Principles Of Classical Thermodynamics Applied To Materials Science

The aim of this book is to present Classical Thermodynamics in a unified way, from the most fundamental principles to non-uniform systems, thereby requiring the introduction of coarse graining methods, leading for instance to phase field methods. Solutions thermodynamics and temperature-concentration phase diagrams are covered, plus also a brief introduction to statistical thermodynamics and topological disorder. The Landau theory is included along with a general treatment of multicomponent instabilities in various types of thermodynamic applications, including phase separation and order-disorder transitions. Nucleation theory and spinodal decomposition are presented as extreme cases of a single approach involving the all-important role of fluctuations.In this way, it is hoped that this coverage will reconcile in a unified manner techniques generally presented separately in physics and materials texts.

"Thermodynamics of Materials" introduces the basic underlying principles of thermodynamics as well as their applicability to the behavior of all classes of materials, while providing an integrated approach from macro- (or classical) thermodynamics to meso- and nanothermodynamics, and microscopic (or statistical) thermodynamics. The book is intended for scientists, engineers and graduate students in all fields involving materials science-related disciplines. Both Dr. Qing Jiang and Dr. Zi Wen are professors at Jilin University.

Thermodynamics in Materials Science, Second Edition is a clear presentation of how thermodynamic data is used to predict the behavior of a wide range of materials, a crucial component in the decision-making process for many materials science and engineering applications. This primary textbook accentuates the integration of principles, strategies, and thermochemical data to generate accurate “maps” of equilibrium states, such as phase diagrams, predominance diagrams, and Pourbaix corrosion diagrams. It also recommends which maps are best suited for specific real-world scenarios and thermodynamic problems. The second edition yet. Each chapter presents its subject matter consistently, based on the classification of thermodynamic systems, properties, and derivations that illustrate important relationships among variables for finding the conditions for equilibrium. Each chapter also contains a summary of important concepts and relationships as well as examples and sample problems that apply appropriate strategies for solving real-world problems. The up-to-date and complete coverage ofthermodynamic data, laws, definitions, strategies, and tools in Thermodynamics in Materials Science, Second Edition provides students and practicing engineers a valuable guide for producing and applying maps of equilibrium states to everyday applications in materials sciences.

Maintaining the substance that made Introduction to the Thermodynamic of Materials a perennial best seller for decades, this Sixth Edition is updated to reflect the broadening field of materials science and engineering. The new edition is reorganized into three major sections to align the book for practical coursework, with the first (Thermodynamic Principles) and second (Phase Equilibria) sections aimed at use in a one semester undergraduate course. The third section (Reactions and Transformations) can be used in other courses of the curriculum that deal with oxidation, energy, and phase transformations. The book is updated to include the role of work terms other than PV work (e.g., magnetic work) along with their attendant aspects of entropy, Maxwell equations, and the role of such applied fields on phase diagrams. There is also an increased emphasis on the thermodynamics of phase transformations and the Sixth Edition features an entirely new chapter 15 that links specific thermodynamic applications to the study of phase transformations. The book also features more than 50 new end of chapter problems and more than 50 new figures.

This 1980 monograph develops from first principles the description of finite deformations of solids under stress and the forces acting, and also the expression of internal forces in terms of stress tensors. The important feature of the book is that elastic properties are discussed and developed consistently from classical thermodynamics. In other books, this point of view is acknowledged only by assuming the existence of an elastic energy function, thus restricting their range mainly to the problem of the spatial distribution of stresses and strains. Topics discussed as applications of the theory include thermal expansion, specific heats, stiffness and complicances, the effects of symmetry on thermodynamic properties, diffusion in a stressed solid, equilibrium in contact with a solution of the solid, phase stability, solid state phase transitions and twinning.

This text explores the connections between different thermodynamic subjects related to fluid systems. Emphasis is placed on the clarification of concepts by returning to the conceptual foundation of thermodynamics and special effort is directed to the use of a simple nomenclature and algebra. The book presents the structural elements of classical thermodynamics of fluid systems, covers the treatment of mixtures, and shows via examples and references both the usefulness and the limitations of classical thermodynamics for the treatment of practical problems related to fluid systems. It also includes diverse selected topics of interest to researchers and advanced students and four practical appendices, including an introduction to material balances and step-by-step procedures for using the Virial EOS and the PRSV EOS for fugacities and the ASOG-KT group method for activity coefficients. The Olivera-Fuentes table of PRSV parameters for more than 800 chemical compounds and the Gmehling-Tochigi tables of ASOG interaction parameters for 43 groups are included.

This textbook facilitates students’ ability to apply fundamental principles and concepts in classical thermodynamics to solve challenging problems relevant to industry and everyday life. It also introduces the reader to the fundamentals of statistical mechanics, including understanding how the microscopic properties of atoms and molecules, and their associated intermolecular interactions, can be accounted for to calculate various average properties of macroscopic systems. The author emphasizes application of the fundamental principles outlined above to the calculation of a variety of thermodynamic properties, to the estimation of conversion efficiencies for work production by heat interactions, and to the solution of practical thermodynamic problems related to the behavior of non-ideal pure fluids and fluid mixtures, including phase equilibria and chemical reaction equilibria. The book contains detailed solutions to many challenging sample problems in classical thermodynamics and statistical mechanics that will help the reader crystallize the material taught. Class-tested and perfected over 30 years of use by nine-time Best Teaching Award recipient Professor Daniel Blankschtein of the Department of Chemical Engineering at MIT, the book is ideal for students of Chemical and Mechanical Engineering, Chemistry, and Materials Science, who will benefit greatly from in-depth discussions and pedagogical explanations of key concepts. Distills critical concepts, methods, and applications from leading full-length textbooks, along with the author’s own deep understanding of the material taught, into a concise yet rigorous graduate and advanced undergraduate text; Enriches the standard curriculum with succinct, problem-based learning strategies derived from the content of 50 lectures given over the years in the Department of Chemical Engineering at MIT; Reinforces concepts covered with detailed solutions to illuminating and challenging homework problems.

This book is a concise, readable, yet authoritative primer of basic classic thermodynamics. Many students have difficulty with thermodynamics, and find at some stage of their careers in academia or industry that they have forgotten what they learned, or never really understood these fundamental physical laws. As the title of the book suggests, the author has distilled the subject down to its essentials, using many simple and clear illustrations, instructive examples, and key equations and simple derivations to elucidate concepts. Based on many years of teaching experience at the undergraduate and graduate levels, “Essential Classical Thermodynamics” is intended to provide a positive learning experience, and to empower the reader to explore the many possibilities for applying thermodynamics in other fields of science, engineering, and even economics where energy plays a central role. Thermodynamics is fun when you understand it!