Mesoscale Chemistry

In the last few decades great strides have been made in chemistry at the nanoscale, where the atomic granularity of matter and the exact positions of individual atoms are key determinants of structure and dynamics. Less attention, however, has been paid to the mesoscale--it is at this scale, in the range extending from large molecules (10 nm) through viruses to eukaryotic cells (10 microns), where interesting ensemble effects and the functionality that is critical to macroscopic phenomenon begins to manifest itself and cannot be described by laws on the scale of atoms and molecules alone. To further explore how knowledge about mesoscale phenomena can impact chemical research and development activities and vice versa, the Chemical Sciences Roundtable of the National Research Council convened a workshop on mesoscale chemistry in November 2014. With a focus on the research on chemical phenomena at the mesoscale, participants examined the opportunities that utilizing those behaviors can have for developing new catalysts, adding new functionality to materials, and increasing our understanding of biological and interfacial systems. The workshop also highlighted some of the challenges for analysis and description of mesoscale structures. This report summarizes the presentations and discussion of the workshop.

Mesoscale Modeling in Chemical Engineering, a volume in the Advances in Chemical Engineering series provides the reader with personal views of authorities in the field. Subjects covered are not limited to the classical chemical engineering disciplines, with contributions connecting chemical engineering to related scientific fields, thus providing new ideas for additional thought. The book balances well developed areas such as process industry, transformation of materials, energy, and environmental issues with areas where applications of chemical engineering are more recent or emerging. Contains reviews by leading authorities in the respective areas Presents Up-to-date reviews of latest techniques in modeling of catalytic processes Includes a mix of US and European authors, as well as academic/industrial/research institute perspectives Contains the critical connections between computation and experimental methods

This book, as the outcome of the COST-728/NetFAM workshop, focuses on the following main topics: 1) on-line coupled meteorology-chemistry modelling with two-way feedbacks, 2) off-line coupled modelling and interfaces, 3) validation and case studies including air quality related episodes, and 4) integration of atmospheric chemical transport (ACT) models with numerical weather prediction (NWP). This book is one of the first attempts to give an overall look on such integrated meso-meteorology and chemistry modelling approach. It reviews the current situation with the on-line and off-line coupling of mesoscale meteorological and ACT models worldwide as well as discusses advantages and shortcomings, best practices, and gives recommendations for on-line and off-line coupling of NWP and ACT models, implementation strategy for different feedback mechanisms, direct and indirect effects of aerosols and advanced interfaces between both types of models. The book is oriented towards numerical weather prediction and air quality modelling communities.

The formation, transport and impact of photo-oxidants, e.g., ozone, is a major environmental problem in densely populated areas with corresponding high emissions of ozone precursor substances such as NOx and volatile organic carbon compounds (VOC). Although major progress has been achieved within the last decade, there are still significant uncertainties in our understanding of the chemical behavior of the polluted atmosphere, in particular the interaction between cities and surrounding areas as well as the contribution of pollution to the global changes, e.g., the oxidation capacity of the troposphere. This book focuses on specific issues related to the chemistry of polluted atmospheres. The main issues cover areas such as modelling, emission inventories, chemical transformation as well as transport of pollutants on an urban/regional scale. The overall topic of the book is addressed in an interdisciplinary approach. The book is of specific interest for advanced researchers in tropospheric chemistry, from the PhD or post-doctoral levels and beyond.

This two-volume set provides an extensive review of the abundant past and recent literature on the atmospheric chemistry in the Mediterranean region. The books document the experience gained on the atmospheric composition over the Mediterranean basin and close areas after six decades of research, starting from early studies of radioactive aerosol fallouts and intense desert dust events in the 1960s, followed by studies of aerosols collected during oceanographic cruises in the early 1980s, and including subsequent knowledge from various surface monitoring stations, intensive campaigns, satellite climatologies, laboratory studies, as well as chemistry-transport and climate models. Through ten thematic sections, the authors examine the sources and fates of atmospheric pollutants over the Mediterranean basin and what we know about the main impacts of the regional atmospheric chemistry. This overview not only considers the full regional cycle of both aerosol and reactive gases including emissions, transport, transformations, and sinks, but also addresses their major impacts on air quality and health, on the radiative budget and climate, on marine chemistry and biogeochemistry . The volumes are an initiative from the ChArMEx project that has federated many studies on those topics in the 2010-2020decade, and update the scientific knowledge by integrating the ChArMEx and non-ChArMEx literature. The books are contributed by a large pool of well-known authors from the respective fields, mainly from France and Greece, but also from six other Mediterranean and eight non-Mediterranean countries. All Chapters have been peer-reviewed by international scientific experts in the corresponding domains. Volume 2 focuses on emissions and their sources, recent progress on chemical processes, aerosol properties, atmospheric deposition, and the impacts of air pollution on human health, regional climate and ecosystems. Recommendations for future research in these fields are finally proposed. The targeted audience is the academic community working on atmospheric chemistry and its impacts, especially teams having a special interest in the Mediterranean region, which includes many countries and institutes worldwide.