Lithium Chemistry

Lithium Process Chemistry: Resources, Extraction, Batteries and Recycling presents, for the first time, the most recent developments and state-of-the-art of lithium production, lithium-ion batteries, and their recycling. The book provides fundamental and theoretical knowledge on hydrometallurgy and electrochemistry in lithium-ion batteries, including terminology related to these two fields. It is of particular interest to electrochemists who usually have no knowledge in hydrometallurgy and hydrometallurgists not familiar with electrochemistry applied to Li-ion batteries. It is also useful for both teachers and students, presenting an overview on Li production, Li-ion battery technologies, and lithium battery recycling processes that is accompanied by numerous graphical presentations of different battery systems and their electrochemical performances. The book represents the first time that hydrometallurgy and electrochemistry on lithium-ion batteries are assembled in one unique source. Provides fundamental and theoretical knowledge on hydrometallurgy and electrochemistry in lithium-ion batteries Represents the first time that hydrometallurgy and electrochemistry on lithium-ion batteries are assembled in one unique source. Ideal for both electrochemists who usually have no knowledge in hydrometallurgy and hydrometallurgists not familiar with electrochemistry applied to Li-ion batteries Presents recent developments, as well as challenges in lithium production and lithium-ion battery technologies and their recycling Covers examples of Li processes production with schematics, also including numerous graphical presentations of different battery systems and their electrochemical performances

An up-to-date, comprehensive guide to LITHIUM CHEMISTRY Although lithium has been the subject of numerous individualstudies, this intriguing element has rarely been examined from thebroad perspective many researchers require. Lithium Chemistry: ATheoretical and Experimental Overview fills this void by providingthe most thorough and up-to-date overview available of currenttheories and experimental data. Supported by nearly two hundred illustrations, this book draws uponthe expertise of prominent researchers in the field, and treats thefull range of modern applications and techniques. The result is aunique and invaluable guide to lithium studies for researchers andgraduate students working in the fields of organic, inorganic, andorgano-metallic chemistry. Lithium Chemistry: A Theoretical and Experimental Overview assumesa background in quantum chemistry and experimental physicalchemistry at the graduate level and includes coverage of thesemajor topics: * Bonding, structures, and energies in organolithium compounds * Theoretical studies of aggregates of lithium compounds * Comparison of lithium and hydrogen bonds * Lithium atom matrix reactions with small molecules * NMR of organolithium compounds * Aspects of the thermochemistry of lithium compounds * The structure of lithiated amines and lithiated ethers--fromcarbanions to carbenoids * Complexes of inorganic lithium salts * Structures of lithium salts of heteroatom compounds * Synthetic ionophores for lithium ions

The Chemistry of Lithium, Sodium, Potassium, Rubidium, Cesium, and Francium studies the physical and chemical properties of the elements listed in the title, including their chemical compounds and reactions. This book first features lithium, including its characterization, metals, and compounds. This topic is followed by discussions on the remaining featured elements in this text, encompassing their discovery and history, occurrence and distribution, and production. Then, this text presents the chemistry and chemical properties of the elements, specifically discussing topics such as the reactions of the metals, intermetallic compounds, hydrides, halides, cyanides and cyanates, and oxides and peroxides. The last two chapters examine biological activity and analytical chemistry of the elements. This book will be valuable to students and experts in the field of chemistry, as well as those in related fields.

The Handbook of Lithium-Ion Battery Pack Design: Chemistry, Components, Types and Terminology,?Second Edition provides a clear and concise explanation of EV and Li-ion batteries for readers that are new to the field. The second edition expands and updates all topics covered in the original book, adding more details to all existing chapters and including major updates to align with all of the rapid changes the industry has experienced over the past few years. This handbook offers a layman’s explanation of the history of vehicle electrification and battery technology, describing the various terminology and acronyms and explaining how to do simple calculations that can be used in determining basic battery sizing, capacity, voltage, and energy. By the end of this book the reader will have a solid understanding of the terminology around Li-ion batteries and be able to undertake simple battery calculations. The book is immensely useful to beginning and experienced engineers alike who are moving into the battery field. Li-ion batteries are one of the most unique systems in automobiles today in that they combine multiple engineering disciplines, yet most engineering programs focus on only a single engineering field. This book provides the reader with a reference to the history, terminology and design criteria needed to understand the Li-ion battery and to successfully lay out a new battery concept. Whether you are an electrical engineer, a mechanical engineer or a chemist, this book will help you better appreciate the inter-relationships between the various battery engineering fields that are required to understand the battery as an Energy Storage System. It gives great insights for readers ranging from engineers to sales, marketing, management, leadership, investors, and government officials. Adds a brief history of battery technology and its evolution to current technologies? Expands and updates the chemistry to include the latest types Discusses thermal runaway and cascading failure mitigation technologies? Expands and updates the descriptions of the battery module and pack components and systems?? Adds description of the manufacturing processes for cells, modules, and packs? Introduces and discusses new topics such as battery-as-a-service, cell to pack and cell to chassis designs, and wireless BMS?

Lithium (Li) metal-based rechargeable batteries hold significant promise to meet the ever-increasing demands for portable electronic devices, electric vehicles and grid-scale energy storage, making them the optimal alternatives for next-generation secondary batteries. Nevertheless, Li metal anodes currently suffer from major drawbacks, including safety concerns, capacity decay and lifespan degradation, which arise from uncontrollable dendrite growth, notorious side reactions and infinite volume variation, thereby limiting their current practical application. Numerous critical endeavors from different perspectives have been dedicated to developing highly stable Li metal anodes. Herein, a comprehensive overview of Li metal anodes regarding fundamental mechanisms, scientific challenges, characterization techniques, theoretical investigations and advanced strategies is systematically presented. First, the basic working principles of Li metal-based batteries are introduced. Specific attention is then paid to the fundamental understanding of and challenges facing Li metal anodes. Accordingly, advanced characterization approaches and theoretical computations are introduced to understand the fundamental mechanisms of dendrite growth and parasitic reactions. Recent key progress in Li anode protection is then comprehensively summarized and categorized to generate an overview of the respective superiorities and limitations of the various strategies. Furthermore, this review concludes the remaining obstacles and potential research directions for inspiring the innovation of Li metal anodes and endeavors to accomplish the practical application of next-generation Li-based batteries.

Explains the current state of the science and points the way to technological advances First developed in the late 1980s, lithium-ion batteries now power everything from tablet computers to power tools to electric cars. Despite tremendous progress in the last two decades in the engineering and manufacturing of lithium-ion batteries, they are currently unable to meet the energy and power demands of many new and emerging devices. This book sets the stage for the development of a new generation of higher-energy density, rechargeable lithium-ion batteries by advancing battery chemistry and identifying new electrode and electrolyte materials. The first chapter of Lithium Batteries sets the foundation for the rest of the book with a brief account of the history of lithium-ion battery development. Next, the book covers such topics as: Advanced organic and ionic liquid electrolytes for battery applications Advanced cathode materials for lithium-ion batteries Metal fluorosulphates capable of doubling the energy density of lithium-ion batteries Efforts to develop lithium-air batteries Alternative anode rechargeable batteries such as magnesium and sodium anode systems Each of the sixteen chapters has been contributed by one or more leading experts in electrochemistry and lithium battery technology. Their contributions are based on the latest published findings as well as their own firsthand laboratory experience. Figures throughout the book help readers understand the concepts underlying the latest efforts to advance the science of batteries and develop new materials. Readers will also find a bibliography at the end of each chapter to facilitate further research into individual topics. Lithium Batteries provides electrochemistry students and researchers with a snapshot of current efforts to improve battery performance as well as the tools needed to advance their own research efforts.

In the decade since the introduction of the first commercial lithium-ion battery research and development on virtually every aspect of the chemistry and engineering of these systems has proceeded at unprecedented levels. This book is a snapshot of the state-of-the-art and where the work is going in the near future. The book is intended not only for researchers, but also for engineers and users of lithium-ion batteries which are found in virtually every type of portable electronic product.