Fire Prevention and Control, "America Burning," 1973) emphasized the vast devastation to life and property--12,OOO lives lost annually due to fire, and these deaths are usually caused by inhaling smoke or toxic gases; 300,000 fire injuries; 11.4 billion dollars in fire cost at which 2.7 billion dollars is related to property loss; a billion dollars to burn injury treatment; and 3.3 billion dollars in productivity loss. It is obvious that much human and economic misery can be attributed to fire situations. In relation to this, polymer flammability has been recognized as an in creasingly important social and scientific problem. The development of flame-retardant polymeric materials is a current example where the initia tive for major scientific and technological developments is motivated by sociological pressure and legislation. This is part of the important trend toward a safer environment and sets a pattern for future example. Flame retardancy deals with our basic everyday life situations-housing, work areas, transportation, clothing and so forth-the "macroenvironment" capsule within which "homosapiens" live. As a result, flame-retardant polymers are now emerging as a specific class of materials leading to new and diversified scientific and technological ventures.

This book deals with the ecological aspects of polymer flame retardation. It deals with methods for estimating polymer flammability, the mode of action of modern flame retardants, and ecological concerns of the most used halogenated flame retardants.

There are obvious benefits in using flame-retardants, as many human lives and property are saved from fire. A large number of compounds have been identified as being used as flame-retardants. At present, knowledge of long-term effects resulting from exposure to flame retardants and their breakdown products is limited. The aim of this volume in the book series New Concepts in Polymer Science is to provide a general overview of the nature, mechanism of action, use and environmental hazards for a number of flame-retardants. This monograph (together with the book by the same authors, Ecological Aspects of Polymer Flame Retardancy (1999) will valuable to anyone interested in the field of flame-retardant chemicals.