Inorganic Two Dimensional Nanomaterials

Inorganic 2D nanomaterials, or inorganic graphene analogues, are gaining great attention due to their unique properties and potential energy applications. They contain ultrathin nanosheet morphology with one-dimensional confinement, but unlike pure carbon graphene, inorganic two-dimensional nanomaterials have a more abundant elemental composition and can form different crystallographic structures. These properties contribute to their unique chemical reaction activity, tunable physical properties and facilitate applications in the field of energy conversion and storage. Inorganic Two-dimensional Nanomaterials details the development of the nanostructures from computational simulation and theoretical understanding to their synthesis and characterization. Individual chapters then cover different applications of the materials as electrocatalysts, flexible supercapicitors, flexible lithium ion batteries and thermoelectrical devices. The book provides a comprehensive overview of the field for researchers working in the areas of materials chemistry, physics, energy and catalysis.

Two-dimensional materials have had widespread applications in nanoelectronics, catalysis, gas capture, water purification, energy storage and conversion. Initially based around graphene, research has since moved on to looking at alternatives, including transitions metal dichalcogenides, layered topological insulators, metallic mono-chalcogenides, borocarbonitrides and phosphorene. This book provides a review of research in the field of these materials, including investigation into their defects, analysis on hybrid structures focusing on their properties and synthesis, and characterization and applications of 2D materials beyond graphene. It is designed to be a single-point reference for students, teachers and researchers of chemistry and its related subjects, particularly in the field of nanomaterials. Contents: Transition Metal Dichalcogenides and Other Layered Materials (Manoj K Jana and C N R Rao)Topological Valleytronics (Motohiko Ezawa)Two-Dimensional, Layered Materials as Catalysts for Oxygen Reduction Reaction (Debdyuti Mukherjee and S Sampath)Phosphorene (Arpita Paul and Umesh V Waghmare)2D van der Waals Hybrid: Structures, Properties and Devices (Md Ali Aamir, Tanweer Ahmed, Kimberly Hsieh, Saurav Islam, Paritosh Karnatak, Ranjit Kashid, Phanibhusan Singha Mahapatra, Jayanta Mishra, Tathagata Paul, Avradip Pradhan, Kallol Roy, Anindita Sahoo and Arindam Ghosh)Thermoelectric Energy Conversion in Layered Metal Chalcogenides (Satya N Guin, Ananya Banik and Kanishka Biswas)Plasma Chemical and Physical Vapour Deposition Methods and Diagnostics for 2D Materials (Majed A. Alrefae, Nicholas R Glavin, Andrey A Voevodin and Timothy S Fisher)Metal Contacts to MOS2 (Naveen Kaushik, Sameer Grover, Mandar M Deshmukh and Saurabh Lodha)Strain Dependent Properties of 2D MX2 (M = Mo and W; X = S, Se and Te) (Tribhuwan Pandey, Swastibrata Bhattacharyya and Abhishek K Singh)Point Defects, Grain Boundaries and Planar Faults in 2D h-BN and TMX2 Theory and Simulations (Anjali Singh and Umesh V Waghmare) Readership: Students, teachers and researchers of chemistry and its related subjects, particularly in the field of nanomaterials. Keywords:2D Materials;Borocarbonitrides;Phosphorene;Graphene;Catalysis;Nanomaterials;Gas Capture;Water Purification;Dichalcogenides;Topological Insulators;Mono-chalcogenidesReview:0

This book focuses on inorganic nanosheets, including various oxides, chalcogenides, and graphenes, that provide two-dimensional (2D) media to develop materials chemistry in broad fields such as electronics, photonics, environmental science, and biology. The application area of nanosheets and nanosheet-based materials covers the analytical, photochemical, optical, biological, energetic, and environmental research fields. All of these applications come from the low dimensionality of the nanosheets, which anisotropically regulate structures of solids, microspaces, and fluids. Understanding nanosheets from chemical, structural, and application aspects in relation to their "fully nanoscopic" characters will help materials scientists to develop novel advanced materials. This is the first book that accurately and concisely summarizes this field including exfoliation and intercalation chemistries of layered crystals. The book provides perspective on the materials chemistry of inorganic nanosheets. The first section describes fundamental aspects of nanosheets common to diverse applications: how unique structures and properties are obtained from nanosheets based on low dimensionality. The second section presents state-of-the-art descriptions of how the 2D nature of nanosheets is utilized in each application of the materials that are developed.

This book highlights the synthesis, chemistry and applications of two-dimensional (2D) inorganic nanoplatelets in polymer nanocomposites.

This book provides much-needed reviews of fast-developing areas of 2D-related photo(electro)catalytic materials.

Functional, flexible and lightweight products are in high demand for modern technologies ranging from microelectronics to energy storage devices. The majority of polymers are thermal and electrical insulators, which hinder their use in these applications. The conductivity of polymers can be significantly enhanced by the incorporation of conducting inorganic nanoparticles. However, this relies not only on the structure and function of the inorganic particles, but is highly determined by the morphology and dispersion of the nanoparticles, interfacial interactions and fabrication technologies of the composites. This book highlights the synthesis, chemistry and applications of two-dimensional (2D) inorganic nanoplatelets in polymer nanocomposites. Chapters cover technical challenges, such as surface functionalisation, compatibilization, interfacial interaction, dispersion, and manufacturing technologies of the polymer nanocomposites. The book also discusses the applications of these polymer nanocomposites in electronics and energy storage. With contributions from global experts, the book provides a much-needed overview of the field, giving advanced undergraduates, postgraduates and other researchers with a convenient introduction to the topic.

This book is an extensive review of the recent accomplishments in the fabrication, process, characterizations, and applications of 2D nanomaterials-based polymer nanocomposites. Consisting of 23 chapters, it covers a comprehensive analysis of 2D nanomaterials and the influence of their properties. It examines the current state of the art, recent progress, new challenges, and future opportunities in developing multifunctional 2D nanomaterials-based polymer nanocomposites. This book presents discussions on the discovery of 2D nanomaterials and their unique properties and structures. It also provides discussions on the applications of 2D nanomaterials-based PNCs and critical reviews of 2D nanomaterials-based PNCs for liquid and gas separation sensing. Furthermore, it gives a detailed overview of anticorrosive coatings based on 2D nanomaterials based on PNCs.

This book provides an overview of the latest scientific developments and technological advances in two-dimensional (2D) nanomaterials for fire-safe polymers. It summarizes the preparation methods for diverse types of 2D nanomaterials and their polymer composites and reviews their flame-retardant properties, toxic gas and smoke emission during combustion, and inhibition strategies. Covers fundamental aspects like influence of size and dispersion of 2D nanomaterials to help readers develop efficient, multi-functional, and ecofriendly fire-safe polymer composites for a wide range of applications Discusses new-emerging 2D nanomaterials for fire-safe polymer applications, including MXenes, graphitic carbon nitride, boron nitride, and black phosphorus Introduces basic modes of flame retardant action of 2D nanomaterials, including smoke and toxic gas suppression, and the role of 2D nanomaterials in promoting char formation This book is suitable for both scholars and engineers in the fields of polymer science and engineering. It is also aimed at graduate students in chemistry, materials, and safety science and engineering.